Synthesis and X-ray Structures of Zinc and Cadmium Pyridinecarboxylate Coordination Networks
New zinc(II) and cadmium(II) coordination polymers with 3-[2-(3-pyridyl)ethenyl]benzoato (L) bridging ligands have been synthesized by treating the metal salts and 3-[2-(3-pyridyl)ethenyl]benzonitrile under hydro(solvo)thermal conditions. [Zn(L)2]·(pyridine), 1, adopts a 1D polymeric structure built...
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| Veröffentlicht in: | Crystal growth & design 2002-09, Vol.2 (5), p.409-414 |
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| description | New zinc(II) and cadmium(II) coordination polymers with 3-[2-(3-pyridyl)ethenyl]benzoato (L) bridging ligands have been synthesized by treating the metal salts and 3-[2-(3-pyridyl)ethenyl]benzonitrile under hydro(solvo)thermal conditions. [Zn(L)2]·(pyridine), 1, adopts a 1D polymeric structure built from mutually perpendicular 22-membered macrocycles. Large open channels formed in 1 are filled with included pyridine guest molecules. Both [Cd2(L)3(NO3)], 2, and [Cd4(L)6(ClO4)2(MeOH)2]·(H2O), 3, adopt complicated 2D polymeric structures that are built from carboxylate-bridged tetracadmium and dicadmium building units, respectively. Crystal data for 1: triclinic space group P1̄, a = 8.601(1), b = 12.364(1), c = 14.224(1) Å, α = 72.687(1), β = 88.118(1), γ = 71.679(1)°, Z = 2. Crystal data for 2: triclinic space group P1̄, a = 10.675(1), b = 12.671(1), c = 14.838(1) Å, α = 74.772(1), β = 88.283(1), γ = 73.671(1)°, Z = 2. Crystal data for 3: monoclinic space group P21, a = 13.165(3), b = 20.119(9), c = 15.446(6) Å, β = 95.19(3), Z = 2. |
| doi_str_mv | 10.1021/cg0200208 |
| format | Article |
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[Zn(L)2]·(pyridine), 1, adopts a 1D polymeric structure built from mutually perpendicular 22-membered macrocycles. Large open channels formed in 1 are filled with included pyridine guest molecules. Both [Cd2(L)3(NO3)], 2, and [Cd4(L)6(ClO4)2(MeOH)2]·(H2O), 3, adopt complicated 2D polymeric structures that are built from carboxylate-bridged tetracadmium and dicadmium building units, respectively. Crystal data for 1: triclinic space group P1̄, a = 8.601(1), b = 12.364(1), c = 14.224(1) Å, α = 72.687(1), β = 88.118(1), γ = 71.679(1)°, Z = 2. Crystal data for 2: triclinic space group P1̄, a = 10.675(1), b = 12.671(1), c = 14.838(1) Å, α = 74.772(1), β = 88.283(1), γ = 73.671(1)°, Z = 2. Crystal data for 3: monoclinic space group P21, a = 13.165(3), b = 20.119(9), c = 15.446(6) Å, β = 95.19(3), Z = 2.</description><identifier>ISSN: 1528-7483</identifier><identifier>EISSN: 1528-7505</identifier><identifier>DOI: 10.1021/cg0200208</identifier><language>eng</language><publisher>Washington,DC: American Chemical Society</publisher><subject>Condensed matter: structure, mechanical and thermal properties ; Exact sciences and technology ; Inorganic compounds ; Metal complexes ; Physics ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids</subject><ispartof>Crystal growth & design, 2002-09, Vol.2 (5), p.409-414</ispartof><rights>Copyright © 2002 American Chemical Society</rights><rights>2003 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a287t-3f93575f3c96a43f0e2f20c8cead9c61dcdaf896c27cabb0f43b1c60918b1e913</citedby><cites>FETCH-LOGICAL-a287t-3f93575f3c96a43f0e2f20c8cead9c61dcdaf896c27cabb0f43b1c60918b1e913</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/cg0200208$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/cg0200208$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>309,310,314,776,780,785,786,2752,23909,23910,25118,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=14404864$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Lin, Wenbin</creatorcontrib><creatorcontrib>Evans, Owen R</creatorcontrib><creatorcontrib>Cui, Yong</creatorcontrib><title>Synthesis and X-ray Structures of Zinc and Cadmium Pyridinecarboxylate Coordination Networks</title><title>Crystal growth & design</title><addtitle>Cryst. Growth Des</addtitle><description>New zinc(II) and cadmium(II) coordination polymers with 3-[2-(3-pyridyl)ethenyl]benzoato (L) bridging ligands have been synthesized by treating the metal salts and 3-[2-(3-pyridyl)ethenyl]benzonitrile under hydro(solvo)thermal conditions. [Zn(L)2]·(pyridine), 1, adopts a 1D polymeric structure built from mutually perpendicular 22-membered macrocycles. Large open channels formed in 1 are filled with included pyridine guest molecules. Both [Cd2(L)3(NO3)], 2, and [Cd4(L)6(ClO4)2(MeOH)2]·(H2O), 3, adopt complicated 2D polymeric structures that are built from carboxylate-bridged tetracadmium and dicadmium building units, respectively. Crystal data for 1: triclinic space group P1̄, a = 8.601(1), b = 12.364(1), c = 14.224(1) Å, α = 72.687(1), β = 88.118(1), γ = 71.679(1)°, Z = 2. Crystal data for 2: triclinic space group P1̄, a = 10.675(1), b = 12.671(1), c = 14.838(1) Å, α = 74.772(1), β = 88.283(1), γ = 73.671(1)°, Z = 2. Crystal data for 3: monoclinic space group P21, a = 13.165(3), b = 20.119(9), c = 15.446(6) Å, β = 95.19(3), Z = 2.</description><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Exact sciences and technology</subject><subject>Inorganic compounds</subject><subject>Metal complexes</subject><subject>Physics</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><issn>1528-7483</issn><issn>1528-7505</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><recordid>eNptkE1LxDAQhoMouK4e_Ae5ePBQTZp-pEcpfsGiwiqICGU6TTRrt1mSFO2_t7rqXoSBGd555oV5CTnk7ISzmJ_iC4vZWHKLTHgayyhPWbr9OydS7JI97xeMsTwTYkKe50MXXpU3nkLX0MfIwUDnwfUYeqc8tZo-mQ6_lyU0S9Mv6d3gTGM6heBq-zG0EBQtrXWjBsHYjt6o8G7dm98nOxparw5--pQ8XJzfl1fR7PbyujybRRDLPERCFyLNUy2wyCARmqlYxwwlKmgKzHiDDWhZZBjnCHXNdCJqjhkruKy5KriYkuO1LzrrvVO6WjmzBDdUnFVfsVR_sYzs0ZpdgUdotYMOjd8cJAlLZJZsOEBfLWzvuvGDf_w-AWwvby8</recordid><startdate>20020901</startdate><enddate>20020901</enddate><creator>Lin, Wenbin</creator><creator>Evans, Owen R</creator><creator>Cui, Yong</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20020901</creationdate><title>Synthesis and X-ray Structures of Zinc and Cadmium Pyridinecarboxylate Coordination Networks</title><author>Lin, Wenbin ; Evans, Owen R ; Cui, Yong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a287t-3f93575f3c96a43f0e2f20c8cead9c61dcdaf896c27cabb0f43b1c60918b1e913</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Exact sciences and technology</topic><topic>Inorganic compounds</topic><topic>Metal complexes</topic><topic>Physics</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lin, Wenbin</creatorcontrib><creatorcontrib>Evans, Owen R</creatorcontrib><creatorcontrib>Cui, Yong</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Crystal growth & design</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lin, Wenbin</au><au>Evans, Owen R</au><au>Cui, Yong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and X-ray Structures of Zinc and Cadmium Pyridinecarboxylate Coordination Networks</atitle><jtitle>Crystal growth & design</jtitle><addtitle>Cryst. Growth Des</addtitle><date>2002-09-01</date><risdate>2002</risdate><volume>2</volume><issue>5</issue><spage>409</spage><epage>414</epage><pages>409-414</pages><issn>1528-7483</issn><eissn>1528-7505</eissn><abstract>New zinc(II) and cadmium(II) coordination polymers with 3-[2-(3-pyridyl)ethenyl]benzoato (L) bridging ligands have been synthesized by treating the metal salts and 3-[2-(3-pyridyl)ethenyl]benzonitrile under hydro(solvo)thermal conditions. [Zn(L)2]·(pyridine), 1, adopts a 1D polymeric structure built from mutually perpendicular 22-membered macrocycles. Large open channels formed in 1 are filled with included pyridine guest molecules. Both [Cd2(L)3(NO3)], 2, and [Cd4(L)6(ClO4)2(MeOH)2]·(H2O), 3, adopt complicated 2D polymeric structures that are built from carboxylate-bridged tetracadmium and dicadmium building units, respectively. Crystal data for 1: triclinic space group P1̄, a = 8.601(1), b = 12.364(1), c = 14.224(1) Å, α = 72.687(1), β = 88.118(1), γ = 71.679(1)°, Z = 2. Crystal data for 2: triclinic space group P1̄, a = 10.675(1), b = 12.671(1), c = 14.838(1) Å, α = 74.772(1), β = 88.283(1), γ = 73.671(1)°, Z = 2. Crystal data for 3: monoclinic space group P21, a = 13.165(3), b = 20.119(9), c = 15.446(6) Å, β = 95.19(3), Z = 2.</abstract><cop>Washington,DC</cop><pub>American Chemical Society</pub><doi>10.1021/cg0200208</doi><tpages>6</tpages></addata></record> |
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| subjects | Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Inorganic compounds Metal complexes Physics Structure of solids and liquids crystallography Structure of specific crystalline solids |
| title | Synthesis and X-ray Structures of Zinc and Cadmium Pyridinecarboxylate Coordination Networks |
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