Di-, Tetra-, and Hexanuclear Hydroxy-Bridged Copper(II) Cluster Compounds: Syntheses, Structures, and Properties
Self-assembly reactions of copper (II) ions, dicarboxylate (adipate or terephthalate) and terminal ligands (4,4′-bipyridine or phenanthroline) yielded three hydroxy-bridged Cu(II) cluster complexes: [Cu(phen)(OH)(H2O)]2·(C8H4O4)·8H2O (1), [Cu4(bpy)4(OH)4(H2O)2]·(C8H4O4)2·6H2O (2) and [Cu6(bpy)6(OH)6...
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| Veröffentlicht in: | Crystal growth & design 2008-08, Vol.8 (8), p.2853-2861 |
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| creator | Li, Xing Cheng, Deyi Lin, Jianli Li, Zhifeng Zheng, Yueqing |
| description | Self-assembly reactions of copper (II) ions, dicarboxylate (adipate or terephthalate) and terminal ligands (4,4′-bipyridine or phenanthroline) yielded three hydroxy-bridged Cu(II) cluster complexes: [Cu(phen)(OH)(H2O)]2·(C8H4O4)·8H2O (1), [Cu4(bpy)4(OH)4(H2O)2]·(C8H4O4)2·6H2O (2) and [Cu6(bpy)6(OH)6(H2O)2]·(C6H8O4)3·23H2O (3) (phen = phenanthroline, bpy = 2,2′-bipyridine, C8H6O4 = terephthalic acid, C6H10O4 = adipic acid). Single crystal X-ray diffraction analyses reveal that complex 1 is a discrete dinuclear Cu2O2 motif, 2 presents a discrete chairlike tetranuclear copper(II) Cu4O4 core formed by two Cu2O2 units, and 3 assumes a discrete hexameric copper(II) Cu6O6 cluster consisting of three Cu2O2 units. The polynuclear structures are generated from the Cu(II) ions linked by the µ2- and/or µ3-OH groups. In 1−3, all Cu(II) ions show square pyramidal coordination geometry, and the dicarboxylate ions act as counteranions to keep the whole structure neutral. Thermogravimetric analyses (TGA) and magnetic properties of 1−3 were studied, respectively. |
| doi_str_mv | 10.1021/cg701150q |
| format | Article |
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Single crystal X-ray diffraction analyses reveal that complex 1 is a discrete dinuclear Cu2O2 motif, 2 presents a discrete chairlike tetranuclear copper(II) Cu4O4 core formed by two Cu2O2 units, and 3 assumes a discrete hexameric copper(II) Cu6O6 cluster consisting of three Cu2O2 units. The polynuclear structures are generated from the Cu(II) ions linked by the µ2- and/or µ3-OH groups. In 1−3, all Cu(II) ions show square pyramidal coordination geometry, and the dicarboxylate ions act as counteranions to keep the whole structure neutral. Thermogravimetric analyses (TGA) and magnetic properties of 1−3 were studied, respectively.</description><identifier>ISSN: 1528-7483</identifier><identifier>EISSN: 1528-7505</identifier><identifier>DOI: 10.1021/cg701150q</identifier><language>eng</language><publisher>Washington,DC: American Chemical Society</publisher><subject>Condensed matter: structure, mechanical and thermal properties ; Cross-disciplinary physics: materials science; rheology ; Exact sciences and technology ; Materials science ; Methods of nanofabrication ; Organic compounds ; Other materials ; Physics ; Self-assembly ; Specific materials ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids</subject><ispartof>Crystal growth & design, 2008-08, Vol.8 (8), p.2853-2861</ispartof><rights>Copyright © 2008 American Chemical Society</rights><rights>2008 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a355t-139b04c6eaf337563f3405f65db026265d7dafc1aac3310e307c7eb9c87f4be63</citedby><cites>FETCH-LOGICAL-a355t-139b04c6eaf337563f3405f65db026265d7dafc1aac3310e307c7eb9c87f4be63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/cg701150q$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/cg701150q$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20577360$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Li, Xing</creatorcontrib><creatorcontrib>Cheng, Deyi</creatorcontrib><creatorcontrib>Lin, Jianli</creatorcontrib><creatorcontrib>Li, Zhifeng</creatorcontrib><creatorcontrib>Zheng, Yueqing</creatorcontrib><title>Di-, Tetra-, and Hexanuclear Hydroxy-Bridged Copper(II) Cluster Compounds: Syntheses, Structures, and Properties</title><title>Crystal growth & design</title><addtitle>Cryst. Growth Des</addtitle><description>Self-assembly reactions of copper (II) ions, dicarboxylate (adipate or terephthalate) and terminal ligands (4,4′-bipyridine or phenanthroline) yielded three hydroxy-bridged Cu(II) cluster complexes: [Cu(phen)(OH)(H2O)]2·(C8H4O4)·8H2O (1), [Cu4(bpy)4(OH)4(H2O)2]·(C8H4O4)2·6H2O (2) and [Cu6(bpy)6(OH)6(H2O)2]·(C6H8O4)3·23H2O (3) (phen = phenanthroline, bpy = 2,2′-bipyridine, C8H6O4 = terephthalic acid, C6H10O4 = adipic acid). Single crystal X-ray diffraction analyses reveal that complex 1 is a discrete dinuclear Cu2O2 motif, 2 presents a discrete chairlike tetranuclear copper(II) Cu4O4 core formed by two Cu2O2 units, and 3 assumes a discrete hexameric copper(II) Cu6O6 cluster consisting of three Cu2O2 units. The polynuclear structures are generated from the Cu(II) ions linked by the µ2- and/or µ3-OH groups. In 1−3, all Cu(II) ions show square pyramidal coordination geometry, and the dicarboxylate ions act as counteranions to keep the whole structure neutral. Thermogravimetric analyses (TGA) and magnetic properties of 1−3 were studied, respectively.</description><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Exact sciences and technology</subject><subject>Materials science</subject><subject>Methods of nanofabrication</subject><subject>Organic compounds</subject><subject>Other materials</subject><subject>Physics</subject><subject>Self-assembly</subject><subject>Specific materials</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><issn>1528-7483</issn><issn>1528-7505</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNptkEtLw0AUhQdRsFYX_oNsBAuN3slkMq07jY8WCgqt6zCZ3KkpaRLvJND8e1PqY-PqO1zOOXAPY5ccbjgE_NasFXAu4fOIDbgMJr6SII9_dDgRp-zMuQ0AqEiIAasfc3_srbAh3VOXmTfDnS5bU6Amb9ZlVO06_4HybI2ZF1d1jXQ9n4-8uGhdg9SftnXVlpm785Zd2XygQzf2lg21pmlpr_elb1T1wSZHd85OrC4cXnxzyN6fn1bxzF-8vszj-4WvhZSNz8U0hdBEqK0QSkbCihCkjWSWQhAFPVWmreFaGyE4oABlFKZTM1E2TDESQzY69BqqnCO0SU35VlOXcEj2UyW_U_Xeq4O31s7owpIuTe5-AwFIpUQEfz5tXLKpWir7D_7p-wJtenSw</recordid><startdate>20080801</startdate><enddate>20080801</enddate><creator>Li, Xing</creator><creator>Cheng, Deyi</creator><creator>Lin, Jianli</creator><creator>Li, Zhifeng</creator><creator>Zheng, Yueqing</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20080801</creationdate><title>Di-, Tetra-, and Hexanuclear Hydroxy-Bridged Copper(II) Cluster Compounds: Syntheses, Structures, and Properties</title><author>Li, Xing ; Cheng, Deyi ; Lin, Jianli ; Li, Zhifeng ; Zheng, Yueqing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a355t-139b04c6eaf337563f3405f65db026265d7dafc1aac3310e307c7eb9c87f4be63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Exact sciences and technology</topic><topic>Materials science</topic><topic>Methods of nanofabrication</topic><topic>Organic compounds</topic><topic>Other materials</topic><topic>Physics</topic><topic>Self-assembly</topic><topic>Specific materials</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Xing</creatorcontrib><creatorcontrib>Cheng, Deyi</creatorcontrib><creatorcontrib>Lin, Jianli</creatorcontrib><creatorcontrib>Li, Zhifeng</creatorcontrib><creatorcontrib>Zheng, Yueqing</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Crystal growth & design</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Xing</au><au>Cheng, Deyi</au><au>Lin, Jianli</au><au>Li, Zhifeng</au><au>Zheng, Yueqing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Di-, Tetra-, and Hexanuclear Hydroxy-Bridged Copper(II) Cluster Compounds: Syntheses, Structures, and Properties</atitle><jtitle>Crystal growth & design</jtitle><addtitle>Cryst. Growth Des</addtitle><date>2008-08-01</date><risdate>2008</risdate><volume>8</volume><issue>8</issue><spage>2853</spage><epage>2861</epage><pages>2853-2861</pages><issn>1528-7483</issn><eissn>1528-7505</eissn><abstract>Self-assembly reactions of copper (II) ions, dicarboxylate (adipate or terephthalate) and terminal ligands (4,4′-bipyridine or phenanthroline) yielded three hydroxy-bridged Cu(II) cluster complexes: [Cu(phen)(OH)(H2O)]2·(C8H4O4)·8H2O (1), [Cu4(bpy)4(OH)4(H2O)2]·(C8H4O4)2·6H2O (2) and [Cu6(bpy)6(OH)6(H2O)2]·(C6H8O4)3·23H2O (3) (phen = phenanthroline, bpy = 2,2′-bipyridine, C8H6O4 = terephthalic acid, C6H10O4 = adipic acid). Single crystal X-ray diffraction analyses reveal that complex 1 is a discrete dinuclear Cu2O2 motif, 2 presents a discrete chairlike tetranuclear copper(II) Cu4O4 core formed by two Cu2O2 units, and 3 assumes a discrete hexameric copper(II) Cu6O6 cluster consisting of three Cu2O2 units. The polynuclear structures are generated from the Cu(II) ions linked by the µ2- and/or µ3-OH groups. In 1−3, all Cu(II) ions show square pyramidal coordination geometry, and the dicarboxylate ions act as counteranions to keep the whole structure neutral. Thermogravimetric analyses (TGA) and magnetic properties of 1−3 were studied, respectively.</abstract><cop>Washington,DC</cop><pub>American Chemical Society</pub><doi>10.1021/cg701150q</doi><tpages>9</tpages></addata></record> |
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| subjects | Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science rheology Exact sciences and technology Materials science Methods of nanofabrication Organic compounds Other materials Physics Self-assembly Specific materials Structure of solids and liquids crystallography Structure of specific crystalline solids |
| title | Di-, Tetra-, and Hexanuclear Hydroxy-Bridged Copper(II) Cluster Compounds: Syntheses, Structures, and Properties |
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