A Rare-Earth MOF Series: Fascinating Structure, Efficient Light Emitters, and Promising Catalysts
A new family of rare-earth polymeric framework RPF-4 has been obtained and its structure solved from an intrinsically triple twinned crystal. The framework formed by a H−O bond free rare-earth matrix, with the Ln atoms separated in two directions, makes them very promising materials for light-emitti...
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Veröffentlicht in: | Crystal growth & design 2008-02, Vol.8 (2), p.378-380 |
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creator | Gándara, F Andrés, A. de Gómez-Lor, B Gutiérrez-Puebla, E Iglesias, M Monge, M. A Proserpio, D. M Snejko, N |
description | A new family of rare-earth polymeric framework RPF-4 has been obtained and its structure solved from an intrinsically triple twinned crystal. The framework formed by a H−O bond free rare-earth matrix, with the Ln atoms separated in two directions, makes them very promising materials for light-emitting diodes. The properties of the materials as heterogeneous catalysts are reported, too. IR spectroscopy suggests the presence of a peroxo complex that acts as active species in the oxidation reaction. |
doi_str_mv | 10.1021/cg700796m |
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IR spectroscopy suggests the presence of a peroxo complex that acts as active species in the oxidation reaction.</description><subject>Applied sciences</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Electronics</subject><subject>Exact sciences and technology</subject><subject>Materials science</subject><subject>Optoelectronic devices</subject><subject>Organic compounds</subject><subject>Other materials</subject><subject>Physics</subject><subject>Semiconductor electronics. Microelectronics. Optoelectronics. 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subjects | Applied sciences Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science rheology Electronics Exact sciences and technology Materials science Optoelectronic devices Organic compounds Other materials Physics Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices Specific materials Structure of solids and liquids crystallography Structure of specific crystalline solids |
title | A Rare-Earth MOF Series: Fascinating Structure, Efficient Light Emitters, and Promising Catalysts |
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