Tracing a Common “Origin” of Phase Transformation, Polymorphism, Disorder, Isosterism, and Isostructuralism in Fluorobenzoylcarvacryl Thiourea
The terms phase transformation, polymorphism, disorder, isosterism, and isostructuralism are often the keywords used in the design and engineering of molecular crystals. Three benzoylcarvacryl thiourea derivatives with [-NH–C(S)–NH–C(O)-] cores generate molecular crystals, which provide the basis fo...
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| Veröffentlicht in: | Crystal growth & design 2012-09, Vol.12 (9), p.4530-4534 |
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| container_issue | 9 |
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| container_title | Crystal growth & design |
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| creator | Dikundwar, Amol G Pete, Umesh D Zade, Chetan M Bendre, Ratnamala S Guru Row, Tayur N |
| description | The terms phase transformation, polymorphism, disorder, isosterism, and isostructuralism are often the keywords used in the design and engineering of molecular crystals. Three benzoylcarvacryl thiourea derivatives with [-NH–C(S)–NH–C(O)-] cores generate molecular crystals, which provide the basis for exploring a common link between the structures related by aforementioned terms. The apparent “origin” of all these structural modifications has been traced to the formation of a planar molecular dimeric chain built with homomeric R2 2(12) and R2 2(8) synthons occurring in tandem, one formed with N–H···O and the other with N–H···S hydrogen bonds. |
| doi_str_mv | 10.1021/cg300699r |
| format | Article |
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Three benzoylcarvacryl thiourea derivatives with [-NH–C(S)–NH–C(O)-] cores generate molecular crystals, which provide the basis for exploring a common link between the structures related by aforementioned terms. The apparent “origin” of all these structural modifications has been traced to the formation of a planar molecular dimeric chain built with homomeric R2 2(12) and R2 2(8) synthons occurring in tandem, one formed with N–H···O and the other with N–H···S hydrogen bonds.</description><identifier>ISSN: 1528-7483</identifier><identifier>EISSN: 1528-7505</identifier><identifier>DOI: 10.1021/cg300699r</identifier><language>eng</language><publisher>Washington,DC: American Chemical Society</publisher><subject>Condensed matter: structure, mechanical and thermal properties ; Constant-composition solid-solid phase transformations: polymorphic, massive, and order-disorder ; Cross-disciplinary physics: materials science; rheology ; Crystalline state (including molecular motions in solids) ; Crystallographic aspects of phase transformations; pressure effects ; Exact sciences and technology ; Materials science ; Phase diagrams and microstructures developed by solidification and solid-solid phase transformations ; Physics ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids</subject><ispartof>Crystal growth & design, 2012-09, Vol.12 (9), p.4530-4534</ispartof><rights>Copyright © 2012 American Chemical Society</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a289t-547ceaa893d5c7bb2ec7d2bdd2fa483321c56c8d64cbdc800d653315c9dce2e63</citedby><cites>FETCH-LOGICAL-a289t-547ceaa893d5c7bb2ec7d2bdd2fa483321c56c8d64cbdc800d653315c9dce2e63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/cg300699r$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/cg300699r$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,777,781,2752,27057,27905,27906,56719,56769</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=26329131$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Dikundwar, Amol G</creatorcontrib><creatorcontrib>Pete, Umesh D</creatorcontrib><creatorcontrib>Zade, Chetan M</creatorcontrib><creatorcontrib>Bendre, Ratnamala S</creatorcontrib><creatorcontrib>Guru Row, Tayur N</creatorcontrib><title>Tracing a Common “Origin” of Phase Transformation, Polymorphism, Disorder, Isosterism, and Isostructuralism in Fluorobenzoylcarvacryl Thiourea</title><title>Crystal growth & design</title><addtitle>Cryst. 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The apparent “origin” of all these structural modifications has been traced to the formation of a planar molecular dimeric chain built with homomeric R2 2(12) and R2 2(8) synthons occurring in tandem, one formed with N–H···O and the other with N–H···S hydrogen bonds.</abstract><cop>Washington,DC</cop><pub>American Chemical Society</pub><doi>10.1021/cg300699r</doi><tpages>5</tpages></addata></record> |
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| ispartof | Crystal growth & design, 2012-09, Vol.12 (9), p.4530-4534 |
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| source | ACS Publications |
| subjects | Condensed matter: structure, mechanical and thermal properties Constant-composition solid-solid phase transformations: polymorphic, massive, and order-disorder Cross-disciplinary physics: materials science rheology Crystalline state (including molecular motions in solids) Crystallographic aspects of phase transformations pressure effects Exact sciences and technology Materials science Phase diagrams and microstructures developed by solidification and solid-solid phase transformations Physics Structure of solids and liquids crystallography Structure of specific crystalline solids |
| title | Tracing a Common “Origin” of Phase Transformation, Polymorphism, Disorder, Isosterism, and Isostructuralism in Fluorobenzoylcarvacryl Thiourea |
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