Pressure-Induced Superconductivity in (MDT-TS)(AuI2)0.441 [MDT- TS = 5H-2-(1,3-diselenol-2-ylidene)-1,3,4,6-tetrathiapentalene]: A New Organic Superconductor Possessing an Incommensurate Anion Lattice
A selenium-containing TTF-type electron donor, MDT-TS [5H-2-(1,3-diselenol-2-ylidene)-1,3,4,6-tetrathiapentalene] was effectively synthesized by a two-step reaction and utilized for electrocrystallization with an AuI2 - anion. The resulting salt, (MDT-TS)(AuI2)0.441, has a unique crystal packing, in...
Gespeichert in:
| Veröffentlicht in: | Chemistry of materials 2004-11, Vol.16 (24), p.5120-5123 |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 5123 |
|---|---|
| container_issue | 24 |
| container_start_page | 5120 |
| container_title | Chemistry of materials |
| container_volume | 16 |
| creator | Takimiya, Kazuo Kodani, Mie Niihara, Naoto Aso, Yoshio Otsubo, Tetsuo Bando, Yoshimasa Kawamoto, Tadashi Mori, Takehiko |
| description | A selenium-containing TTF-type electron donor, MDT-TS [5H-2-(1,3-diselenol-2-ylidene)-1,3,4,6-tetrathiapentalene] was effectively synthesized by a two-step reaction and utilized for electrocrystallization with an AuI2 - anion. The resulting salt, (MDT-TS)(AuI2)0.441, has a unique crystal packing, in which the donor subcell and the anion lattice are incommensurate. Although the salt has relatively high conductivity at room temperature (600 S cm-1), it showed a metal−insulator (MI) transition at T MI = 50 K. Application of hydrostatic pressure suppressed the MI transition, and at 11.4 kbar (MDT-TS)(AuI2)0.441 showed a superconducting transition at T c = 4.7 K. |
| doi_str_mv | 10.1021/cm049144t |
| format | Article |
| fullrecord | <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_cm049144t</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c418556081</sourcerecordid><originalsourceid>FETCH-LOGICAL-a350t-21ea43b6fd115a75f404733b3b18a62b1807cba60572da8dda0a4ad69c581acd3</originalsourceid><addsrcrecordid>eNptkd-KEzEUxgdRsK5e-Aa5EVpo1mQmmUwFL0r9s5XqFmYEWZFwmmTWrNNMSTK79s5bH86X8ElMqewieJOQ7_zyne9wsuwpJaeU5PS52hI2o4zFe9mI8pxgTkh-PxuRaiYwE7x8mD0K4YoQmvBqlP1aexPC4A1eOj0oo1E97IxX_eEV7bWNe2QdGr9_1eCmnoznwzKfkFPGKPp80H7_-NnU6CXiZzjHYzotsLbBdMb1XRL2ndXGmQlOhSmbljia6CF-tbAzLkLCzJcXyQLN0Qdzg879JTir_onQe7TuQ0ghrbtE4NDSqX67NS6FhmjQ3NneoRXEaJV5nD1ooQvmyd_7JPv45nWzOMOr87fLxXyFoeAk4pwaYMWmbDWlHARvGWGiKDbFhlZQ5ukkQm2gJFzkGiqtgQADXc4UrygoXZxkk6Ov8imbN63cebsFv5eUyMMe5O0eEvvsyO4gKOhaD07ZcPehLMiMUJE4fORsiOb7bR38N1mKQnDZrGt5wetycSHeyU93vqCCvOoH79LE_-n_B-8to9c</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Pressure-Induced Superconductivity in (MDT-TS)(AuI2)0.441 [MDT- TS = 5H-2-(1,3-diselenol-2-ylidene)-1,3,4,6-tetrathiapentalene]: A New Organic Superconductor Possessing an Incommensurate Anion Lattice</title><source>ACS Publications</source><creator>Takimiya, Kazuo ; Kodani, Mie ; Niihara, Naoto ; Aso, Yoshio ; Otsubo, Tetsuo ; Bando, Yoshimasa ; Kawamoto, Tadashi ; Mori, Takehiko</creator><creatorcontrib>Takimiya, Kazuo ; Kodani, Mie ; Niihara, Naoto ; Aso, Yoshio ; Otsubo, Tetsuo ; Bando, Yoshimasa ; Kawamoto, Tadashi ; Mori, Takehiko</creatorcontrib><description>A selenium-containing TTF-type electron donor, MDT-TS [5H-2-(1,3-diselenol-2-ylidene)-1,3,4,6-tetrathiapentalene] was effectively synthesized by a two-step reaction and utilized for electrocrystallization with an AuI2 - anion. The resulting salt, (MDT-TS)(AuI2)0.441, has a unique crystal packing, in which the donor subcell and the anion lattice are incommensurate. Although the salt has relatively high conductivity at room temperature (600 S cm-1), it showed a metal−insulator (MI) transition at T MI = 50 K. Application of hydrostatic pressure suppressed the MI transition, and at 11.4 kbar (MDT-TS)(AuI2)0.441 showed a superconducting transition at T c = 4.7 K.</description><identifier>ISSN: 0897-4756</identifier><identifier>EISSN: 1520-5002</identifier><identifier>DOI: 10.1021/cm049144t</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Applied sciences ; Chemistry ; Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Condensed matter: structure, mechanical and thermal properties ; Exact sciences and technology ; General and physical chemistry ; Physicochemistry of polymers ; Physics</subject><ispartof>Chemistry of materials, 2004-11, Vol.16 (24), p.5120-5123</ispartof><rights>Copyright © 2004 American Chemical Society</rights><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a350t-21ea43b6fd115a75f404733b3b18a62b1807cba60572da8dda0a4ad69c581acd3</citedby><cites>FETCH-LOGICAL-a350t-21ea43b6fd115a75f404733b3b18a62b1807cba60572da8dda0a4ad69c581acd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/cm049144t$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/cm049144t$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=16309017$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Takimiya, Kazuo</creatorcontrib><creatorcontrib>Kodani, Mie</creatorcontrib><creatorcontrib>Niihara, Naoto</creatorcontrib><creatorcontrib>Aso, Yoshio</creatorcontrib><creatorcontrib>Otsubo, Tetsuo</creatorcontrib><creatorcontrib>Bando, Yoshimasa</creatorcontrib><creatorcontrib>Kawamoto, Tadashi</creatorcontrib><creatorcontrib>Mori, Takehiko</creatorcontrib><title>Pressure-Induced Superconductivity in (MDT-TS)(AuI2)0.441 [MDT- TS = 5H-2-(1,3-diselenol-2-ylidene)-1,3,4,6-tetrathiapentalene]: A New Organic Superconductor Possessing an Incommensurate Anion Lattice</title><title>Chemistry of materials</title><addtitle>Chem. Mater</addtitle><description>A selenium-containing TTF-type electron donor, MDT-TS [5H-2-(1,3-diselenol-2-ylidene)-1,3,4,6-tetrathiapentalene] was effectively synthesized by a two-step reaction and utilized for electrocrystallization with an AuI2 - anion. The resulting salt, (MDT-TS)(AuI2)0.441, has a unique crystal packing, in which the donor subcell and the anion lattice are incommensurate. Although the salt has relatively high conductivity at room temperature (600 S cm-1), it showed a metal−insulator (MI) transition at T MI = 50 K. Application of hydrostatic pressure suppressed the MI transition, and at 11.4 kbar (MDT-TS)(AuI2)0.441 showed a superconducting transition at T c = 4.7 K.</description><subject>Applied sciences</subject><subject>Chemistry</subject><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Physicochemistry of polymers</subject><subject>Physics</subject><issn>0897-4756</issn><issn>1520-5002</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNptkd-KEzEUxgdRsK5e-Aa5EVpo1mQmmUwFL0r9s5XqFmYEWZFwmmTWrNNMSTK79s5bH86X8ElMqewieJOQ7_zyne9wsuwpJaeU5PS52hI2o4zFe9mI8pxgTkh-PxuRaiYwE7x8mD0K4YoQmvBqlP1aexPC4A1eOj0oo1E97IxX_eEV7bWNe2QdGr9_1eCmnoznwzKfkFPGKPp80H7_-NnU6CXiZzjHYzotsLbBdMb1XRL2ndXGmQlOhSmbljia6CF-tbAzLkLCzJcXyQLN0Qdzg879JTir_onQe7TuQ0ghrbtE4NDSqX67NS6FhmjQ3NneoRXEaJV5nD1ooQvmyd_7JPv45nWzOMOr87fLxXyFoeAk4pwaYMWmbDWlHARvGWGiKDbFhlZQ5ukkQm2gJFzkGiqtgQADXc4UrygoXZxkk6Ov8imbN63cebsFv5eUyMMe5O0eEvvsyO4gKOhaD07ZcPehLMiMUJE4fORsiOb7bR38N1mKQnDZrGt5wetycSHeyU93vqCCvOoH79LE_-n_B-8to9c</recordid><startdate>20041130</startdate><enddate>20041130</enddate><creator>Takimiya, Kazuo</creator><creator>Kodani, Mie</creator><creator>Niihara, Naoto</creator><creator>Aso, Yoshio</creator><creator>Otsubo, Tetsuo</creator><creator>Bando, Yoshimasa</creator><creator>Kawamoto, Tadashi</creator><creator>Mori, Takehiko</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20041130</creationdate><title>Pressure-Induced Superconductivity in (MDT-TS)(AuI2)0.441 [MDT- TS = 5H-2-(1,3-diselenol-2-ylidene)-1,3,4,6-tetrathiapentalene]: A New Organic Superconductor Possessing an Incommensurate Anion Lattice</title><author>Takimiya, Kazuo ; Kodani, Mie ; Niihara, Naoto ; Aso, Yoshio ; Otsubo, Tetsuo ; Bando, Yoshimasa ; Kawamoto, Tadashi ; Mori, Takehiko</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a350t-21ea43b6fd115a75f404733b3b18a62b1807cba60572da8dda0a4ad69c581acd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Applied sciences</topic><topic>Chemistry</topic><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Physicochemistry of polymers</topic><topic>Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Takimiya, Kazuo</creatorcontrib><creatorcontrib>Kodani, Mie</creatorcontrib><creatorcontrib>Niihara, Naoto</creatorcontrib><creatorcontrib>Aso, Yoshio</creatorcontrib><creatorcontrib>Otsubo, Tetsuo</creatorcontrib><creatorcontrib>Bando, Yoshimasa</creatorcontrib><creatorcontrib>Kawamoto, Tadashi</creatorcontrib><creatorcontrib>Mori, Takehiko</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Chemistry of materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Takimiya, Kazuo</au><au>Kodani, Mie</au><au>Niihara, Naoto</au><au>Aso, Yoshio</au><au>Otsubo, Tetsuo</au><au>Bando, Yoshimasa</au><au>Kawamoto, Tadashi</au><au>Mori, Takehiko</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Pressure-Induced Superconductivity in (MDT-TS)(AuI2)0.441 [MDT- TS = 5H-2-(1,3-diselenol-2-ylidene)-1,3,4,6-tetrathiapentalene]: A New Organic Superconductor Possessing an Incommensurate Anion Lattice</atitle><jtitle>Chemistry of materials</jtitle><addtitle>Chem. Mater</addtitle><date>2004-11-30</date><risdate>2004</risdate><volume>16</volume><issue>24</issue><spage>5120</spage><epage>5123</epage><pages>5120-5123</pages><issn>0897-4756</issn><eissn>1520-5002</eissn><abstract>A selenium-containing TTF-type electron donor, MDT-TS [5H-2-(1,3-diselenol-2-ylidene)-1,3,4,6-tetrathiapentalene] was effectively synthesized by a two-step reaction and utilized for electrocrystallization with an AuI2 - anion. The resulting salt, (MDT-TS)(AuI2)0.441, has a unique crystal packing, in which the donor subcell and the anion lattice are incommensurate. Although the salt has relatively high conductivity at room temperature (600 S cm-1), it showed a metal−insulator (MI) transition at T MI = 50 K. Application of hydrostatic pressure suppressed the MI transition, and at 11.4 kbar (MDT-TS)(AuI2)0.441 showed a superconducting transition at T c = 4.7 K.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/cm049144t</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0897-4756 |
| ispartof | Chemistry of materials, 2004-11, Vol.16 (24), p.5120-5123 |
| issn | 0897-4756 1520-5002 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_cm049144t |
| source | ACS Publications |
| subjects | Applied sciences Chemistry Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Exact sciences and technology General and physical chemistry Physicochemistry of polymers Physics |
| title | Pressure-Induced Superconductivity in (MDT-TS)(AuI2)0.441 [MDT- TS = 5H-2-(1,3-diselenol-2-ylidene)-1,3,4,6-tetrathiapentalene]: A New Organic Superconductor Possessing an Incommensurate Anion Lattice |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-21T14%3A26%3A09IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Pressure-Induced%20Superconductivity%20in%20(MDT-TS)(AuI2)0.441%20%5BMDT-%E2%80%89TS%20=%205H-2-(1,3-diselenol-2-ylidene)-1,3,4,6-tetrathiapentalene%5D:%E2%80%89%20A%20New%20Organic%20Superconductor%20Possessing%20an%20Incommensurate%20Anion%20Lattice&rft.jtitle=Chemistry%20of%20materials&rft.au=Takimiya,%20Kazuo&rft.date=2004-11-30&rft.volume=16&rft.issue=24&rft.spage=5120&rft.epage=5123&rft.pages=5120-5123&rft.issn=0897-4756&rft.eissn=1520-5002&rft_id=info:doi/10.1021/cm049144t&rft_dat=%3Cacs_cross%3Ec418556081%3C/acs_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |