Solvothermal Syntheses of Two Novel Layered Quaternary Silver−Antimony(III) Sulfides with Different Strategies

Two new silver antimony sulfides, KAg2SbS3 (1) and K2Ag3Sb3S7 (2), have been synthesized solvothermally in the presence of thiophenol as a mineralizer. Compound 1 contains a hexagonal net formed by condensation of Ag2SbS3 six-membered rings. These sheets are linked through Ag−S bonds to obtain doubl...

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Veröffentlicht in:Crystal growth & design 2009-09, Vol.9 (9), p.3821-3824
Hauptverfasser: Yao, Hua-Gang, Ji, Min, Ji, Shou-Hua, Zhang, Ren-Chun, An, Yong-Lin, Ning, Gui-ling
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Sprache:eng
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