Structure-Related Electrochemistry of Sulfur-Poly(acrylonitrile) Composite Cathode Materials for Rechargeable Lithium Batteries

Structure-Related Electrochemistry of Sulfur-Poly(acrylonitrile) Composite Cathode Materials for Rechargeable Lithium Batteries

The structure of sulfur-poly(acrylonitrile)-based Li-sulfur batteries is elucidated and correlated with the electrochemical performance of such devices. Apart from the poly(acrylonitrile)-derived backbone, thioamide as well as poly(sulfide) structures are proposed. Furthermore, the intermediary form...

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Veröffentlicht in:Chemistry of materials 2011-11, Vol.23 (22), p.5024-5028
Hauptverfasser: Fanous, Jean, Wegner, Marcus, Grimminger, Jens, Andresen, Änne, Buchmeiser, Michael R
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container_end_page 5028
container_issue 22
container_start_page 5024
container_title Chemistry of materials
container_volume 23
creator Fanous, Jean
Wegner, Marcus
Grimminger, Jens
Andresen, Änne
Buchmeiser, Michael R
description The structure of sulfur-poly(acrylonitrile)-based Li-sulfur batteries is elucidated and correlated with the electrochemical performance of such devices. Apart from the poly(acrylonitrile)-derived backbone, thioamide as well as poly(sulfide) structures are proposed. Furthermore, the intermediary formation of S8 during cycling and the role of the electrolyte in its reintegration during charging into are addressed. In summary, a comprehensive picture of the chemistry and electrochemistry of Li-sulfur batteries is presented.
doi_str_mv 10.1021/cm202467u
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title Structure-Related Electrochemistry of Sulfur-Poly(acrylonitrile) Composite Cathode Materials for Rechargeable Lithium Batteries
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