Highly Catalytic Single-Crystal Dendritic Pt Nanostructures Supported on Carbon Nanotubes
Herein we describe a one-step method for the preparation of single-crystal, dendritic Pt nanoparticles with no need of organic solvents, templates, or seeded growth. It is shown that Pt nanoparticles with two different shapesspherical or dendriticcan be efficiently supported onto the sidewalls of...
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Veröffentlicht in: | Chemistry of materials 2009-04, Vol.21 (8), p.1531-1535 |
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container_title | Chemistry of materials |
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creator | Sanles-Sobrido, Marcos Correa-Duarte, Miguel A. Carregal-Romero, Susana Rodríguez-González, Benito Álvarez-Puebla, Ramón A. Hervés, Pablo Liz-Marzán, Luis M. |
description | Herein we describe a one-step method for the preparation of single-crystal, dendritic Pt nanoparticles with no need of organic solvents, templates, or seeded growth. It is shown that Pt nanoparticles with two different shapesspherical or dendriticcan be efficiently supported onto the sidewalls of carbon nanotubes. Notably, the supported dendritic Pt nanostructrures yield unprecedented catalytic activity, evidenced through the lowest activation energy within an electron-transfer reaction as compared with those reported in the literature for Pt nanostructures. |
doi_str_mv | 10.1021/cm8033214 |
format | Article |
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It is shown that Pt nanoparticles with two different shapesspherical or dendriticcan be efficiently supported onto the sidewalls of carbon nanotubes. Notably, the supported dendritic Pt nanostructrures yield unprecedented catalytic activity, evidenced through the lowest activation energy within an electron-transfer reaction as compared with those reported in the literature for Pt nanostructures.</description><identifier>ISSN: 0897-4756</identifier><identifier>EISSN: 1520-5002</identifier><identifier>DOI: 10.1021/cm8033214</identifier><language>eng</language><publisher>American Chemical Society</publisher><subject>Nanomaterials (Nanops, Nanotubes, etc.) ; Self-Assembly and Self-Assembled Materials</subject><ispartof>Chemistry of materials, 2009-04, Vol.21 (8), p.1531-1535</ispartof><rights>Copyright © 2009 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a325t-2f42149cc73759843a52085030a091d666d517712253fcf680643400b269b57c3</citedby><cites>FETCH-LOGICAL-a325t-2f42149cc73759843a52085030a091d666d517712253fcf680643400b269b57c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/cm8033214$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/cm8033214$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids></links><search><creatorcontrib>Sanles-Sobrido, Marcos</creatorcontrib><creatorcontrib>Correa-Duarte, Miguel A.</creatorcontrib><creatorcontrib>Carregal-Romero, Susana</creatorcontrib><creatorcontrib>Rodríguez-González, Benito</creatorcontrib><creatorcontrib>Álvarez-Puebla, Ramón A.</creatorcontrib><creatorcontrib>Hervés, Pablo</creatorcontrib><creatorcontrib>Liz-Marzán, Luis M.</creatorcontrib><title>Highly Catalytic Single-Crystal Dendritic Pt Nanostructures Supported on Carbon Nanotubes</title><title>Chemistry of materials</title><addtitle>Chem. Mater</addtitle><description>Herein we describe a one-step method for the preparation of single-crystal, dendritic Pt nanoparticles with no need of organic solvents, templates, or seeded growth. It is shown that Pt nanoparticles with two different shapesspherical or dendriticcan be efficiently supported onto the sidewalls of carbon nanotubes. Notably, the supported dendritic Pt nanostructrures yield unprecedented catalytic activity, evidenced through the lowest activation energy within an electron-transfer reaction as compared with those reported in the literature for Pt nanostructures.</description><subject>Nanomaterials (Nanops, Nanotubes, etc.)</subject><subject>Self-Assembly and Self-Assembled Materials</subject><issn>0897-4756</issn><issn>1520-5002</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNptkD1PwzAURS0EEqEw8A-yMDAEnr-dEQVKkSpAKgxMkeM4JVWaVLYz5N_jqIiJ6UrvHV0dXYSuMdxhIPje7BVQSjA7QQnmBDIOQE5RAiqXGZNcnKML73cAOOIqQV-rdvvdTWmhg-6m0Jp00_bbzmaFm3w8pY-2r107P95D-qr7wQc3mjA669PNeDgMLtg6HfrY4KoYMxLGyvpLdNboztur31ygz-XTR7HK1m_PL8XDOtOU8JCRhkXb3BhJJc8VozpaKw4UNOS4FkLUHEuJCeG0MY1QIBhlABURecWloQt0e-w1bvDe2aY8uHav3VRiKOdNyr9NIntzZLXx5W4YXR_N_uF-AAd3Xmg</recordid><startdate>20090428</startdate><enddate>20090428</enddate><creator>Sanles-Sobrido, Marcos</creator><creator>Correa-Duarte, Miguel A.</creator><creator>Carregal-Romero, Susana</creator><creator>Rodríguez-González, Benito</creator><creator>Álvarez-Puebla, Ramón A.</creator><creator>Hervés, Pablo</creator><creator>Liz-Marzán, Luis M.</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20090428</creationdate><title>Highly Catalytic Single-Crystal Dendritic Pt Nanostructures Supported on Carbon Nanotubes</title><author>Sanles-Sobrido, Marcos ; Correa-Duarte, Miguel A. ; Carregal-Romero, Susana ; Rodríguez-González, Benito ; Álvarez-Puebla, Ramón A. ; Hervés, Pablo ; Liz-Marzán, Luis M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a325t-2f42149cc73759843a52085030a091d666d517712253fcf680643400b269b57c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Nanomaterials (Nanops, Nanotubes, etc.)</topic><topic>Self-Assembly and Self-Assembled Materials</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sanles-Sobrido, Marcos</creatorcontrib><creatorcontrib>Correa-Duarte, Miguel A.</creatorcontrib><creatorcontrib>Carregal-Romero, Susana</creatorcontrib><creatorcontrib>Rodríguez-González, Benito</creatorcontrib><creatorcontrib>Álvarez-Puebla, Ramón A.</creatorcontrib><creatorcontrib>Hervés, Pablo</creatorcontrib><creatorcontrib>Liz-Marzán, Luis M.</creatorcontrib><collection>CrossRef</collection><jtitle>Chemistry of materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sanles-Sobrido, Marcos</au><au>Correa-Duarte, Miguel A.</au><au>Carregal-Romero, Susana</au><au>Rodríguez-González, Benito</au><au>Álvarez-Puebla, Ramón A.</au><au>Hervés, Pablo</au><au>Liz-Marzán, Luis M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Highly Catalytic Single-Crystal Dendritic Pt Nanostructures Supported on Carbon Nanotubes</atitle><jtitle>Chemistry of materials</jtitle><addtitle>Chem. 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subjects | Nanomaterials (Nanops, Nanotubes, etc.) Self-Assembly and Self-Assembled Materials |
title | Highly Catalytic Single-Crystal Dendritic Pt Nanostructures Supported on Carbon Nanotubes |
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