Electrochemical Patterning of a Polyfluorene Precursor Polymer from a Microcontact Printed (μCP) Monolayer
Selective area electropolymerization of a precursor polymer in a microcontact printed pattern was used to generate a patterned conjugated and fluorescent polymer thin film. The precursor polyfluorene polymer, which has photoluminescent properties defined by the polymer main chain and electropolymeri...
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| Veröffentlicht in: | Chemistry of materials 2004-07, Vol.16 (15), p.2852-2856 |
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| container_end_page | 2856 |
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| container_issue | 15 |
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| container_title | Chemistry of materials |
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| creator | Xia, Chuanjun Advincula, Rigoberto C Baba, Akira Knoll, Wolfgang |
| description | Selective area electropolymerization of a precursor polymer in a microcontact printed pattern was used to generate a patterned conjugated and fluorescent polymer thin film. The precursor polyfluorene polymer, which has photoluminescent properties defined by the polymer main chain and electropolymerizability from the pendant carbazole units, was synthesized using a Yamamoto coupling route. The polymer was then electrochemically deposited and cross-linked selectively on the alkyl SAM defined regions to form patterns ( |
| doi_str_mv | 10.1021/cm049544g |
| format | Article |
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The precursor polyfluorene polymer, which has photoluminescent properties defined by the polymer main chain and electropolymerizability from the pendant carbazole units, was synthesized using a Yamamoto coupling route. The polymer was then electrochemically deposited and cross-linked selectively on the alkyl SAM defined regions to form patterns (<50 nm height) with high fidelity. The patterns were characterized by atomic force microscopy and optical fluorescence microscopy. The fluorescence micrograph confirmed that the polymer main chain was largely unaffected by redox electrochemistry and showed highly regular patterning characteristics in a large area. This new combination of site-selective electropolymerization and the precursor approach should provide a unique way to make patterned conjugated polymer systems.</description><identifier>ISSN: 0897-4756</identifier><identifier>EISSN: 1520-5002</identifier><identifier>DOI: 10.1021/cm049544g</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Applied sciences ; Chemistry ; Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Condensed matter: structure, mechanical and thermal properties ; Exact sciences and technology ; General and physical chemistry ; Physicochemistry of polymers ; Physics</subject><ispartof>Chemistry of materials, 2004-07, Vol.16 (15), p.2852-2856</ispartof><rights>Copyright © 2004 American Chemical Society</rights><rights>2004 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a325t-16b5315148a701a258b3c189ab9bd4a46bae7b135574c431ec8b6dee4cbc57ca3</citedby><cites>FETCH-LOGICAL-a325t-16b5315148a701a258b3c189ab9bd4a46bae7b135574c431ec8b6dee4cbc57ca3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/cm049544g$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/cm049544g$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,777,781,2752,27057,27905,27906,56719,56769</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=15965980$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Xia, Chuanjun</creatorcontrib><creatorcontrib>Advincula, Rigoberto C</creatorcontrib><creatorcontrib>Baba, Akira</creatorcontrib><creatorcontrib>Knoll, Wolfgang</creatorcontrib><title>Electrochemical Patterning of a Polyfluorene Precursor Polymer from a Microcontact Printed (μCP) Monolayer</title><title>Chemistry of materials</title><addtitle>Chem. Mater</addtitle><description>Selective area electropolymerization of a precursor polymer in a microcontact printed pattern was used to generate a patterned conjugated and fluorescent polymer thin film. The precursor polyfluorene polymer, which has photoluminescent properties defined by the polymer main chain and electropolymerizability from the pendant carbazole units, was synthesized using a Yamamoto coupling route. The polymer was then electrochemically deposited and cross-linked selectively on the alkyl SAM defined regions to form patterns (<50 nm height) with high fidelity. The patterns were characterized by atomic force microscopy and optical fluorescence microscopy. The fluorescence micrograph confirmed that the polymer main chain was largely unaffected by redox electrochemistry and showed highly regular patterning characteristics in a large area. This new combination of site-selective electropolymerization and the precursor approach should provide a unique way to make patterned conjugated polymer systems.</description><subject>Applied sciences</subject><subject>Chemistry</subject><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Physicochemistry of polymers</subject><subject>Physics</subject><issn>0897-4756</issn><issn>1520-5002</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNptkE1OwzAQhS0EEqWw4AbZINFFwE7s_CxRRQtSKyIoLNhYY9cpaRMb2a5E78YZOBOGonbDaqSZb97MewidE3xFcEKuZYdpyShdHKAeYQmOGcbJIerhosxjmrPsGJ04t8SYBLzoodVtq6S3Rr6prpHQRhV4r6xu9CIydQRRZdpN3a6NVVpFlVVybZ2xv-1O2ai2pgvUtJFBw2gP0geq0V7No8uvz2E1iKZGmxY2yp6ioxpap87-ah89j25nw7t48jC-H95MYkgT5mOSCZYSRmgBOSaQsEKkkhQliFLMKdBMgMoFSRnLqaQpUbIQ2VwpKoVkuYS0jwZb3fCTc1bV_N02HdgNJ5j_pMR3KQX2Ysu-gwv2awtaNm6_wMqMlQUOXLzlGufVx24OdsWzPM0Zn1VP_JG8vozJdMSLvS5Ix5dmbXVw_M_9byBihGk</recordid><startdate>20040727</startdate><enddate>20040727</enddate><creator>Xia, Chuanjun</creator><creator>Advincula, Rigoberto C</creator><creator>Baba, Akira</creator><creator>Knoll, Wolfgang</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20040727</creationdate><title>Electrochemical Patterning of a Polyfluorene Precursor Polymer from a Microcontact Printed (μCP) Monolayer</title><author>Xia, Chuanjun ; Advincula, Rigoberto C ; Baba, Akira ; Knoll, Wolfgang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a325t-16b5315148a701a258b3c189ab9bd4a46bae7b135574c431ec8b6dee4cbc57ca3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Applied sciences</topic><topic>Chemistry</topic><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Physicochemistry of polymers</topic><topic>Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xia, Chuanjun</creatorcontrib><creatorcontrib>Advincula, Rigoberto C</creatorcontrib><creatorcontrib>Baba, Akira</creatorcontrib><creatorcontrib>Knoll, Wolfgang</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Chemistry of materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xia, Chuanjun</au><au>Advincula, Rigoberto C</au><au>Baba, Akira</au><au>Knoll, Wolfgang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrochemical Patterning of a Polyfluorene Precursor Polymer from a Microcontact Printed (μCP) Monolayer</atitle><jtitle>Chemistry of materials</jtitle><addtitle>Chem. Mater</addtitle><date>2004-07-27</date><risdate>2004</risdate><volume>16</volume><issue>15</issue><spage>2852</spage><epage>2856</epage><pages>2852-2856</pages><issn>0897-4756</issn><eissn>1520-5002</eissn><abstract>Selective area electropolymerization of a precursor polymer in a microcontact printed pattern was used to generate a patterned conjugated and fluorescent polymer thin film. The precursor polyfluorene polymer, which has photoluminescent properties defined by the polymer main chain and electropolymerizability from the pendant carbazole units, was synthesized using a Yamamoto coupling route. The polymer was then electrochemically deposited and cross-linked selectively on the alkyl SAM defined regions to form patterns (<50 nm height) with high fidelity. The patterns were characterized by atomic force microscopy and optical fluorescence microscopy. The fluorescence micrograph confirmed that the polymer main chain was largely unaffected by redox electrochemistry and showed highly regular patterning characteristics in a large area. This new combination of site-selective electropolymerization and the precursor approach should provide a unique way to make patterned conjugated polymer systems.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/cm049544g</doi><tpages>5</tpages></addata></record> |
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| ispartof | Chemistry of materials, 2004-07, Vol.16 (15), p.2852-2856 |
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| source | ACS Publications |
| subjects | Applied sciences Chemistry Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Exact sciences and technology General and physical chemistry Physicochemistry of polymers Physics |
| title | Electrochemical Patterning of a Polyfluorene Precursor Polymer from a Microcontact Printed (μCP) Monolayer |
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