Triglyme−Li+ Cation Solvate Structures:  Models for Amorphous Concentrated Liquid and Polymer Electrolytes (I)

Triglyme−Li+ Cation Solvate Structures:  Models for Amorphous Concentrated Liquid and Polymer Electrolytes (I)

Crystalline phases of (triglyme)1:LiX (X = CF3SO3 -, BF4 -, ClO4 -, and AsF6 -) have been isolated and structurally characterized. The phases are isostructural and represent a novel form of Li+ cation coordination not observed in crystalline poly(ethylene oxide) (PEO)−salt phases. The crystal struct...

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Veröffentlicht in:Chemistry of materials 2003-12, Vol.15 (24), p.4679-4684
Hauptverfasser: Henderson, Wesley A, Brooks, Neil R, Brennessel, William W, Young, Victor G
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Sprache:eng
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Chemistry
Electrochemistry
Exact sciences and technology
General and physical chemistry
Properties of electrolytes: conductivity
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container_issue 24
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container_title Chemistry of materials
container_volume 15
creator Henderson, Wesley A
Brooks, Neil R
Brennessel, William W
Young, Victor G
description Crystalline phases of (triglyme)1:LiX (X = CF3SO3 -, BF4 -, ClO4 -, and AsF6 -) have been isolated and structurally characterized. The phases are isostructural and represent a novel form of Li+ cation coordination not observed in crystalline poly(ethylene oxide) (PEO)−salt phases. The crystal structure of a (triglyme)1:LiBPh4 phase has also been determined, which differs markedly from those found with the smaller anions. In addition, a more concentrated (triglyme)2/3:LiCF3SO3 phase has been characterized, which also displays a novel form of Li+ cation coordination. Such solvates represent models for interchain cation transport transition states in concentrated liquid and amorphous PEO electrolytes.
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subjects Chemistry
Electrochemistry
Exact sciences and technology
General and physical chemistry
Properties of electrolytes: conductivity
title Triglyme−Li+ Cation Solvate Structures:  Models for Amorphous Concentrated Liquid and Polymer Electrolytes (I)
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