Structural Variation in Mellitate Complexes of First-Row Transition Metals: What Chance for Design?

Eight compounds of Co, Ni, and Cu with mellitate ligands display a wide variety of structures with metal–mellitate coordination polymer dimensionality 0–3. Usually mellitate is fully deprotonated (mel6–), but there is one example of Hmel5– and one of H2mel4–. [M3(mel)(OH2)12]­·6H2O (M = Co or Ni) ar...

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Veröffentlicht in:	Crystal growth & design 2014-12, Vol.14 (12), p.6282-6293
Hauptverfasser:	Clegg, William, Holcroft, James M
Format:	Artikel
Sprache:	eng
Schlagworte:	Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Physics Structure of solids and liquids crystallography Structure of specific crystalline solids
Online-Zugang:	Volltext
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