Photochemical heavy-atom effects
The effects of halogenated solvents such as n-butyl chloride, n-propyl bromide, and ethyl iodide, on the photochemistry of several aromatic compounds are reviewed. Dimerization of acenaphthylene is discussed in terms of spin -orbit coupling induced by the solvents. Appropriate wave functions are giv...
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| Veröffentlicht in: | Acc. Chem. Res.; (United States) 1978-09, Vol.11 (9), p.334-341 |
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| container_end_page | 341 |
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| container_issue | 9 |
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| container_title | Acc. Chem. Res.; (United States) |
| container_volume | 11 |
| creator | Koziar, Joseph C Cowan, Dwaine O |
| description | The effects of halogenated solvents such as n-butyl chloride, n-propyl bromide, and ethyl iodide, on the photochemistry of several aromatic compounds are reviewed. Dimerization of acenaphthylene is discussed in terms of spin -orbit coupling induced by the solvents. Appropriate wave functions are given for both the solvents and the compound. Cycloaddition reactions, electrocyclic rearrangements, and photochemical cis-trans isomerization are also considered. |
| doi_str_mv | 10.1021/ar50129a003 |
| format | Article |
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Dimerization of acenaphthylene is discussed in terms of spin -orbit coupling induced by the solvents. Appropriate wave functions are given for both the solvents and the compound. Cycloaddition reactions, electrocyclic rearrangements, and photochemical cis-trans isomerization are also considered.</description><identifier>ISSN: 0001-4842</identifier><identifier>EISSN: 1520-4898</identifier><identifier>DOI: 10.1021/ar50129a003</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) ; 400500 - Photochemistry ; AROMATICS ; CHEMICAL REACTIONS ; CHEMISTRY ; CONDENSED AROMATICS ; COUPLING ; DECOMPOSITION ; DIMERIZATION ; DOCUMENT TYPES ; HALOGENATED ALIPHATIC HYDROCARBONS ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; INTERMEDIATE COUPLING ; ISOMERIZATION ; L-S COUPLING ; ORGANIC COMPOUNDS ; ORGANIC HALOGEN COMPOUNDS ; ORGANIC SOLVENTS ; PHOTOCHEMICAL REACTIONS ; PHOTOCHEMISTRY ; PHOTOLYSIS ; POLYMERIZATION ; REVIEWS ; SOLVENTS</subject><ispartof>Acc. Chem. 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| ispartof | Acc. Chem. Res.; (United States), 1978-09, Vol.11 (9), p.334-341 |
| issn | 0001-4842 1520-4898 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_ar50129a003 |
| source | American Chemical Society Journals |
| subjects | 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) 400500 - Photochemistry AROMATICS CHEMICAL REACTIONS CHEMISTRY CONDENSED AROMATICS COUPLING DECOMPOSITION DIMERIZATION DOCUMENT TYPES HALOGENATED ALIPHATIC HYDROCARBONS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY INTERMEDIATE COUPLING ISOMERIZATION L-S COUPLING ORGANIC COMPOUNDS ORGANIC HALOGEN COMPOUNDS ORGANIC SOLVENTS PHOTOCHEMICAL REACTIONS PHOTOCHEMISTRY PHOTOLYSIS POLYMERIZATION REVIEWS SOLVENTS |
| title | Photochemical heavy-atom effects |
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