Synthesis of One Monolayer of Hexagonal Boron Nitride on Ni(111) from B-Trichloroborazine (ClBNH)3
Single-layer h-BN films may be grown on Ni(111) by using B-trichloroborazine (ClBNH)3. Scanning tunneling microscopy shows perfect monolayers with a very low density of defects. This way of producing stoichiometric, ultimately thin h-BN layers is an alternate route to the use of borazine (HBNH)3. Th...
Gespeichert in:
| Veröffentlicht in: | Chemistry of materials 2004-01, Vol.16 (2), p.343-345 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 345 |
|---|---|
| container_issue | 2 |
| container_start_page | 343 |
| container_title | Chemistry of materials |
| container_volume | 16 |
| creator | Auwärter, Willi Suter, Hans Ulrich Sachdev, Hermann Greber, Thomas |
| description | Single-layer h-BN films may be grown on Ni(111) by using B-trichloroborazine (ClBNH)3. Scanning tunneling microscopy shows perfect monolayers with a very low density of defects. This way of producing stoichiometric, ultimately thin h-BN layers is an alternate route to the use of borazine (HBNH)3. The h-BN growth patterns indicate a reaction mechanism that proceeds via six-membered ring opening of these cyclic BN molecules. A set of density functional calculations for B-trichloroborazine, borazine, and N-trichloroborazine yields bond energies and bond lengths for these molecules. |
| doi_str_mv | 10.1021/cm034805s |
| format | Article |
| fullrecord | <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_cm034805s</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>b053695265</sourcerecordid><originalsourceid>FETCH-LOGICAL-a393t-792023be71058845121aaaad29a46c6441178d3f9d1c5bebe8c819c952a67a633</originalsourceid><addsrcrecordid>eNptkEFPAjEQhRujiYge_Ad7MYHDaqfd7naPggImCETw3HS7XSkuW9KuCfjrXcTAxbnM5M03b5KH0C3ge8AEHtQa04hj5s9QCxjBIcOYnKMW5mkSRgmLL9GV9yuMocF5C2XzXVUvtTc-sEUwrXTwaitbyp12e2Gkt_LDVrIMetbZKpiY2plcB79jBwC6QeHsOuiFC2fUsmygzDr5bRqjTr_sTUZdeo0uCll6ffPX2-h98Lzoj8LxdPjSfxyHkqa0DpOUYEIznQBmnEcMCMimcpLKKFZxFAEkPKdFmoNimc40VxxSlTIi40TGlLZR9-CrnPXe6UJsnFlLtxOAxT4ccQynYe8O7EZ6JcvCyUoZfzpgEaScsIYLD5zxtd4e99J9ijihCROL2VyQt2HMZ4O5eDr5SuXFyn65Jjr_z_8fN2F87Q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Synthesis of One Monolayer of Hexagonal Boron Nitride on Ni(111) from B-Trichloroborazine (ClBNH)3</title><source>ACS Publications</source><creator>Auwärter, Willi ; Suter, Hans Ulrich ; Sachdev, Hermann ; Greber, Thomas</creator><creatorcontrib>Auwärter, Willi ; Suter, Hans Ulrich ; Sachdev, Hermann ; Greber, Thomas</creatorcontrib><description>Single-layer h-BN films may be grown on Ni(111) by using B-trichloroborazine (ClBNH)3. Scanning tunneling microscopy shows perfect monolayers with a very low density of defects. This way of producing stoichiometric, ultimately thin h-BN layers is an alternate route to the use of borazine (HBNH)3. The h-BN growth patterns indicate a reaction mechanism that proceeds via six-membered ring opening of these cyclic BN molecules. A set of density functional calculations for B-trichloroborazine, borazine, and N-trichloroborazine yields bond energies and bond lengths for these molecules.</description><identifier>ISSN: 0897-4756</identifier><identifier>EISSN: 1520-5002</identifier><identifier>DOI: 10.1021/cm034805s</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Applied sciences ; Chemistry ; Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Condensed matter: structure, mechanical and thermal properties ; Exact sciences and technology ; General and physical chemistry ; Physicochemistry of polymers ; Physics</subject><ispartof>Chemistry of materials, 2004-01, Vol.16 (2), p.343-345</ispartof><rights>Copyright © 2004 American Chemical Society</rights><rights>2004 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a393t-792023be71058845121aaaad29a46c6441178d3f9d1c5bebe8c819c952a67a633</citedby><cites>FETCH-LOGICAL-a393t-792023be71058845121aaaad29a46c6441178d3f9d1c5bebe8c819c952a67a633</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/cm034805s$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/cm034805s$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=15419825$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Auwärter, Willi</creatorcontrib><creatorcontrib>Suter, Hans Ulrich</creatorcontrib><creatorcontrib>Sachdev, Hermann</creatorcontrib><creatorcontrib>Greber, Thomas</creatorcontrib><title>Synthesis of One Monolayer of Hexagonal Boron Nitride on Ni(111) from B-Trichloroborazine (ClBNH)3</title><title>Chemistry of materials</title><addtitle>Chem. Mater</addtitle><description>Single-layer h-BN films may be grown on Ni(111) by using B-trichloroborazine (ClBNH)3. Scanning tunneling microscopy shows perfect monolayers with a very low density of defects. This way of producing stoichiometric, ultimately thin h-BN layers is an alternate route to the use of borazine (HBNH)3. The h-BN growth patterns indicate a reaction mechanism that proceeds via six-membered ring opening of these cyclic BN molecules. A set of density functional calculations for B-trichloroborazine, borazine, and N-trichloroborazine yields bond energies and bond lengths for these molecules.</description><subject>Applied sciences</subject><subject>Chemistry</subject><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Physicochemistry of polymers</subject><subject>Physics</subject><issn>0897-4756</issn><issn>1520-5002</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNptkEFPAjEQhRujiYge_Ad7MYHDaqfd7naPggImCETw3HS7XSkuW9KuCfjrXcTAxbnM5M03b5KH0C3ge8AEHtQa04hj5s9QCxjBIcOYnKMW5mkSRgmLL9GV9yuMocF5C2XzXVUvtTc-sEUwrXTwaitbyp12e2Gkt_LDVrIMetbZKpiY2plcB79jBwC6QeHsOuiFC2fUsmygzDr5bRqjTr_sTUZdeo0uCll6ffPX2-h98Lzoj8LxdPjSfxyHkqa0DpOUYEIznQBmnEcMCMimcpLKKFZxFAEkPKdFmoNimc40VxxSlTIi40TGlLZR9-CrnPXe6UJsnFlLtxOAxT4ccQynYe8O7EZ6JcvCyUoZfzpgEaScsIYLD5zxtd4e99J9ijihCROL2VyQt2HMZ4O5eDr5SuXFyn65Jjr_z_8fN2F87Q</recordid><startdate>20040127</startdate><enddate>20040127</enddate><creator>Auwärter, Willi</creator><creator>Suter, Hans Ulrich</creator><creator>Sachdev, Hermann</creator><creator>Greber, Thomas</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20040127</creationdate><title>Synthesis of One Monolayer of Hexagonal Boron Nitride on Ni(111) from B-Trichloroborazine (ClBNH)3</title><author>Auwärter, Willi ; Suter, Hans Ulrich ; Sachdev, Hermann ; Greber, Thomas</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a393t-792023be71058845121aaaad29a46c6441178d3f9d1c5bebe8c819c952a67a633</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Applied sciences</topic><topic>Chemistry</topic><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Physicochemistry of polymers</topic><topic>Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Auwärter, Willi</creatorcontrib><creatorcontrib>Suter, Hans Ulrich</creatorcontrib><creatorcontrib>Sachdev, Hermann</creatorcontrib><creatorcontrib>Greber, Thomas</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Chemistry of materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Auwärter, Willi</au><au>Suter, Hans Ulrich</au><au>Sachdev, Hermann</au><au>Greber, Thomas</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of One Monolayer of Hexagonal Boron Nitride on Ni(111) from B-Trichloroborazine (ClBNH)3</atitle><jtitle>Chemistry of materials</jtitle><addtitle>Chem. Mater</addtitle><date>2004-01-27</date><risdate>2004</risdate><volume>16</volume><issue>2</issue><spage>343</spage><epage>345</epage><pages>343-345</pages><issn>0897-4756</issn><eissn>1520-5002</eissn><abstract>Single-layer h-BN films may be grown on Ni(111) by using B-trichloroborazine (ClBNH)3. Scanning tunneling microscopy shows perfect monolayers with a very low density of defects. This way of producing stoichiometric, ultimately thin h-BN layers is an alternate route to the use of borazine (HBNH)3. The h-BN growth patterns indicate a reaction mechanism that proceeds via six-membered ring opening of these cyclic BN molecules. A set of density functional calculations for B-trichloroborazine, borazine, and N-trichloroborazine yields bond energies and bond lengths for these molecules.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/cm034805s</doi><tpages>3</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0897-4756 |
| ispartof | Chemistry of materials, 2004-01, Vol.16 (2), p.343-345 |
| issn | 0897-4756 1520-5002 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_cm034805s |
| source | ACS Publications |
| subjects | Applied sciences Chemistry Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Exact sciences and technology General and physical chemistry Physicochemistry of polymers Physics |
| title | Synthesis of One Monolayer of Hexagonal Boron Nitride on Ni(111) from B-Trichloroborazine (ClBNH)3 |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-11T07%3A19%3A55IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20of%20One%20Monolayer%20of%20Hexagonal%20Boron%20Nitride%20on%20Ni(111)%20from%20B-Trichloroborazine%20(ClBNH)3&rft.jtitle=Chemistry%20of%20materials&rft.au=Auw%C3%A4rter,%20Willi&rft.date=2004-01-27&rft.volume=16&rft.issue=2&rft.spage=343&rft.epage=345&rft.pages=343-345&rft.issn=0897-4756&rft.eissn=1520-5002&rft_id=info:doi/10.1021/cm034805s&rft_dat=%3Cacs_cross%3Eb053695265%3C/acs_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |