Preparation and Characterization of Intercalation Compounds of Layered Double Hydroxides with Metallic Oxalato Complexes
Intercalation of metallic oxalato complexes CoOx2 2-, CuOx2 2-, MnOx3 3-, and GaOx3 3- in [Zn2Al] and [Mg2Al] LDHs was successfully carried out leading to well characterized products in which metallic complexes lying between layers were subjected to minor modifications following intercalation as con...
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| Veröffentlicht in: | Chemistry of materials 2004-03, Vol.16 (5), p.935-945 |
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| container_title | Chemistry of materials |
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| creator | Beaudot, Philippe De Roy, Marie Elisabeth Besse, Jean Pierre |
| description | Intercalation of metallic oxalato complexes CoOx2 2-, CuOx2 2-, MnOx3 3-, and GaOx3 3- in [Zn2Al] and [Mg2Al] LDHs was successfully carried out leading to well characterized products in which metallic complexes lying between layers were subjected to minor modifications following intercalation as confirmed by XRD, FTIR, and particularly XAFS studies. The obtained data permitted modeling the layout of metallic oxalato complexes between the layers for each compound. Thermal treatments undertaken on exchanged compounds led to a mixing of oxides with increase in surface areas particularly for the Ga-containing product. Dispersed oxide and metallic particules were obtained by a soft chemistry treatment in refluxing ethylene glycol. |
| doi_str_mv | 10.1021/cm0311067 |
| format | Article |
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The obtained data permitted modeling the layout of metallic oxalato complexes between the layers for each compound. Thermal treatments undertaken on exchanged compounds led to a mixing of oxides with increase in surface areas particularly for the Ga-containing product. 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Dispersed oxide and metallic particules were obtained by a soft chemistry treatment in refluxing ethylene glycol.</description><subject>Applied sciences</subject><subject>Chemistry</subject><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Physicochemistry of polymers</subject><subject>Physics</subject><issn>0897-4756</issn><issn>1520-5002</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNptkEtPwzAQhC0EEqVw4B_kwoFDwI84jyMKlFYEtYhytjaOo6akcWSnIuXX4xLUXjhZu_PNWLMIXRN8RzAl93KDGSE4jE7QiHCKfY4xPUUjHCeRH0Q8PEcX1q4xdhCNR6hfGNWCga7SjQdN4aUrN8lOmep7WOrSmzVullAPi1RvWr1tCruXMtgpowrvUW_zWnnTXWF0XxXKel9Vt_JeVQd1XUlv3u_t-tdcq17ZS3RWQm3V1d87Rh-Tp2U69bP58yx9yHxglHd-UhZhWEaKFAXQCPJSAqeUuYY5S0DmhMUUwpwnTDmV4CCBksucsZwESUJyNka3Q6402lqjStGaagNmJwgW-5OJw8kcezOwLVhXtzTQyMoeDZwHYUxCx_kDV9lO9QcdzKdwKREXy8W7IC-TtykJqMiOuSCtWOutaVzjf_7_AdQMiHQ</recordid><startdate>20040309</startdate><enddate>20040309</enddate><creator>Beaudot, Philippe</creator><creator>De Roy, Marie Elisabeth</creator><creator>Besse, Jean Pierre</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20040309</creationdate><title>Preparation and Characterization of Intercalation Compounds of Layered Double Hydroxides with Metallic Oxalato Complexes</title><author>Beaudot, Philippe ; De Roy, Marie Elisabeth ; Besse, Jean Pierre</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a325t-9fd66f7e1dda27abfca5223106b39acb1382a6b593e7ab1049af5cb33b14991b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Applied sciences</topic><topic>Chemistry</topic><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Physicochemistry of polymers</topic><topic>Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Beaudot, Philippe</creatorcontrib><creatorcontrib>De Roy, Marie Elisabeth</creatorcontrib><creatorcontrib>Besse, Jean Pierre</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Chemistry of materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Beaudot, Philippe</au><au>De Roy, Marie Elisabeth</au><au>Besse, Jean Pierre</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation and Characterization of Intercalation Compounds of Layered Double Hydroxides with Metallic Oxalato Complexes</atitle><jtitle>Chemistry of materials</jtitle><addtitle>Chem. 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| source | ACS Publications |
| subjects | Applied sciences Chemistry Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Exact sciences and technology General and physical chemistry Physicochemistry of polymers Physics |
| title | Preparation and Characterization of Intercalation Compounds of Layered Double Hydroxides with Metallic Oxalato Complexes |
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