Three Novel Homochiral Helical Metal−Organic Frameworks Based on Amino Acid Ligand: Syntheses, Crystal Structures, and Properties
Three novel homochiral helical metal−organic frameworks (MOFs), namely [Zn(LTP)2] n (1), [Cd(LTP)2] n (2), and [Ni(LTP)2] n (3) (LTP = l-thioproline), have been synthesized and characterized. X-ray crystallographic analysis shows that all the three complexes consist of homochiral left-handed or righ...
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| Veröffentlicht in: | Crystal growth & design 2011-01, Vol.11 (1), p.93-99 |
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| creator | Dong, Lanjun Chu, Wei Zhu, Qinlei Huang, Rudan |
| description | Three novel homochiral helical metal−organic frameworks (MOFs), namely [Zn(LTP)2] n (1), [Cd(LTP)2] n (2), and [Ni(LTP)2] n (3) (LTP = l-thioproline), have been synthesized and characterized. X-ray crystallographic analysis shows that all the three complexes consist of homochiral left-handed or right-handed helical chains. Complex 1 exhibits 1-D Zn-carboxyl right-handed helical chains constructed by pentacoordinated Zn2+ ions. Complex 2 shows a 2-D homochiral coordination framework with (4, 4) topology based on Cd-carboxyl right-handed helical chains in which Cd2+ ions are 6-fold coordinated. There are various hydrogen bonds between the adjacent helical chains in 1 and 2 which connect them into 3-D supramolecular networks. Complex 3 also exhibits a 2-D homochiral layer structure with (4, 4) topology containing Ni-carboxyl left-handed helical chains. The luminescence properties of 1 and 2 have been investigated briefly. |
| doi_str_mv | 10.1021/cg1009175 |
| format | Article |
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X-ray crystallographic analysis shows that all the three complexes consist of homochiral left-handed or right-handed helical chains. Complex 1 exhibits 1-D Zn-carboxyl right-handed helical chains constructed by pentacoordinated Zn2+ ions. Complex 2 shows a 2-D homochiral coordination framework with (4, 4) topology based on Cd-carboxyl right-handed helical chains in which Cd2+ ions are 6-fold coordinated. There are various hydrogen bonds between the adjacent helical chains in 1 and 2 which connect them into 3-D supramolecular networks. Complex 3 also exhibits a 2-D homochiral layer structure with (4, 4) topology containing Ni-carboxyl left-handed helical chains. 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Growth Des</addtitle><description>Three novel homochiral helical metal−organic frameworks (MOFs), namely [Zn(LTP)2] n (1), [Cd(LTP)2] n (2), and [Ni(LTP)2] n (3) (LTP = l-thioproline), have been synthesized and characterized. X-ray crystallographic analysis shows that all the three complexes consist of homochiral left-handed or right-handed helical chains. Complex 1 exhibits 1-D Zn-carboxyl right-handed helical chains constructed by pentacoordinated Zn2+ ions. Complex 2 shows a 2-D homochiral coordination framework with (4, 4) topology based on Cd-carboxyl right-handed helical chains in which Cd2+ ions are 6-fold coordinated. There are various hydrogen bonds between the adjacent helical chains in 1 and 2 which connect them into 3-D supramolecular networks. Complex 3 also exhibits a 2-D homochiral layer structure with (4, 4) topology containing Ni-carboxyl left-handed helical chains. The luminescence properties of 1 and 2 have been investigated briefly.</description><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Exact sciences and technology</subject><subject>Materials science</subject><subject>Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation</subject><subject>Optical properties of bulk materials and thin films</subject><subject>Organic compounds</subject><subject>Other materials</subject><subject>Physics</subject><subject>Specific materials</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><issn>1528-7483</issn><issn>1528-7505</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNptkDFPwzAQhS0EEqUw8A-8MCARsOM4MWylohSpUKSWOXKcc-uSxJWdgjqzMPMT-SW4KnRieu9O3z3pHkKnlFxSEtMrNaOEXNOM76EO5bGIMk74_p9PBDtER94vCCFZylgHfUznDgA_2Teo8NDWVs2Nk8FCZVTQR2hl9f35NXYz2RiFB07W8G7dq8e30kOJbYN7tWks7ilT4pEJWHmDJ-umnYMHf4H7bu1DBp60bqXaldvsAoOfnV2Caw34Y3SgZeXh5Fe76GVwN-0Po9H4_qHfG0UyFtdtpGXCCs3DQFKhQBScgy4o18CUoEJlcSxKmrBSxkVG00IKWmpQBVOSJEAZ66Lzba5y1nsHOl86U0u3zinJN-3lu_YCe7Zll9KHHrSTjTJ-dxCzLCFpqHPHSeXzhV25JnzwT94PJOF9eg</recordid><startdate>20110105</startdate><enddate>20110105</enddate><creator>Dong, Lanjun</creator><creator>Chu, Wei</creator><creator>Zhu, Qinlei</creator><creator>Huang, Rudan</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20110105</creationdate><title>Three Novel Homochiral Helical Metal−Organic Frameworks Based on Amino Acid Ligand: Syntheses, Crystal Structures, and Properties</title><author>Dong, Lanjun ; Chu, Wei ; Zhu, Qinlei ; Huang, Rudan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a289t-fa43bf5a28068ce8b55efb15fe3c818c7228d143da2b716ba81dfecb3ca04e133</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Exact sciences and technology</topic><topic>Materials science</topic><topic>Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation</topic><topic>Optical properties of bulk materials and thin films</topic><topic>Organic compounds</topic><topic>Other materials</topic><topic>Physics</topic><topic>Specific materials</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dong, Lanjun</creatorcontrib><creatorcontrib>Chu, Wei</creatorcontrib><creatorcontrib>Zhu, Qinlei</creatorcontrib><creatorcontrib>Huang, Rudan</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Crystal growth & design</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dong, Lanjun</au><au>Chu, Wei</au><au>Zhu, Qinlei</au><au>Huang, Rudan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Three Novel Homochiral Helical Metal−Organic Frameworks Based on Amino Acid Ligand: Syntheses, Crystal Structures, and Properties</atitle><jtitle>Crystal growth & design</jtitle><addtitle>Cryst. Growth Des</addtitle><date>2011-01-05</date><risdate>2011</risdate><volume>11</volume><issue>1</issue><spage>93</spage><epage>99</epage><pages>93-99</pages><issn>1528-7483</issn><eissn>1528-7505</eissn><abstract>Three novel homochiral helical metal−organic frameworks (MOFs), namely [Zn(LTP)2] n (1), [Cd(LTP)2] n (2), and [Ni(LTP)2] n (3) (LTP = l-thioproline), have been synthesized and characterized. X-ray crystallographic analysis shows that all the three complexes consist of homochiral left-handed or right-handed helical chains. Complex 1 exhibits 1-D Zn-carboxyl right-handed helical chains constructed by pentacoordinated Zn2+ ions. Complex 2 shows a 2-D homochiral coordination framework with (4, 4) topology based on Cd-carboxyl right-handed helical chains in which Cd2+ ions are 6-fold coordinated. There are various hydrogen bonds between the adjacent helical chains in 1 and 2 which connect them into 3-D supramolecular networks. Complex 3 also exhibits a 2-D homochiral layer structure with (4, 4) topology containing Ni-carboxyl left-handed helical chains. The luminescence properties of 1 and 2 have been investigated briefly.</abstract><cop>Washington,DC</cop><pub>American Chemical Society</pub><doi>10.1021/cg1009175</doi><tpages>7</tpages></addata></record> |
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| subjects | Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science rheology Exact sciences and technology Materials science Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation Optical properties of bulk materials and thin films Organic compounds Other materials Physics Specific materials Structure of solids and liquids crystallography Structure of specific crystalline solids |
| title | Three Novel Homochiral Helical Metal−Organic Frameworks Based on Amino Acid Ligand: Syntheses, Crystal Structures, and Properties |
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