Synthesis of Comb Polysiloxane Polyelectrolytes Containing Oligoether and Perfluoroether Side Chains

Synthesis of Comb Polysiloxane Polyelectrolytes Containing Oligoether and Perfluoroether Side Chains

Comb polyelectrolytes consisting of a polysiloxane backbone with tetraglyme and lithium-sulfonate terminated perfluoroether side chains have been synthesized. Both types of side chains were independently prepared with allyl functionality and attached to poly(methylhydrosiloxane) by hydrosilylation....

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Veröffentlicht in:Chemistry of materials 2003-11, Vol.15 (22), p.4223-4230
Hauptverfasser: Snyder, J. F, Hutchison, J. C, Ratner, M. A, Shriver, D. F
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Sprache:eng
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Applied sciences
Exact sciences and technology
Inorganic and organomineral polymers
Physicochemistry of polymers
Preparation
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container_issue 22
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container_title Chemistry of materials
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creator Snyder, J. F
Hutchison, J. C
Ratner, M. A
Shriver, D. F
description Comb polyelectrolytes consisting of a polysiloxane backbone with tetraglyme and lithium-sulfonate terminated perfluoroether side chains have been synthesized. Both types of side chains were independently prepared with allyl functionality and attached to poly(methylhydrosiloxane) by hydrosilylation. Several methods are described to form lithium sulfonate from sulfonate esters. Spectroscopic and thermal characterizations of the resulting polyelectrolyte are described.
doi_str_mv 10.1021/cm0217396
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subjects Applied sciences
Exact sciences and technology
Inorganic and organomineral polymers
Physicochemistry of polymers
Preparation
title Synthesis of Comb Polysiloxane Polyelectrolytes Containing Oligoether and Perfluoroether Side Chains
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