From Recovered Palladium to Molecular and Nanoscale Catalysts

[PdI2(Me2dazdt)] is obtained from palladium powder via a 100% atom-economical Pd(0) leaching reaction using Me2dazdt (N,N′-dimethyl-perhydrodiazepine-2,3-dithione) and iodine. This complex is a versatile starting point for ligand exchange reactions with (di)­phosphines, yielding trans-[PdI2(PPh3)2]...

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Veröffentlicht in:ACS sustainable chemistry & engineering 2019-07, Vol.7 (14), p.12389-12398, Article acssuschemeng.9b01877
Hauptverfasser: Jantan, Khairil A, Chan, Kuang Wen, Melis, Laura, White, Andrew J. P, Marchiò, Luciano, Deplano, Paola, Serpe, Angela, Wilton-Ely, James D. E. T
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Sprache:eng
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