Spontaneous Assembly of d−f Coordination Frameworks: Syntheses, Structures, and Photoluminescence
A series of new d−f heterometallic coordination frameworks, namely, [LnM(Hbic)2(ox)H2O]·2H2O [Ln = Nd, M = Cu (1); Ln = Eu, M = Ag (2); Ln = Tb, M = Ag (3); H2bic = 1H-benzimidazole-5-carboxylic acid; ox = oxalate] for type I, [LnCu(Hbic)3(ox)0.5]·H2O [Ln = Sm (4), Ln = Dy (5)] for type II, and [LnA...
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| Veröffentlicht in: | Crystal growth & design 2010-01, Vol.10 (1), p.114-121 |
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| creator | Peng, Guo Qiu, Yong-Cai Liu, Zhi-Hui Liu, Biao Deng, Hong |
| description | A series of new d−f heterometallic coordination frameworks, namely, [LnM(Hbic)2(ox)H2O]·2H2O [Ln = Nd, M = Cu (1); Ln = Eu, M = Ag (2); Ln = Tb, M = Ag (3); H2bic = 1H-benzimidazole-5-carboxylic acid; ox = oxalate] for type I, [LnCu(Hbic)3(ox)0.5]·H2O [Ln = Sm (4), Ln = Dy (5)] for type II, and [LnAg(Hbic)(ox)1.5] [Ln = Eu (6)] for type III, were successfully synthesized by using different metal salts and rationally controlling reaction temperature. Complexes 1−3 represent 1D polymeric chain architectures that are constructed from the connections between lanthanide-oxalate chains and M(Hbic)2 subunits. Complexes 4 and 5 are 2D layered structures which are assembled by lanthanide-oxalate and Cu(Hbic)3 units. Complex 6 exhibits another 2D layered coordination framework that is built up by tetranuclear Eu2Ag2 clusters and mixed ox and Hbic linkers. The polymeric coordination frameworks of complexes 1−6 are sustained by both hydrogen bonding and π−π stacking interactions, and they are self-assembled to form the 3D supramolecular frameworks. |
| doi_str_mv | 10.1021/cg900571v |
| format | Article |
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Complexes 1−3 represent 1D polymeric chain architectures that are constructed from the connections between lanthanide-oxalate chains and M(Hbic)2 subunits. Complexes 4 and 5 are 2D layered structures which are assembled by lanthanide-oxalate and Cu(Hbic)3 units. Complex 6 exhibits another 2D layered coordination framework that is built up by tetranuclear Eu2Ag2 clusters and mixed ox and Hbic linkers. The polymeric coordination frameworks of complexes 1−6 are sustained by both hydrogen bonding and π−π stacking interactions, and they are self-assembled to form the 3D supramolecular frameworks.</description><identifier>ISSN: 1528-7483</identifier><identifier>EISSN: 1528-7505</identifier><identifier>DOI: 10.1021/cg900571v</identifier><language>eng</language><publisher>Washington,DC: American Chemical Society</publisher><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Condensed matter: structure, mechanical and thermal properties ; Cross-disciplinary physics: materials science; rheology ; Exact sciences and technology ; Materials science ; Methods of nanofabrication ; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation ; Organic compounds ; Photoluminescence ; Physics ; Self-assembly ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids</subject><ispartof>Crystal growth & design, 2010-01, Vol.10 (1), p.114-121</ispartof><rights>Copyright © 2009 American Chemical Society</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a355t-dd075705d2003281ec082f2149b74b4c18138c20b1af73b627e895339fa774053</citedby><cites>FETCH-LOGICAL-a355t-dd075705d2003281ec082f2149b74b4c18138c20b1af73b627e895339fa774053</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/cg900571v$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/cg900571v$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2763,27075,27923,27924,56737,56787</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22362675$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Peng, Guo</creatorcontrib><creatorcontrib>Qiu, Yong-Cai</creatorcontrib><creatorcontrib>Liu, Zhi-Hui</creatorcontrib><creatorcontrib>Liu, Biao</creatorcontrib><creatorcontrib>Deng, Hong</creatorcontrib><title>Spontaneous Assembly of d−f Coordination Frameworks: Syntheses, Structures, and Photoluminescence</title><title>Crystal growth & design</title><addtitle>Cryst. Growth Des</addtitle><description>A series of new d−f heterometallic coordination frameworks, namely, [LnM(Hbic)2(ox)H2O]·2H2O [Ln = Nd, M = Cu (1); Ln = Eu, M = Ag (2); Ln = Tb, M = Ag (3); H2bic = 1H-benzimidazole-5-carboxylic acid; ox = oxalate] for type I, [LnCu(Hbic)3(ox)0.5]·H2O [Ln = Sm (4), Ln = Dy (5)] for type II, and [LnAg(Hbic)(ox)1.5] [Ln = Eu (6)] for type III, were successfully synthesized by using different metal salts and rationally controlling reaction temperature. Complexes 1−3 represent 1D polymeric chain architectures that are constructed from the connections between lanthanide-oxalate chains and M(Hbic)2 subunits. Complexes 4 and 5 are 2D layered structures which are assembled by lanthanide-oxalate and Cu(Hbic)3 units. Complex 6 exhibits another 2D layered coordination framework that is built up by tetranuclear Eu2Ag2 clusters and mixed ox and Hbic linkers. The polymeric coordination frameworks of complexes 1−6 are sustained by both hydrogen bonding and π−π stacking interactions, and they are self-assembled to form the 3D supramolecular frameworks.</description><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Exact sciences and technology</subject><subject>Materials science</subject><subject>Methods of nanofabrication</subject><subject>Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation</subject><subject>Organic compounds</subject><subject>Photoluminescence</subject><subject>Physics</subject><subject>Self-assembly</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><issn>1528-7483</issn><issn>1528-7505</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNptkLFOwzAYhC0EEqUw8AZeGJAI_LbjOGGrKgpIlUAqzJHj2DQlsSvbAfUNmHlEnoRWhbIw3Q3fnXSH0CmBSwKUXKmXAoAL8raHBoTTPBEc-P6vT3N2iI5CWACAyBgbIDVbOhul1a4PeBSC7qp2hZ3B9dfHp8Fj53zdWBkbZ_HEy06_O_8arvFsZeNcBx0u8Cz6XsXeb7y0NX6cu-javmusDkpbpY_RgZFt0Cc_OkTPk5un8V0yfbi9H4-miWScx6SuQXABvKYAjOZEK8ipoSQtKpFWqSI5YbmiUBFpBKsyKnRecMYKI4VIgbMhOt_2Ku9C8NqUS9900q9KAuXmnXL3zpo927JLGZRsjZdWNWEXoJRlNBP8j5MqlAvXe7te8E_fN5Udcaw</recordid><startdate>20100106</startdate><enddate>20100106</enddate><creator>Peng, Guo</creator><creator>Qiu, Yong-Cai</creator><creator>Liu, Zhi-Hui</creator><creator>Liu, Biao</creator><creator>Deng, Hong</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20100106</creationdate><title>Spontaneous Assembly of d−f Coordination Frameworks: Syntheses, Structures, and Photoluminescence</title><author>Peng, Guo ; Qiu, Yong-Cai ; Liu, Zhi-Hui ; Liu, Biao ; Deng, Hong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a355t-dd075705d2003281ec082f2149b74b4c18138c20b1af73b627e895339fa774053</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Exact sciences and technology</topic><topic>Materials science</topic><topic>Methods of nanofabrication</topic><topic>Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation</topic><topic>Organic compounds</topic><topic>Photoluminescence</topic><topic>Physics</topic><topic>Self-assembly</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Peng, Guo</creatorcontrib><creatorcontrib>Qiu, Yong-Cai</creatorcontrib><creatorcontrib>Liu, Zhi-Hui</creatorcontrib><creatorcontrib>Liu, Biao</creatorcontrib><creatorcontrib>Deng, Hong</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Crystal growth & design</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Peng, Guo</au><au>Qiu, Yong-Cai</au><au>Liu, Zhi-Hui</au><au>Liu, Biao</au><au>Deng, Hong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Spontaneous Assembly of d−f Coordination Frameworks: Syntheses, Structures, and Photoluminescence</atitle><jtitle>Crystal growth & design</jtitle><addtitle>Cryst. Growth Des</addtitle><date>2010-01-06</date><risdate>2010</risdate><volume>10</volume><issue>1</issue><spage>114</spage><epage>121</epage><pages>114-121</pages><issn>1528-7483</issn><eissn>1528-7505</eissn><abstract>A series of new d−f heterometallic coordination frameworks, namely, [LnM(Hbic)2(ox)H2O]·2H2O [Ln = Nd, M = Cu (1); Ln = Eu, M = Ag (2); Ln = Tb, M = Ag (3); H2bic = 1H-benzimidazole-5-carboxylic acid; ox = oxalate] for type I, [LnCu(Hbic)3(ox)0.5]·H2O [Ln = Sm (4), Ln = Dy (5)] for type II, and [LnAg(Hbic)(ox)1.5] [Ln = Eu (6)] for type III, were successfully synthesized by using different metal salts and rationally controlling reaction temperature. Complexes 1−3 represent 1D polymeric chain architectures that are constructed from the connections between lanthanide-oxalate chains and M(Hbic)2 subunits. Complexes 4 and 5 are 2D layered structures which are assembled by lanthanide-oxalate and Cu(Hbic)3 units. Complex 6 exhibits another 2D layered coordination framework that is built up by tetranuclear Eu2Ag2 clusters and mixed ox and Hbic linkers. The polymeric coordination frameworks of complexes 1−6 are sustained by both hydrogen bonding and π−π stacking interactions, and they are self-assembled to form the 3D supramolecular frameworks.</abstract><cop>Washington,DC</cop><pub>American Chemical Society</pub><doi>10.1021/cg900571v</doi><tpages>8</tpages></addata></record> |
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| subjects | Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science rheology Exact sciences and technology Materials science Methods of nanofabrication Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation Organic compounds Photoluminescence Physics Self-assembly Structure of solids and liquids crystallography Structure of specific crystalline solids |
| title | Spontaneous Assembly of d−f Coordination Frameworks: Syntheses, Structures, and Photoluminescence |
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