Energetics of Self-Assembly and Chain Confinement in Silver Alkanethiolates:  Enthalpy−Entropy Interplay

The formation enthalpies by in situ direct synthesis calorimetry for a series of silver alkanethiolates, AgS(CH2) n CH3, with various long chain-length substituents (n = 9, 11, 15, and 17) are reported. The calorimetric results support a mechanism of stepwise hierarchical assembly involving primary...

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Veröffentlicht in:	Chemistry of materials 2005-11, Vol.17 (22), p.5428-5438
Hauptverfasser:	Levchenko, Andrey A, Yee, Chanel K, Parikh, Atul N, Navrotsky, Alexandra
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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