Spatial Electrochromism in Metallopolymeric Films of Ruthenium Polypyridyl Complexes

Thin films of poly[Ru(vbpy)2(py)2]2+ (vbpy is 4-vinyl-4‘-methyl-2,2‘-bipyridine; py is pyridine) have been deposited on electrodes by reductive electropolymerization. Photolysis of the films in the presence of chloride ion leads to photochemical loss of the pyridine ligands and sequential formation...

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Veröffentlicht in:	Chemistry of Materials 1996-01, Vol.8 (1), p.264-273
Hauptverfasser:	Leasure, Robert M, Ou, Wei, Moss, John A, Linton, Richard W, Meyer, Thomas J
Format:	Artikel
Sprache:	eng
Schlagworte:	40 CHEMISTRY Applied sciences CHEMICAL PREPARATION Chemistry Electrochemistry ELECTROCHROMISM Electrodeposition Exact sciences and technology General and physical chemistry Inorganic and organomineral polymers MATERIALS SCIENCE PHOTOCHEMISTRY PHOTOELECTRON SPECTROSCOPY Physicochemistry of polymers POLYMERIZATION Properties and characterization REDOX POTENTIAL RUTHENIUM COMPLEXES SPATIAL RESOLUTION Study of interfaces THIN FILMS VOLTAMETRY X-RAY SPECTROSCOPY
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