Single-Source Precursor Route for the Synthesis of EuS Nanocrystals

A single-source precursor synthetic route for the preparation of colloidal EuS nanocrystals is reported. By varying the decomposition conditions of the lanthanide complex, cube-, sphere-, or polygon-shaped nanocrystals with good colloidal stability are prepared. Size control is not achieved. It is d...

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Veröffentlicht in:Chemistry of materials 2005-06, Vol.17 (13), p.3451-3456
Hauptverfasser: Mirkovic, Tihana, Hines, Margaret A, Nair, P. Sreekumari, Scholes, Gregory D
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container_title Chemistry of materials
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creator Mirkovic, Tihana
Hines, Margaret A
Nair, P. Sreekumari
Scholes, Gregory D
description A single-source precursor synthetic route for the preparation of colloidal EuS nanocrystals is reported. By varying the decomposition conditions of the lanthanide complex, cube-, sphere-, or polygon-shaped nanocrystals with good colloidal stability are prepared. Size control is not achieved. It is demonstrated that chelating ligands incorporated into the precursor, for example, 1,10-phenanthroline and 2,2‘-bipyridine, are integrated, together with the stabilizing ligands trioctylphosphine and oleylamine, onto the nanocrystal surface.
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