Tether Length Control of Topology in Cadmium 4-Methylphthalate Two-Dimensional Coordination Polymers: An Acentric Buckled Grid and a Rare Self-Catenated Layer
Hydrothermal synthesis has afforded a pair of dual-ligand divalent cadmium 4-methylphthalate (mph) two-dimensional (2-D) coordination polymers, wherein the length of the dipyridyl co-ligand plays a predominant role in the overall structural topology. [Cd2(mph)2(dpe)4] n (1, dpe = 1,2-di(4-pyridyl)et...
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Veröffentlicht in: | Crystal growth & design 2011-03, Vol.11 (3), p.678-683 |
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description | Hydrothermal synthesis has afforded a pair of dual-ligand divalent cadmium 4-methylphthalate (mph) two-dimensional (2-D) coordination polymers, wherein the length of the dipyridyl co-ligand plays a predominant role in the overall structural topology. [Cd2(mph)2(dpe)4] n (1, dpe = 1,2-di(4-pyridyl)ethane) possesses an acentric buckled (4,4) grid topology, with a pendant, monodentate dpe ligand bound to each Cd atom. Use of a slightly longer dipyridyl tether allowed generation of the 2-D phase [Cd2(mph)2(dpp)3] n (2, dpp = 1,3-di(4-pyridyl)propane). The dpp ligands in 2 all bridge two cadmium atoms, promoting the formation of a very rare 4-connected 66 self-catenated layer topology. Luminescent and thermal properties of 1 and 2 are also discussed. |
doi_str_mv | 10.1021/cg100972s |
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Luminescent and thermal properties of 1 and 2 are also discussed.</description><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Exact sciences and technology</subject><subject>Physics</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><subject>Thermal expansion; thermomechanical effects and density</subject><subject>Thermal properties of condensed matter</subject><subject>Thermal properties of crystalline solids</subject><issn>1528-7483</issn><issn>1528-7505</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNptkD1PwzAQhiMEEqUw8A-8MDAE_JFPthKgIBWBoMyRY19aF8eu7FQof4bfilGhLAynu9M99wxvFJ0SfEEwJZdiQTAuc-r3ohFJaRHnKU73f-ekYIfRkfcrjHGeMTaKPufQL8GhGZhFv0SVNb2zGtkWze3aarsYkDKo4rJTmw4l8WPAB71e9kuueQ9o_mHjG9WB8coaroPAOqkM78OKnq0eOnD-Ck0MmggIbiXQ9Ua8a5Bo6pRE3IRCL9wBegXdxlWQhu9wnvEB3HF00HLt4eSnj6O3u9t5dR_PnqYP1WQWc5amfczaREhKsciEJImEkgPOWdo0KYM8BYqzkkKS4Vy2TYYlo0lS0IblTZYVuCCMjaPzrVc4672Dtl471XE31ATX38HWu2ADe7Zl19wLrlvHjVB-90BZSYqS4T-OC1-v7MaFfPw_vi8HtIVS</recordid><startdate>20110302</startdate><enddate>20110302</enddate><creator>Farnum, Gregory A</creator><creator>Pochodylo, Amy L</creator><creator>LaDuca, Robert L</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20110302</creationdate><title>Tether Length Control of Topology in Cadmium 4-Methylphthalate Two-Dimensional Coordination Polymers: An Acentric Buckled Grid and a Rare Self-Catenated Layer</title><author>Farnum, Gregory A ; Pochodylo, Amy L ; LaDuca, Robert L</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a355t-3f4cd220c6cd14de9ae0735bb53e75e20692e4607dfb60d324482b37b66808133</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Exact sciences and technology</topic><topic>Physics</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><topic>Thermal expansion; thermomechanical effects and density</topic><topic>Thermal properties of condensed matter</topic><topic>Thermal properties of crystalline solids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Farnum, Gregory A</creatorcontrib><creatorcontrib>Pochodylo, Amy L</creatorcontrib><creatorcontrib>LaDuca, Robert L</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Crystal growth & design</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Farnum, Gregory A</au><au>Pochodylo, Amy L</au><au>LaDuca, Robert L</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tether Length Control of Topology in Cadmium 4-Methylphthalate Two-Dimensional Coordination Polymers: An Acentric Buckled Grid and a Rare Self-Catenated Layer</atitle><jtitle>Crystal growth & design</jtitle><addtitle>Cryst. Growth Des</addtitle><date>2011-03-02</date><risdate>2011</risdate><volume>11</volume><issue>3</issue><spage>678</spage><epage>683</epage><pages>678-683</pages><issn>1528-7483</issn><eissn>1528-7505</eissn><abstract>Hydrothermal synthesis has afforded a pair of dual-ligand divalent cadmium 4-methylphthalate (mph) two-dimensional (2-D) coordination polymers, wherein the length of the dipyridyl co-ligand plays a predominant role in the overall structural topology. [Cd2(mph)2(dpe)4] n (1, dpe = 1,2-di(4-pyridyl)ethane) possesses an acentric buckled (4,4) grid topology, with a pendant, monodentate dpe ligand bound to each Cd atom. Use of a slightly longer dipyridyl tether allowed generation of the 2-D phase [Cd2(mph)2(dpp)3] n (2, dpp = 1,3-di(4-pyridyl)propane). The dpp ligands in 2 all bridge two cadmium atoms, promoting the formation of a very rare 4-connected 66 self-catenated layer topology. Luminescent and thermal properties of 1 and 2 are also discussed.</abstract><cop>Washington,DC</cop><pub>American Chemical Society</pub><doi>10.1021/cg100972s</doi><tpages>6</tpages></addata></record> |
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subjects | Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Physics Structure of solids and liquids crystallography Structure of specific crystalline solids Thermal expansion thermomechanical effects and density Thermal properties of condensed matter Thermal properties of crystalline solids |
title | Tether Length Control of Topology in Cadmium 4-Methylphthalate Two-Dimensional Coordination Polymers: An Acentric Buckled Grid and a Rare Self-Catenated Layer |
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