Steric Control over Supramolecular Polymer Formation in trans-1,2-Bis(4-pyridyl)ethylene Adducts of Zinc Xanthates: Implications for Luminescence

Steric control over supramolecular aggregation is demonstrated for a series of adducts formed between Zn(S2COR)2 and trans-1,2-bis(4-pyridyl)ethylene, whereby supramolecular zigzag polymers are found when R is small, that is, Et (1) and n-Bu (2), but only bimetallic aggregates could be formed when R...

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Veröffentlicht in:Crystal growth & design 2010-03, Vol.10 (3), p.1247-1256
Hauptverfasser: Kang, Jun-Gill, Shin, Jung-Sik, Cho, Dong-Hee, Jeong, Yong-Kwang, Park, Changmoon, Soh, Shu Fang, Lai, Chian Sing, Tiekink, Edward R. T
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Sprache:eng
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