Dihydrolevoglucosenone (Cyrene) as a Biobased Green Alternative to Organic Solvents for the Preparation of Supramolecular Gels Consisting of Self-Assembling Dipeptide Derivatives

Dihydrolevoglucosenone (Cyrene) as a Biobased Green Alternative to Organic Solvents for the Preparation of Supramolecular Gels Consisting of Self-Assembling Dipeptide Derivatives

Herein, we describe the use of Cyrene, a biobased green solvent, to prepare supramolecular gels composed of self-assembling dipeptide derivatives. The gelation behavior was evaluated by using a conventional tube-inversion method. The basic properties, of the obtained supramolecular gels, including c...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:ACS sustainable chemistry & engineering 2024-01, Vol.12 (4), p.1420-1426
Hauptverfasser: Sugiura, Shintaro, Shintani, Yuki, Higashi, Sayuri L., Shibata, Aya, Ikeda, Masato
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 1426
container_issue 4
container_start_page 1420
container_title ACS sustainable chemistry & engineering
container_volume 12
creator Sugiura, Shintaro
Shintani, Yuki
Higashi, Sayuri L.
Shibata, Aya
Ikeda, Masato
description Herein, we describe the use of Cyrene, a biobased green solvent, to prepare supramolecular gels composed of self-assembling dipeptide derivatives. The gelation behavior was evaluated by using a conventional tube-inversion method. The basic properties, of the obtained supramolecular gels, including critical gel concentrations and viscoelastic properties, were assessed. In addition, the self-assembled fibrous network inside the gels was investigated via confocal laser scanning microscopy after fluorescence staining. The results offer important insights into the preparation of supramolecular gel-based materials with minimal environmental damage for practical applications.
doi_str_mv 10.1021/acssuschemeng.3c05026
format Article
fullrecord <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_acssuschemeng_3c05026</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c164504333</sourcerecordid><originalsourceid>FETCH-LOGICAL-a243t-2198d542ac3fd52303ee11a6000fcad40188efd82f6242b46691fde3f05697ec3</originalsourceid><addsrcrecordid>eNqFkM9OwzAMxisEEtPgEZB8hENHkv6hPY4NBhLSkIBzlaVOlylLqridtNfiCekGBzjhiy3bnz_5F0VXnE04E_xWKqKe1Bq36JpJoljGRH4SjQTPi5ilRXb6qz6PLok2bIiyTETBR9Hn3Kz3dfAWd76xvfKEzjuE69k-oMMbkAQS7o1fScIaFgHRwdR2GJzszA6h87AMjXRGwZu3O3QdgfYBujXCa8BWhmHPO_Aa3vo2yO1gpXorAyzQEsy8I0Odcc1xA62Op0S4XdlDa25abDtTI8wxmN3RkS6iMy0t4eVPHkcfjw_vs6f4Zbl4nk1fYinSpIsFL4s6S4VUia4zkbAEkXOZD89rJeuU8aJAXRdC5yIVqzTPS65rTDTL8vIOVTKOsu-7KniigLpqg9nKsK84qw7sqz_sqx_2g45_64ZxtfH9QMrSP5ovWLyRWQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Dihydrolevoglucosenone (Cyrene) as a Biobased Green Alternative to Organic Solvents for the Preparation of Supramolecular Gels Consisting of Self-Assembling Dipeptide Derivatives</title><source>ACS Publications</source><creator>Sugiura, Shintaro ; Shintani, Yuki ; Higashi, Sayuri L. ; Shibata, Aya ; Ikeda, Masato</creator><creatorcontrib>Sugiura, Shintaro ; Shintani, Yuki ; Higashi, Sayuri L. ; Shibata, Aya ; Ikeda, Masato</creatorcontrib><description>Herein, we describe the use of Cyrene, a biobased green solvent, to prepare supramolecular gels composed of self-assembling dipeptide derivatives. The gelation behavior was evaluated by using a conventional tube-inversion method. The basic properties, of the obtained supramolecular gels, including critical gel concentrations and viscoelastic properties, were assessed. In addition, the self-assembled fibrous network inside the gels was investigated via confocal laser scanning microscopy after fluorescence staining. The results offer important insights into the preparation of supramolecular gel-based materials with minimal environmental damage for practical applications.</description><identifier>ISSN: 2168-0485</identifier><identifier>EISSN: 2168-0485</identifier><identifier>DOI: 10.1021/acssuschemeng.3c05026</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>ACS sustainable chemistry &amp; engineering, 2024-01, Vol.12 (4), p.1420-1426</ispartof><rights>2024 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-a243t-2198d542ac3fd52303ee11a6000fcad40188efd82f6242b46691fde3f05697ec3</cites><orcidid>0000-0003-4097-8292 ; 0000-0001-8488-4808</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acssuschemeng.3c05026$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acssuschemeng.3c05026$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids></links><search><creatorcontrib>Sugiura, Shintaro</creatorcontrib><creatorcontrib>Shintani, Yuki</creatorcontrib><creatorcontrib>Higashi, Sayuri L.</creatorcontrib><creatorcontrib>Shibata, Aya</creatorcontrib><creatorcontrib>Ikeda, Masato</creatorcontrib><title>Dihydrolevoglucosenone (Cyrene) as a Biobased Green Alternative to Organic Solvents for the Preparation of Supramolecular Gels Consisting of Self-Assembling Dipeptide Derivatives</title><title>ACS sustainable chemistry &amp; engineering</title><addtitle>ACS Sustainable Chem. Eng</addtitle><description>Herein, we describe the use of Cyrene, a biobased green solvent, to prepare supramolecular gels composed of self-assembling dipeptide derivatives. The gelation behavior was evaluated by using a conventional tube-inversion method. The basic properties, of the obtained supramolecular gels, including critical gel concentrations and viscoelastic properties, were assessed. In addition, the self-assembled fibrous network inside the gels was investigated via confocal laser scanning microscopy after fluorescence staining. The results offer important insights into the preparation of supramolecular gel-based materials with minimal environmental damage for practical applications.</description><issn>2168-0485</issn><issn>2168-0485</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNqFkM9OwzAMxisEEtPgEZB8hENHkv6hPY4NBhLSkIBzlaVOlylLqridtNfiCekGBzjhiy3bnz_5F0VXnE04E_xWKqKe1Bq36JpJoljGRH4SjQTPi5ilRXb6qz6PLok2bIiyTETBR9Hn3Kz3dfAWd76xvfKEzjuE69k-oMMbkAQS7o1fScIaFgHRwdR2GJzszA6h87AMjXRGwZu3O3QdgfYBujXCa8BWhmHPO_Aa3vo2yO1gpXorAyzQEsy8I0Odcc1xA62Op0S4XdlDa25abDtTI8wxmN3RkS6iMy0t4eVPHkcfjw_vs6f4Zbl4nk1fYinSpIsFL4s6S4VUia4zkbAEkXOZD89rJeuU8aJAXRdC5yIVqzTPS65rTDTL8vIOVTKOsu-7KniigLpqg9nKsK84qw7sqz_sqx_2g45_64ZxtfH9QMrSP5ovWLyRWQ</recordid><startdate>20240129</startdate><enddate>20240129</enddate><creator>Sugiura, Shintaro</creator><creator>Shintani, Yuki</creator><creator>Higashi, Sayuri L.</creator><creator>Shibata, Aya</creator><creator>Ikeda, Masato</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-4097-8292</orcidid><orcidid>https://orcid.org/0000-0001-8488-4808</orcidid></search><sort><creationdate>20240129</creationdate><title>Dihydrolevoglucosenone (Cyrene) as a Biobased Green Alternative to Organic Solvents for the Preparation of Supramolecular Gels Consisting of Self-Assembling Dipeptide Derivatives</title><author>Sugiura, Shintaro ; Shintani, Yuki ; Higashi, Sayuri L. ; Shibata, Aya ; Ikeda, Masato</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a243t-2198d542ac3fd52303ee11a6000fcad40188efd82f6242b46691fde3f05697ec3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sugiura, Shintaro</creatorcontrib><creatorcontrib>Shintani, Yuki</creatorcontrib><creatorcontrib>Higashi, Sayuri L.</creatorcontrib><creatorcontrib>Shibata, Aya</creatorcontrib><creatorcontrib>Ikeda, Masato</creatorcontrib><collection>CrossRef</collection><jtitle>ACS sustainable chemistry &amp; engineering</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sugiura, Shintaro</au><au>Shintani, Yuki</au><au>Higashi, Sayuri L.</au><au>Shibata, Aya</au><au>Ikeda, Masato</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dihydrolevoglucosenone (Cyrene) as a Biobased Green Alternative to Organic Solvents for the Preparation of Supramolecular Gels Consisting of Self-Assembling Dipeptide Derivatives</atitle><jtitle>ACS sustainable chemistry &amp; engineering</jtitle><addtitle>ACS Sustainable Chem. Eng</addtitle><date>2024-01-29</date><risdate>2024</risdate><volume>12</volume><issue>4</issue><spage>1420</spage><epage>1426</epage><pages>1420-1426</pages><issn>2168-0485</issn><eissn>2168-0485</eissn><abstract>Herein, we describe the use of Cyrene, a biobased green solvent, to prepare supramolecular gels composed of self-assembling dipeptide derivatives. The gelation behavior was evaluated by using a conventional tube-inversion method. The basic properties, of the obtained supramolecular gels, including critical gel concentrations and viscoelastic properties, were assessed. In addition, the self-assembled fibrous network inside the gels was investigated via confocal laser scanning microscopy after fluorescence staining. The results offer important insights into the preparation of supramolecular gel-based materials with minimal environmental damage for practical applications.</abstract><pub>American Chemical Society</pub><doi>10.1021/acssuschemeng.3c05026</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0003-4097-8292</orcidid><orcidid>https://orcid.org/0000-0001-8488-4808</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 2168-0485
ispartof ACS sustainable chemistry & engineering, 2024-01, Vol.12 (4), p.1420-1426
issn 2168-0485
2168-0485
language eng
recordid cdi_crossref_primary_10_1021_acssuschemeng_3c05026
source ACS Publications
title Dihydrolevoglucosenone (Cyrene) as a Biobased Green Alternative to Organic Solvents for the Preparation of Supramolecular Gels Consisting of Self-Assembling Dipeptide Derivatives
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T12%3A10%3A08IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Dihydrolevoglucosenone%20(Cyrene)%20as%20a%20Biobased%20Green%20Alternative%20to%20Organic%20Solvents%20for%20the%20Preparation%20of%20Supramolecular%20Gels%20Consisting%20of%20Self-Assembling%20Dipeptide%20Derivatives&rft.jtitle=ACS%20sustainable%20chemistry%20&%20engineering&rft.au=Sugiura,%20Shintaro&rft.date=2024-01-29&rft.volume=12&rft.issue=4&rft.spage=1420&rft.epage=1426&rft.pages=1420-1426&rft.issn=2168-0485&rft.eissn=2168-0485&rft_id=info:doi/10.1021/acssuschemeng.3c05026&rft_dat=%3Cacs_cross%3Ec164504333%3C/acs_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true