A Novel Approach to the Efficient Oxygenation of Hydrocarbons under Mild Conditions. Superior Oxo Transfer Selectivity Using Dioxiranes

The design of efficient and general methods for the selective oxyfunctionalization of unactivated carbon−hydrogen bonds continues to represent a major challenge for the community of chemists, despite the fact that the oxidation of alkanes is a major feature of the chemical economy. A low level of se...

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Veröffentlicht in:	Accounts of chemical research 2006-01, Vol.39 (1), p.1-9
Hauptverfasser:	Curci, Ruggero, D'Accolti, Lucia, Fusco, Caterina
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkanes - chemistry Alkanes - metabolism Epoxy Compounds - chemistry Hydroxylation Models, Molecular Oxidants - chemistry Oxidation-Reduction Stereoisomerism
Online-Zugang:	Volltext
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