New 3D Lanthanide Phosphonates: Syntheses, Crystal Structure, Thermal Stability, Luminescence, and Magnetism
Hydrothermal reactions of lanthanide oxide or lanthanide chloride with 3-ammonium-1-hydroxypropylidene-1,1-diphosphonic acid (+H3NCH2CH2C(OH)(PO3H2)(PO3H–), H4L) afforded seven new lanthanide phosphonates, namely, [Ln(HL)] (Ln = Eu (1), Tb (2), Sm (3), Gd (4), Er (5), Nd (6), and Pr (7)). Compo...
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| Veröffentlicht in: | Crystal growth & design 2014-12, Vol.14 (12), p.6197-6204 |
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| creator | Fu, Ruibiao Hu, Shengmin Wu, Xintao |
| description | Hydrothermal reactions of lanthanide oxide or lanthanide chloride with 3-ammonium-1-hydroxypropylidene-1,1-diphosphonic acid (+H3NCH2CH2C(OH)(PO3H2)(PO3H–), H4L) afforded seven new lanthanide phosphonates, namely, [Ln(HL)] (Ln = Eu (1), Tb (2), Sm (3), Gd (4), Er (5), Nd (6), and Pr (7)). Compounds 1–7 are characterized by single-crystal X-ray diffraction, powder XRD, elemental analysis, IR spectroscopy, and thermogravimetric analysis (TGA). Compounds 1–5 crystallize in the orthorhombic Pnma space group, whereas compounds 6 and 7 crystallize in the monoclinic P2(1)/c space group. Compounds 1–7 exhibit a similar 3D open framework with eight-membered ring channels, which are occupied by organic pendants of CH2CH2NH3. TGA and PXRD reveal that compound 1 is thermally stable up to 350 °C under an air atmosphere. It is interesting that compounds 1 and 2 display bright red and green luminescence, respectively, which can be further enhanced obviously upon cooling to 10 K. It is worth noting that the bright red emission of compound 1 can be preserved after heat-treatment at 350 °C under an air atmosphere. Compounds 6 and 7 can give off NIR luminescence and near UV emission, respectively. Furthermore, the magnetic properties of solids 1 and 3–6 have also been studied. |
| doi_str_mv | 10.1021/cg501355t |
| format | Article |
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Compounds 1–7 are characterized by single-crystal X-ray diffraction, powder XRD, elemental analysis, IR spectroscopy, and thermogravimetric analysis (TGA). Compounds 1–5 crystallize in the orthorhombic Pnma space group, whereas compounds 6 and 7 crystallize in the monoclinic P2(1)/c space group. Compounds 1–7 exhibit a similar 3D open framework with eight-membered ring channels, which are occupied by organic pendants of CH2CH2NH3. TGA and PXRD reveal that compound 1 is thermally stable up to 350 °C under an air atmosphere. It is interesting that compounds 1 and 2 display bright red and green luminescence, respectively, which can be further enhanced obviously upon cooling to 10 K. It is worth noting that the bright red emission of compound 1 can be preserved after heat-treatment at 350 °C under an air atmosphere. Compounds 6 and 7 can give off NIR luminescence and near UV emission, respectively. Furthermore, the magnetic properties of solids 1 and 3–6 have also been studied.</description><identifier>ISSN: 1528-7483</identifier><identifier>EISSN: 1528-7505</identifier><identifier>DOI: 10.1021/cg501355t</identifier><language>eng</language><publisher>Washington,DC: American Chemical Society</publisher><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Condensed matter: structure, mechanical and thermal properties ; Exact sciences and technology ; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation ; Optical properties of bulk materials and thin films ; Physics ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids ; Thermal expansion; thermomechanical effects and density ; Thermal properties of condensed matter ; Thermal properties of crystalline solids</subject><ispartof>Crystal growth & design, 2014-12, Vol.14 (12), p.6197-6204</ispartof><rights>Copyright © 2014 American Chemical Society</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a289t-84efbe47a4d2fd1ff0e5eb66d6c286446612490ad8a9b0b1019df7a3513d2c9e3</citedby><cites>FETCH-LOGICAL-a289t-84efbe47a4d2fd1ff0e5eb66d6c286446612490ad8a9b0b1019df7a3513d2c9e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/cg501355t$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/cg501355t$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,777,781,2752,27057,27905,27906,56719,56769</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=29033978$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Fu, Ruibiao</creatorcontrib><creatorcontrib>Hu, Shengmin</creatorcontrib><creatorcontrib>Wu, Xintao</creatorcontrib><title>New 3D Lanthanide Phosphonates: Syntheses, Crystal Structure, Thermal Stability, Luminescence, and Magnetism</title><title>Crystal growth & design</title><addtitle>Cryst. Growth Des</addtitle><description>Hydrothermal reactions of lanthanide oxide or lanthanide chloride with 3-ammonium-1-hydroxypropylidene-1,1-diphosphonic acid (+H3NCH2CH2C(OH)(PO3H2)(PO3H–), H4L) afforded seven new lanthanide phosphonates, namely, [Ln(HL)] (Ln = Eu (1), Tb (2), Sm (3), Gd (4), Er (5), Nd (6), and Pr (7)). Compounds 1–7 are characterized by single-crystal X-ray diffraction, powder XRD, elemental analysis, IR spectroscopy, and thermogravimetric analysis (TGA). Compounds 1–5 crystallize in the orthorhombic Pnma space group, whereas compounds 6 and 7 crystallize in the monoclinic P2(1)/c space group. Compounds 1–7 exhibit a similar 3D open framework with eight-membered ring channels, which are occupied by organic pendants of CH2CH2NH3. TGA and PXRD reveal that compound 1 is thermally stable up to 350 °C under an air atmosphere. It is interesting that compounds 1 and 2 display bright red and green luminescence, respectively, which can be further enhanced obviously upon cooling to 10 K. It is worth noting that the bright red emission of compound 1 can be preserved after heat-treatment at 350 °C under an air atmosphere. Compounds 6 and 7 can give off NIR luminescence and near UV emission, respectively. Furthermore, the magnetic properties of solids 1 and 3–6 have also been studied.</description><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Exact sciences and technology</subject><subject>Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation</subject><subject>Optical properties of bulk materials and thin films</subject><subject>Physics</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><subject>Thermal expansion; thermomechanical effects and density</subject><subject>Thermal properties of condensed matter</subject><subject>Thermal properties of crystalline solids</subject><issn>1528-7483</issn><issn>1528-7505</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNptkEtPwzAQhC0EEqVw4B_4wgGpATuO8-CGylMqD6nlHG2cdROUOJXtCOXfEyiUC6dd7X4z0gwhp5xdcBbyS7WWjAsp_R6ZcBmmQSKZ3P_do1QckiPn3hljSSzEhDTP-EHFDV2A8RWYukT6WnVuU3UGPLoruhzGBzp0Mzq3g_PQ0KW3vfK9xRldVWjb7xMUdVP7YUYXfVsbdAqNGgEwJX2CtUFfu_aYHGhoHJ78zCl5u7tdzR-Cxcv94_x6EUCYZj5II9QFRglEZahLrjVDiUUcl7EK0ziK4piHUcagTCErWMEZz0qdgJBclKHKUEzJ-dZX2c45izrf2LoFO-Sc5V815buaRvZsy27AKWi0BaNqtxOEGRMiS9I_DpTL37vemjHBP36f3I50hA</recordid><startdate>20141203</startdate><enddate>20141203</enddate><creator>Fu, Ruibiao</creator><creator>Hu, Shengmin</creator><creator>Wu, Xintao</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20141203</creationdate><title>New 3D Lanthanide Phosphonates: Syntheses, Crystal Structure, Thermal Stability, Luminescence, and Magnetism</title><author>Fu, Ruibiao ; Hu, Shengmin ; Wu, Xintao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a289t-84efbe47a4d2fd1ff0e5eb66d6c286446612490ad8a9b0b1019df7a3513d2c9e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Exact sciences and technology</topic><topic>Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation</topic><topic>Optical properties of bulk materials and thin films</topic><topic>Physics</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><topic>Thermal expansion; thermomechanical effects and density</topic><topic>Thermal properties of condensed matter</topic><topic>Thermal properties of crystalline solids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fu, Ruibiao</creatorcontrib><creatorcontrib>Hu, Shengmin</creatorcontrib><creatorcontrib>Wu, Xintao</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Crystal growth & design</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fu, Ruibiao</au><au>Hu, Shengmin</au><au>Wu, Xintao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New 3D Lanthanide Phosphonates: Syntheses, Crystal Structure, Thermal Stability, Luminescence, and Magnetism</atitle><jtitle>Crystal growth & design</jtitle><addtitle>Cryst. Growth Des</addtitle><date>2014-12-03</date><risdate>2014</risdate><volume>14</volume><issue>12</issue><spage>6197</spage><epage>6204</epage><pages>6197-6204</pages><issn>1528-7483</issn><eissn>1528-7505</eissn><abstract>Hydrothermal reactions of lanthanide oxide or lanthanide chloride with 3-ammonium-1-hydroxypropylidene-1,1-diphosphonic acid (+H3NCH2CH2C(OH)(PO3H2)(PO3H–), H4L) afforded seven new lanthanide phosphonates, namely, [Ln(HL)] (Ln = Eu (1), Tb (2), Sm (3), Gd (4), Er (5), Nd (6), and Pr (7)). Compounds 1–7 are characterized by single-crystal X-ray diffraction, powder XRD, elemental analysis, IR spectroscopy, and thermogravimetric analysis (TGA). Compounds 1–5 crystallize in the orthorhombic Pnma space group, whereas compounds 6 and 7 crystallize in the monoclinic P2(1)/c space group. Compounds 1–7 exhibit a similar 3D open framework with eight-membered ring channels, which are occupied by organic pendants of CH2CH2NH3. TGA and PXRD reveal that compound 1 is thermally stable up to 350 °C under an air atmosphere. It is interesting that compounds 1 and 2 display bright red and green luminescence, respectively, which can be further enhanced obviously upon cooling to 10 K. It is worth noting that the bright red emission of compound 1 can be preserved after heat-treatment at 350 °C under an air atmosphere. Compounds 6 and 7 can give off NIR luminescence and near UV emission, respectively. Furthermore, the magnetic properties of solids 1 and 3–6 have also been studied.</abstract><cop>Washington,DC</cop><pub>American Chemical Society</pub><doi>10.1021/cg501355t</doi><tpages>8</tpages></addata></record> |
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| subjects | Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation Optical properties of bulk materials and thin films Physics Structure of solids and liquids crystallography Structure of specific crystalline solids Thermal expansion thermomechanical effects and density Thermal properties of condensed matter Thermal properties of crystalline solids |
| title | New 3D Lanthanide Phosphonates: Syntheses, Crystal Structure, Thermal Stability, Luminescence, and Magnetism |
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