Two Novel Zinc(II) Metal–Organic Frameworks Based on Triazole-Carboxylate Shared Paddle-Wheel Units: Synthesis, Structure, and Gas Adsorption
Two novel porous metal–organic frameworks {Zn7(btc)4(dmtrz)2(H2O)5} n (1) and {[Zn6(btc)4(dmtrz)3]·3H3O·2H2O} n (2) (H3btc = 1,3,5-benzenetricarboxylic acid, Hdmtrz = 3,5-dimethyl-1H-1,2,4-triazole) have been solvothermally synthesized. Single-crystal structure analysis reveals that both structure 1...
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| Veröffentlicht in: | Crystal growth & design 2011-07, Vol.11 (7), p.2811-2816 |
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| container_title | Crystal growth & design |
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| creator | Ling, Yun Chen, Zhenxia Zheng, Hua Zhou, Yaming Weng, Linhong Zhao, Dongyuan |
| description | Two novel porous metal–organic frameworks {Zn7(btc)4(dmtrz)2(H2O)5} n (1) and {[Zn6(btc)4(dmtrz)3]·3H3O·2H2O} n (2) (H3btc = 1,3,5-benzenetricarboxylic acid, Hdmtrz = 3,5-dimethyl-1H-1,2,4-triazole) have been solvothermally synthesized. Single-crystal structure analysis reveals that both structure 1 and 2 contain special triazole-carboxylate shared paddle-wheel units. The crucial factors to the assembly of such paddle-wheel units are discussed. Gas adsorption studies suggest that 2 is a potential microporous material for adsorptive separation of CO2 over N2. |
| doi_str_mv | 10.1021/cg101569a |
| format | Article |
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Single-crystal structure analysis reveals that both structure 1 and 2 contain special triazole-carboxylate shared paddle-wheel units. The crucial factors to the assembly of such paddle-wheel units are discussed. Gas adsorption studies suggest that 2 is a potential microporous material for adsorptive separation of CO2 over N2.</description><identifier>ISSN: 1528-7483</identifier><identifier>EISSN: 1528-7505</identifier><identifier>DOI: 10.1021/cg101569a</identifier><language>eng</language><publisher>Washington,DC: American Chemical Society</publisher><subject>Condensed matter: structure, mechanical and thermal properties ; Cross-disciplinary physics: materials science; rheology ; Exact sciences and technology ; Materials science ; Organic compounds ; Other materials ; Physics ; Porous materials; granular materials ; Solid surfaces and solid-solid interfaces ; Specific materials ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids ; Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</subject><ispartof>Crystal growth & design, 2011-07, Vol.11 (7), p.2811-2816</ispartof><rights>Copyright © 2011 American Chemical Society</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a289t-592b4a65115fbb834fedbb7a46a968b98c96d666951b763598a55834f47b1233</citedby><cites>FETCH-LOGICAL-a289t-592b4a65115fbb834fedbb7a46a968b98c96d666951b763598a55834f47b1233</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/cg101569a$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/cg101569a$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>315,781,785,2766,27080,27928,27929,56742,56792</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24349509$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Ling, Yun</creatorcontrib><creatorcontrib>Chen, Zhenxia</creatorcontrib><creatorcontrib>Zheng, Hua</creatorcontrib><creatorcontrib>Zhou, Yaming</creatorcontrib><creatorcontrib>Weng, Linhong</creatorcontrib><creatorcontrib>Zhao, Dongyuan</creatorcontrib><title>Two Novel Zinc(II) Metal–Organic Frameworks Based on Triazole-Carboxylate Shared Paddle-Wheel Units: Synthesis, Structure, and Gas Adsorption</title><title>Crystal growth & design</title><addtitle>Cryst. Growth Des</addtitle><description>Two novel porous metal–organic frameworks {Zn7(btc)4(dmtrz)2(H2O)5} n (1) and {[Zn6(btc)4(dmtrz)3]·3H3O·2H2O} n (2) (H3btc = 1,3,5-benzenetricarboxylic acid, Hdmtrz = 3,5-dimethyl-1H-1,2,4-triazole) have been solvothermally synthesized. Single-crystal structure analysis reveals that both structure 1 and 2 contain special triazole-carboxylate shared paddle-wheel units. The crucial factors to the assembly of such paddle-wheel units are discussed. Gas adsorption studies suggest that 2 is a potential microporous material for adsorptive separation of CO2 over N2.</description><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Exact sciences and technology</subject><subject>Materials science</subject><subject>Organic compounds</subject><subject>Other materials</subject><subject>Physics</subject><subject>Porous materials; granular materials</subject><subject>Solid surfaces and solid-solid interfaces</subject><subject>Specific materials</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><subject>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</subject><issn>1528-7483</issn><issn>1528-7505</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNptkM1OAjEUhSdGExFd-AbdmEjCaDszLVN3SARJ8CcBY-JmctvpwODQknYQceUbuPANfRKHoLhxdW9yvnOSczzvmOAzggNyLscEE8o47Hg1QoPYb1FMd3__KA73vQPnphjjFgvDmvcxWhp0a15UgZ5yLU_7_Qa6USUUX--fd3YMOpeoa2GmlsY-O3QJTqXIaDSyObyZQvkdsMK8rgooFRpOwFbyPaRppTxOVJX6oPPSXaDhSpcT5XLXRMPSLmS5sKqJQKeoBw61U2fsvMyNPvT2MiicOvq5dW_UvRp1rv3BXa_faQ98CGJe-pQHIgJGCaGZEHEYZSoVogURA85iwWPJWcoY45SIqijlMVC6xqKWIEEY1r3GJlZa45xVWTK3-QzsKiE4WQ-ZbIes2JMNOwcnocgsaJm7rSGIwohTzP84kC6ZmoXVVYF_8r4BRT6ACg</recordid><startdate>20110706</startdate><enddate>20110706</enddate><creator>Ling, Yun</creator><creator>Chen, Zhenxia</creator><creator>Zheng, Hua</creator><creator>Zhou, Yaming</creator><creator>Weng, Linhong</creator><creator>Zhao, Dongyuan</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20110706</creationdate><title>Two Novel Zinc(II) Metal–Organic Frameworks Based on Triazole-Carboxylate Shared Paddle-Wheel Units: Synthesis, Structure, and Gas Adsorption</title><author>Ling, Yun ; Chen, Zhenxia ; Zheng, Hua ; Zhou, Yaming ; Weng, Linhong ; Zhao, Dongyuan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a289t-592b4a65115fbb834fedbb7a46a968b98c96d666951b763598a55834f47b1233</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Exact sciences and technology</topic><topic>Materials science</topic><topic>Organic compounds</topic><topic>Other materials</topic><topic>Physics</topic><topic>Porous materials; granular materials</topic><topic>Solid surfaces and solid-solid interfaces</topic><topic>Specific materials</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><topic>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ling, Yun</creatorcontrib><creatorcontrib>Chen, Zhenxia</creatorcontrib><creatorcontrib>Zheng, Hua</creatorcontrib><creatorcontrib>Zhou, Yaming</creatorcontrib><creatorcontrib>Weng, Linhong</creatorcontrib><creatorcontrib>Zhao, Dongyuan</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Crystal growth & design</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ling, Yun</au><au>Chen, Zhenxia</au><au>Zheng, Hua</au><au>Zhou, Yaming</au><au>Weng, Linhong</au><au>Zhao, Dongyuan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Two Novel Zinc(II) Metal–Organic Frameworks Based on Triazole-Carboxylate Shared Paddle-Wheel Units: Synthesis, Structure, and Gas Adsorption</atitle><jtitle>Crystal growth & design</jtitle><addtitle>Cryst. Growth Des</addtitle><date>2011-07-06</date><risdate>2011</risdate><volume>11</volume><issue>7</issue><spage>2811</spage><epage>2816</epage><pages>2811-2816</pages><issn>1528-7483</issn><eissn>1528-7505</eissn><abstract>Two novel porous metal–organic frameworks {Zn7(btc)4(dmtrz)2(H2O)5} n (1) and {[Zn6(btc)4(dmtrz)3]·3H3O·2H2O} n (2) (H3btc = 1,3,5-benzenetricarboxylic acid, Hdmtrz = 3,5-dimethyl-1H-1,2,4-triazole) have been solvothermally synthesized. Single-crystal structure analysis reveals that both structure 1 and 2 contain special triazole-carboxylate shared paddle-wheel units. The crucial factors to the assembly of such paddle-wheel units are discussed. Gas adsorption studies suggest that 2 is a potential microporous material for adsorptive separation of CO2 over N2.</abstract><cop>Washington,DC</cop><pub>American Chemical Society</pub><doi>10.1021/cg101569a</doi><tpages>6</tpages></addata></record> |
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| source | ACS Publications |
| subjects | Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science rheology Exact sciences and technology Materials science Organic compounds Other materials Physics Porous materials granular materials Solid surfaces and solid-solid interfaces Specific materials Structure of solids and liquids crystallography Structure of specific crystalline solids Surfaces and interfaces thin films and whiskers (structure and nonelectronic properties) |
| title | Two Novel Zinc(II) Metal–Organic Frameworks Based on Triazole-Carboxylate Shared Paddle-Wheel Units: Synthesis, Structure, and Gas Adsorption |
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