Crystallization-Induced Asymmetric Transformations in Crotyl Molybdenum Complexes

Crystallization-Induced Asymmetric Transformations in Crotyl Molybdenum Complexes

Equilibria between epimers and diastereomers of pseudo-octahedral crotyl molybdenum complexes that contain bisphosphines occur in solution. Epimerization of the crotyl-molybdenum moiety is slow (t 1/2 = 7 h at 15 °C). Crystallization yields a single diastereomer, and this system provides a set of ch...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Crystal growth & design 2005-11, Vol.5 (6), p.2356-2361
Hauptverfasser: Faller, J. W, Sarantopoulos, Nikos
Format: Artikel
Sprache:eng
Schlagworte:
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Materials science
Methods of crystal growth
physics of crystal growth
Physics
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 2361
container_issue 6
container_start_page 2356
container_title Crystal growth & design
container_volume 5
creator Faller, J. W
Sarantopoulos, Nikos
description Equilibria between epimers and diastereomers of pseudo-octahedral crotyl molybdenum complexes that contain bisphosphines occur in solution. Epimerization of the crotyl-molybdenum moiety is slow (t 1/2 = 7 h at 15 °C). Crystallization yields a single diastereomer, and this system provides a set of chiral nonracemic η3-crotyl complexes that can be easily handled and preserved for a reasonable time in solution at convenient temperatures.
doi_str_mv 10.1021/cg050152b
format Article
fullrecord <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_cg050152b</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c710206762</sourcerecordid><originalsourceid>FETCH-LOGICAL-a289t-f87299ae80b3eb34353a37c5e5aabf4a3f29ac844e0d5b828d3bc02f14adbdd63</originalsourceid><addsrcrecordid>eNptkD1PwzAYhC0EEqUw8A-8MDAEHDuunbGK-KhUhJDKHL3-QqmcOLJTifDrCRTownQ3PHfSHUKXObnJCc1v9RvhJOdUHaHZJDITnPDjX19IdorOUtoSQsSCsRl6qeKYBvC--YChCV226sxOW4OXaWxbO8RG402ELrkQ228i4abDVQzD6PFT8KMyttu1uApt7-27TefoxIFP9uJH5-j1_m5TPWbr54dVtVxnQGU5ZE4KWpZgJVHMKlYwzoAJzS0HUK4A5mgJWhaFJYYrSaVhShPq8gKMMmbB5uh636tjSClaV_exaSGOdU7qry_qvy8m9mrP9pA0eDcN0k06BASVREhx4ECneht2sZsW_NP3CSyabJU</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Crystallization-Induced Asymmetric Transformations in Crotyl Molybdenum Complexes</title><source>ACS Publications</source><creator>Faller, J. W ; Sarantopoulos, Nikos</creator><creatorcontrib>Faller, J. W ; Sarantopoulos, Nikos</creatorcontrib><description>Equilibria between epimers and diastereomers of pseudo-octahedral crotyl molybdenum complexes that contain bisphosphines occur in solution. Epimerization of the crotyl-molybdenum moiety is slow (t 1/2 = 7 h at 15 °C). Crystallization yields a single diastereomer, and this system provides a set of chiral nonracemic η3-crotyl complexes that can be easily handled and preserved for a reasonable time in solution at convenient temperatures.</description><identifier>ISSN: 1528-7483</identifier><identifier>EISSN: 1528-7505</identifier><identifier>DOI: 10.1021/cg050152b</identifier><language>eng</language><publisher>Washington,DC: American Chemical Society</publisher><subject>Cross-disciplinary physics: materials science; rheology ; Exact sciences and technology ; Materials science ; Methods of crystal growth; physics of crystal growth ; Physics</subject><ispartof>Crystal growth &amp; design, 2005-11, Vol.5 (6), p.2356-2361</ispartof><rights>Copyright © 2005 American Chemical Society</rights><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a289t-f87299ae80b3eb34353a37c5e5aabf4a3f29ac844e0d5b828d3bc02f14adbdd63</citedby><cites>FETCH-LOGICAL-a289t-f87299ae80b3eb34353a37c5e5aabf4a3f29ac844e0d5b828d3bc02f14adbdd63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/cg050152b$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/cg050152b$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2763,27075,27923,27924,56737,56787</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=17280787$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Faller, J. W</creatorcontrib><creatorcontrib>Sarantopoulos, Nikos</creatorcontrib><title>Crystallization-Induced Asymmetric Transformations in Crotyl Molybdenum Complexes</title><title>Crystal growth &amp; design</title><addtitle>Cryst. Growth Des</addtitle><description>Equilibria between epimers and diastereomers of pseudo-octahedral crotyl molybdenum complexes that contain bisphosphines occur in solution. Epimerization of the crotyl-molybdenum moiety is slow (t 1/2 = 7 h at 15 °C). Crystallization yields a single diastereomer, and this system provides a set of chiral nonracemic η3-crotyl complexes that can be easily handled and preserved for a reasonable time in solution at convenient temperatures.</description><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Exact sciences and technology</subject><subject>Materials science</subject><subject>Methods of crystal growth; physics of crystal growth</subject><subject>Physics</subject><issn>1528-7483</issn><issn>1528-7505</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNptkD1PwzAYhC0EEqUw8A-8MDAEHDuunbGK-KhUhJDKHL3-QqmcOLJTifDrCRTownQ3PHfSHUKXObnJCc1v9RvhJOdUHaHZJDITnPDjX19IdorOUtoSQsSCsRl6qeKYBvC--YChCV226sxOW4OXaWxbO8RG402ELrkQ228i4abDVQzD6PFT8KMyttu1uApt7-27TefoxIFP9uJH5-j1_m5TPWbr54dVtVxnQGU5ZE4KWpZgJVHMKlYwzoAJzS0HUK4A5mgJWhaFJYYrSaVhShPq8gKMMmbB5uh636tjSClaV_exaSGOdU7qry_qvy8m9mrP9pA0eDcN0k06BASVREhx4ECneht2sZsW_NP3CSyabJU</recordid><startdate>20051101</startdate><enddate>20051101</enddate><creator>Faller, J. W</creator><creator>Sarantopoulos, Nikos</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20051101</creationdate><title>Crystallization-Induced Asymmetric Transformations in Crotyl Molybdenum Complexes</title><author>Faller, J. W ; Sarantopoulos, Nikos</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a289t-f87299ae80b3eb34353a37c5e5aabf4a3f29ac844e0d5b828d3bc02f14adbdd63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Exact sciences and technology</topic><topic>Materials science</topic><topic>Methods of crystal growth; physics of crystal growth</topic><topic>Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Faller, J. W</creatorcontrib><creatorcontrib>Sarantopoulos, Nikos</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Crystal growth &amp; design</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Faller, J. W</au><au>Sarantopoulos, Nikos</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystallization-Induced Asymmetric Transformations in Crotyl Molybdenum Complexes</atitle><jtitle>Crystal growth &amp; design</jtitle><addtitle>Cryst. Growth Des</addtitle><date>2005-11-01</date><risdate>2005</risdate><volume>5</volume><issue>6</issue><spage>2356</spage><epage>2361</epage><pages>2356-2361</pages><issn>1528-7483</issn><eissn>1528-7505</eissn><abstract>Equilibria between epimers and diastereomers of pseudo-octahedral crotyl molybdenum complexes that contain bisphosphines occur in solution. Epimerization of the crotyl-molybdenum moiety is slow (t 1/2 = 7 h at 15 °C). Crystallization yields a single diastereomer, and this system provides a set of chiral nonracemic η3-crotyl complexes that can be easily handled and preserved for a reasonable time in solution at convenient temperatures.</abstract><cop>Washington,DC</cop><pub>American Chemical Society</pub><doi>10.1021/cg050152b</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1528-7483
ispartof Crystal growth & design, 2005-11, Vol.5 (6), p.2356-2361
issn 1528-7483
1528-7505
language eng
recordid cdi_crossref_primary_10_1021_cg050152b
source ACS Publications
subjects Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Materials science
Methods of crystal growth
physics of crystal growth
Physics
title Crystallization-Induced Asymmetric Transformations in Crotyl Molybdenum Complexes
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-12T05%3A21%3A12IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Crystallization-Induced%20Asymmetric%20Transformations%20in%20Crotyl%20Molybdenum%20Complexes&rft.jtitle=Crystal%20growth%20&%20design&rft.au=Faller,%20J.%20W&rft.date=2005-11-01&rft.volume=5&rft.issue=6&rft.spage=2356&rft.epage=2361&rft.pages=2356-2361&rft.issn=1528-7483&rft.eissn=1528-7505&rft_id=info:doi/10.1021/cg050152b&rft_dat=%3Cacs_cross%3Ec710206762%3C/acs_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true