Ligand Free Heterogeneous Sonogashira Cross-Coupling Reaction over an in Situ Organoiodine Capsulized Palladium Anchored to a Perovskite Catalyst

Ligand Free Heterogeneous Sonogashira Cross-Coupling Reaction over an in Situ Organoiodine Capsulized Palladium Anchored to a Perovskite Catalyst

An environmentally friendly Sonogashira cross-coupling reaction is described in this study with high potential for application in a fluidized system. The LaCo0.9Ni0.05Pd0.05O3 perovskite based catalyst provided a high turnover frequency (TOF) of 900 h–1 via mainly a heterogeneous mechanism in an env...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:ACS sustainable chemistry & engineering 2019-08, Vol.7 (15), p.12697-12706
Hauptverfasser: Alapour, Saba, Farahani, Majid D, Ramjugernath, Deresh, Koorbanally, Neil A, Friedrich, Holger B
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 12706
container_issue 15
container_start_page 12697
container_title ACS sustainable chemistry & engineering
container_volume 7
creator Alapour, Saba
Farahani, Majid D
Ramjugernath, Deresh
Koorbanally, Neil A
Friedrich, Holger B
description An environmentally friendly Sonogashira cross-coupling reaction is described in this study with high potential for application in a fluidized system. The LaCo0.9Ni0.05Pd0.05O3 perovskite based catalyst provided a high turnover frequency (TOF) of 900 h–1 via mainly a heterogeneous mechanism in an environmentally friendly mixed medium of water and acetonitrile. Nanosized Pd(0) sites were anchored to the surface of perovskite using an in situ formed colloidal agent. This capsulizing agent was found to consist of organic compounds containing iodine atoms that interacted strongly with basic sites of the hydrophobic perovskite carrier using adsorption forces. This study illustrates a unique and strong principle for designing green heterogeneous catalysts for common valuable organic reactions.
doi_str_mv 10.1021/acssuschemeng.8b05772
format Article
fullrecord <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_acssuschemeng_8b05772</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>h42904660</sourcerecordid><originalsourceid>FETCH-LOGICAL-a361t-1bdaedd9c783e1d3e932ea17247b44a3888d549a1dd728bfd35ee2ef6d6bcec3</originalsourceid><addsrcrecordid>eNqFUNtuwjAMraZNGmJ8wqT8QFnTa_qIqjEmIYEG75WbuCWsJChJkdhf7I8XBA_b0_xiy_Y59jlB8EyjKY1i-gLc2sHyHR5QdVPWRFlRxHfBKKY5C6OUZfe_6sdgYu0-8lGWSczoKPheyg6UIHODSBbo0OgOFerBko1WugO7kwZIZbS1YaWHYy9VRz4QuJNaEX1CQ0ARqchGuoGsjGfTUgupkFRwtEMvv1CQNfQ9CDkcyEzxnTa-5TQBsvb3TvZTusu2g_5s3VPw0EJvcXLL42A7f91Wi3C5enuvZssQkpy6kDYCUIiSFyxBKhL0ghBoEadFk6aQMMZElpZAhShi1rQiyRBjbHORNxx5Mg6yKy2_SDPY1kcjD2DONY3qi7P1H2frm7MeR684P673ejDKP_kP5geCBoZC</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Ligand Free Heterogeneous Sonogashira Cross-Coupling Reaction over an in Situ Organoiodine Capsulized Palladium Anchored to a Perovskite Catalyst</title><source>American Chemical Society Journals</source><creator>Alapour, Saba ; Farahani, Majid D ; Ramjugernath, Deresh ; Koorbanally, Neil A ; Friedrich, Holger B</creator><creatorcontrib>Alapour, Saba ; Farahani, Majid D ; Ramjugernath, Deresh ; Koorbanally, Neil A ; Friedrich, Holger B</creatorcontrib><description>An environmentally friendly Sonogashira cross-coupling reaction is described in this study with high potential for application in a fluidized system. The LaCo0.9Ni0.05Pd0.05O3 perovskite based catalyst provided a high turnover frequency (TOF) of 900 h–1 via mainly a heterogeneous mechanism in an environmentally friendly mixed medium of water and acetonitrile. Nanosized Pd(0) sites were anchored to the surface of perovskite using an in situ formed colloidal agent. This capsulizing agent was found to consist of organic compounds containing iodine atoms that interacted strongly with basic sites of the hydrophobic perovskite carrier using adsorption forces. This study illustrates a unique and strong principle for designing green heterogeneous catalysts for common valuable organic reactions.</description><identifier>ISSN: 2168-0485</identifier><identifier>EISSN: 2168-0485</identifier><identifier>DOI: 10.1021/acssuschemeng.8b05772</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>ACS sustainable chemistry &amp; engineering, 2019-08, Vol.7 (15), p.12697-12706</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a361t-1bdaedd9c783e1d3e932ea17247b44a3888d549a1dd728bfd35ee2ef6d6bcec3</citedby><cites>FETCH-LOGICAL-a361t-1bdaedd9c783e1d3e932ea17247b44a3888d549a1dd728bfd35ee2ef6d6bcec3</cites><orcidid>0000-0002-6214-4021 ; 0000-0002-1329-0815 ; 0000-0002-1971-0120 ; 0000-0003-3447-7846</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acssuschemeng.8b05772$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acssuschemeng.8b05772$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids></links><search><creatorcontrib>Alapour, Saba</creatorcontrib><creatorcontrib>Farahani, Majid D</creatorcontrib><creatorcontrib>Ramjugernath, Deresh</creatorcontrib><creatorcontrib>Koorbanally, Neil A</creatorcontrib><creatorcontrib>Friedrich, Holger B</creatorcontrib><title>Ligand Free Heterogeneous Sonogashira Cross-Coupling Reaction over an in Situ Organoiodine Capsulized Palladium Anchored to a Perovskite Catalyst</title><title>ACS sustainable chemistry &amp; engineering</title><addtitle>ACS Sustainable Chem. Eng</addtitle><description>An environmentally friendly Sonogashira cross-coupling reaction is described in this study with high potential for application in a fluidized system. The LaCo0.9Ni0.05Pd0.05O3 perovskite based catalyst provided a high turnover frequency (TOF) of 900 h–1 via mainly a heterogeneous mechanism in an environmentally friendly mixed medium of water and acetonitrile. Nanosized Pd(0) sites were anchored to the surface of perovskite using an in situ formed colloidal agent. This capsulizing agent was found to consist of organic compounds containing iodine atoms that interacted strongly with basic sites of the hydrophobic perovskite carrier using adsorption forces. This study illustrates a unique and strong principle for designing green heterogeneous catalysts for common valuable organic reactions.</description><issn>2168-0485</issn><issn>2168-0485</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFUNtuwjAMraZNGmJ8wqT8QFnTa_qIqjEmIYEG75WbuCWsJChJkdhf7I8XBA_b0_xiy_Y59jlB8EyjKY1i-gLc2sHyHR5QdVPWRFlRxHfBKKY5C6OUZfe_6sdgYu0-8lGWSczoKPheyg6UIHODSBbo0OgOFerBko1WugO7kwZIZbS1YaWHYy9VRz4QuJNaEX1CQ0ARqchGuoGsjGfTUgupkFRwtEMvv1CQNfQ9CDkcyEzxnTa-5TQBsvb3TvZTusu2g_5s3VPw0EJvcXLL42A7f91Wi3C5enuvZssQkpy6kDYCUIiSFyxBKhL0ghBoEadFk6aQMMZElpZAhShi1rQiyRBjbHORNxx5Mg6yKy2_SDPY1kcjD2DONY3qi7P1H2frm7MeR684P673ejDKP_kP5geCBoZC</recordid><startdate>20190805</startdate><enddate>20190805</enddate><creator>Alapour, Saba</creator><creator>Farahani, Majid D</creator><creator>Ramjugernath, Deresh</creator><creator>Koorbanally, Neil A</creator><creator>Friedrich, Holger B</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-6214-4021</orcidid><orcidid>https://orcid.org/0000-0002-1329-0815</orcidid><orcidid>https://orcid.org/0000-0002-1971-0120</orcidid><orcidid>https://orcid.org/0000-0003-3447-7846</orcidid></search><sort><creationdate>20190805</creationdate><title>Ligand Free Heterogeneous Sonogashira Cross-Coupling Reaction over an in Situ Organoiodine Capsulized Palladium Anchored to a Perovskite Catalyst</title><author>Alapour, Saba ; Farahani, Majid D ; Ramjugernath, Deresh ; Koorbanally, Neil A ; Friedrich, Holger B</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a361t-1bdaedd9c783e1d3e932ea17247b44a3888d549a1dd728bfd35ee2ef6d6bcec3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Alapour, Saba</creatorcontrib><creatorcontrib>Farahani, Majid D</creatorcontrib><creatorcontrib>Ramjugernath, Deresh</creatorcontrib><creatorcontrib>Koorbanally, Neil A</creatorcontrib><creatorcontrib>Friedrich, Holger B</creatorcontrib><collection>CrossRef</collection><jtitle>ACS sustainable chemistry &amp; engineering</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Alapour, Saba</au><au>Farahani, Majid D</au><au>Ramjugernath, Deresh</au><au>Koorbanally, Neil A</au><au>Friedrich, Holger B</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ligand Free Heterogeneous Sonogashira Cross-Coupling Reaction over an in Situ Organoiodine Capsulized Palladium Anchored to a Perovskite Catalyst</atitle><jtitle>ACS sustainable chemistry &amp; engineering</jtitle><addtitle>ACS Sustainable Chem. Eng</addtitle><date>2019-08-05</date><risdate>2019</risdate><volume>7</volume><issue>15</issue><spage>12697</spage><epage>12706</epage><pages>12697-12706</pages><issn>2168-0485</issn><eissn>2168-0485</eissn><abstract>An environmentally friendly Sonogashira cross-coupling reaction is described in this study with high potential for application in a fluidized system. The LaCo0.9Ni0.05Pd0.05O3 perovskite based catalyst provided a high turnover frequency (TOF) of 900 h–1 via mainly a heterogeneous mechanism in an environmentally friendly mixed medium of water and acetonitrile. Nanosized Pd(0) sites were anchored to the surface of perovskite using an in situ formed colloidal agent. This capsulizing agent was found to consist of organic compounds containing iodine atoms that interacted strongly with basic sites of the hydrophobic perovskite carrier using adsorption forces. This study illustrates a unique and strong principle for designing green heterogeneous catalysts for common valuable organic reactions.</abstract><pub>American Chemical Society</pub><doi>10.1021/acssuschemeng.8b05772</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-6214-4021</orcidid><orcidid>https://orcid.org/0000-0002-1329-0815</orcidid><orcidid>https://orcid.org/0000-0002-1971-0120</orcidid><orcidid>https://orcid.org/0000-0003-3447-7846</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 2168-0485
ispartof ACS sustainable chemistry & engineering, 2019-08, Vol.7 (15), p.12697-12706
issn 2168-0485
2168-0485
language eng
recordid cdi_crossref_primary_10_1021_acssuschemeng_8b05772
source American Chemical Society Journals
title Ligand Free Heterogeneous Sonogashira Cross-Coupling Reaction over an in Situ Organoiodine Capsulized Palladium Anchored to a Perovskite Catalyst
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-07T20%3A58%3A50IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Ligand%20Free%20Heterogeneous%20Sonogashira%20Cross-Coupling%20Reaction%20over%20an%20in%20Situ%20Organoiodine%20Capsulized%20Palladium%20Anchored%20to%20a%20Perovskite%20Catalyst&rft.jtitle=ACS%20sustainable%20chemistry%20&%20engineering&rft.au=Alapour,%20Saba&rft.date=2019-08-05&rft.volume=7&rft.issue=15&rft.spage=12697&rft.epage=12706&rft.pages=12697-12706&rft.issn=2168-0485&rft.eissn=2168-0485&rft_id=info:doi/10.1021/acssuschemeng.8b05772&rft_dat=%3Cacs_cross%3Eh42904660%3C/acs_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true