Role of Defects and Growth Directions in the Formation of Periodically Twinned and Kinked Unseeded Germanium Nanowires

Here we show the impact of preferred growth directions and defects in the formation of complex Ge nanowire (NW) structures grown by a simple organic medium based synthesis. Various types of NWs are examined including: straight defect free NWs; periodically bent NWs with precise angles between the NW...

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Veröffentlicht in:Crystal growth & design 2011-07, Vol.11 (7), p.3266-3272
Hauptverfasser: Geaney, Hugh, Dickinson, Calum, Weng, Weihao, Kiely, Christopher J, Barrett, Christopher A, Gunning, Robert D, Ryan, Kevin M
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container_end_page 3272
container_issue 7
container_start_page 3266
container_title Crystal growth & design
container_volume 11
creator Geaney, Hugh
Dickinson, Calum
Weng, Weihao
Kiely, Christopher J
Barrett, Christopher A
Gunning, Robert D
Ryan, Kevin M
description Here we show the impact of preferred growth directions and defects in the formation of complex Ge nanowire (NW) structures grown by a simple organic medium based synthesis. Various types of NWs are examined including: straight defect free NWs; periodically bent NWs with precise angles between the NW segments; NWs with mutually exclusive lateral or longitudinal faults; and more complex “wormlike” structures. We show that choice of solvent and reaction temperature can be used to tune the morphology of the NWs formed. The various types of NWs were probed in depth using transmission electron microscopy (TEM), scanning electron microscopy (SEM), selected area electron diffraction (SAED), and dark field TEM (DFTEM).
doi_str_mv 10.1021/cg200510y
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subjects Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Materials science
Methods of nanofabrication
Nanoscale materials and structures: fabrication and characterization
Other topics in nanoscale materials and structures
Physics
Quantum wires
title Role of Defects and Growth Directions in the Formation of Periodically Twinned and Kinked Unseeded Germanium Nanowires
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