Existence of metal-ammonia solvation complexes in lamellar titanium disulfide

The relatively weak forces binding the layers of the lamellar transition metal disulfides (TS{sub 2}) make them logical choices for the investigation of solvation chemistry in two dimensions. A wide variety of solvation-cation intercalation compounds of these materials have been investigated. The au...

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Veröffentlicht in:	Chemistry of materials 1991-01, Vol.3 (1), p.17-19
Hauptverfasser:	Ong, E. W, McKelvy, M. J, Dotson, L. A, Glaunsinger, W. S
Format:	Artikel
Sprache:	eng
Schlagworte:	400201 - Chemical & Physicochemical Properties AMMONIUM COMPLEXES CALORIMETRY CHALCOGENIDES CHEMICAL ANALYSIS COMPLEXES DATA EXPERIMENTAL DATA GRAVIMETRIC ANALYSIS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MEASURING METHODS NUMERICAL DATA QUANTITATIVE CHEMICAL ANALYSIS SOLVATION SULFIDES SULFUR COMPOUNDS THERMAL ANALYSIS THERMAL GRAVIMETRIC ANALYSIS TITANIUM COMPOUNDS TITANIUM SULFIDES TRANSITION ELEMENT COMPOUNDS
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container_title	Chemistry of materials
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creator	Ong, E. W McKelvy, M. J Dotson, L. A Glaunsinger, W. S
description	The relatively weak forces binding the layers of the lamellar transition metal disulfides (TS{sub 2}) make them logical choices for the investigation of solvation chemistry in two dimensions. A wide variety of solvation-cation intercalation compounds of these materials have been investigated. The authors report the first evidence for intercalated metal-ammonia solvation complexes for divalent and trivalent metals. Discrete solvent-to-metal coordination numbers of two, three, and possibly six, as well as coordination transitions, have been identified by thermal analysis of TiS{sub 2} intercalation compounds.
doi_str_mv	10.1021/cm00013a008
format	Article
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Mater</addtitle><date>1991-01-01</date><risdate>1991</risdate><volume>3</volume><issue>1</issue><spage>17</spage><epage>19</epage><pages>17-19</pages><issn>0897-4756</issn><eissn>1520-5002</eissn><abstract>The relatively weak forces binding the layers of the lamellar transition metal disulfides (TS{sub 2}) make them logical choices for the investigation of solvation chemistry in two dimensions. A wide variety of solvation-cation intercalation compounds of these materials have been investigated. The authors report the first evidence for intercalated metal-ammonia solvation complexes for divalent and trivalent metals. Discrete solvent-to-metal coordination numbers of two, three, and possibly six, as well as coordination transitions, have been identified by thermal analysis of TiS{sub 2} intercalation compounds.</abstract><cop>United States</cop><pub>American Chemical Society</pub><doi>10.1021/cm00013a008</doi><tpages>3</tpages></addata></record>
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subjects	400201 - Chemical & Physicochemical Properties AMMONIUM COMPLEXES CALORIMETRY CHALCOGENIDES CHEMICAL ANALYSIS COMPLEXES DATA EXPERIMENTAL DATA GRAVIMETRIC ANALYSIS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MEASURING METHODS NUMERICAL DATA QUANTITATIVE CHEMICAL ANALYSIS SOLVATION SULFIDES SULFUR COMPOUNDS THERMAL ANALYSIS THERMAL GRAVIMETRIC ANALYSIS TITANIUM COMPOUNDS TITANIUM SULFIDES TRANSITION ELEMENT COMPOUNDS
title	Existence of metal-ammonia solvation complexes in lamellar titanium disulfide
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