Tether Length Control of Topology in Cadmium 4-Methylphthalate Two-Dimensional Coordination Polymers: An Acentric Buckled Grid and a Rare Self-Catenated Layer

Hydrothermal synthesis has afforded a pair of dual-ligand divalent cadmium 4-methylphthalate (mph) two-dimensional (2-D) coordination polymers, wherein the length of the dipyridyl co-ligand plays a predominant role in the overall structural topology. [Cd2(mph)2(dpe)4] n (1, dpe = 1,2-di(4-pyridyl)et...

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Veröffentlicht in:Crystal growth & design 2011-03, Vol.11 (3), p.678-683
Hauptverfasser: Farnum, Gregory A, Pochodylo, Amy L, LaDuca, Robert L
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Pochodylo, Amy L
LaDuca, Robert L
description Hydrothermal synthesis has afforded a pair of dual-ligand divalent cadmium 4-methylphthalate (mph) two-dimensional (2-D) coordination polymers, wherein the length of the dipyridyl co-ligand plays a predominant role in the overall structural topology. [Cd2(mph)2(dpe)4] n (1, dpe = 1,2-di(4-pyridyl)ethane) possesses an acentric buckled (4,4) grid topology, with a pendant, monodentate dpe ligand bound to each Cd atom. Use of a slightly longer dipyridyl tether allowed generation of the 2-D phase [Cd2(mph)2(dpp)3] n (2, dpp = 1,3-di(4-pyridyl)propane). The dpp ligands in 2 all bridge two cadmium atoms, promoting the formation of a very rare 4-connected 66 self-catenated layer topology. Luminescent and thermal properties of 1 and 2 are also discussed.
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subjects Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
Thermal expansion
thermomechanical effects and density
Thermal properties of condensed matter
Thermal properties of crystalline solids
title Tether Length Control of Topology in Cadmium 4-Methylphthalate Two-Dimensional Coordination Polymers: An Acentric Buckled Grid and a Rare Self-Catenated Layer
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