Selective Synthesis of Bioderived Dibenzofurans and Bicycloalkanes from a Cellulose-Based Route

Selective Synthesis of Bioderived Dibenzofurans and Bicycloalkanes from a Cellulose-Based Route

The synthesis of dibenzofurans and bicycloalkanes from biomass is important for sustainable high-value chemicals and high-density fuels. Currently, their biomass-based precursor is mainly derived from lignin with limited yields. Herein, we propose a cellulose-based synthesis route for dibenzofurans...

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Veröffentlicht in:ACS sustainable chemistry & engineering 2021-05, Vol.9 (19), p.6748-6755
Hauptverfasser: Cai, Taimei, Deng, Qiang, Peng, Hailong, Zhong, Jin, Wang, Jun, Dai, Guiping, Zeng, Zheling, Zou, Ji-Jun, Deng, Shuguang
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container_issue 19
container_start_page 6748
container_title ACS sustainable chemistry & engineering
container_volume 9
creator Cai, Taimei
Deng, Qiang
Peng, Hailong
Zhong, Jin
Wang, Jun
Dai, Guiping
Zeng, Zheling
Zou, Ji-Jun
Deng, Shuguang
description The synthesis of dibenzofurans and bicycloalkanes from biomass is important for sustainable high-value chemicals and high-density fuels. Currently, their biomass-based precursor is mainly derived from lignin with limited yields. Herein, we propose a cellulose-based synthesis route for dibenzofurans with a yield of 72.3% via the integration of oxidative coupling of 1,2,4-benzenetriol to diphenol combined with subsequent dehydration under environmentally friendly reaction conditions. After hydrodeoxygenation, bicycloalkanes are obtained with a yield of 70.5% by catalysis performed over Pd/C and various zeolites. This work provides a powerful cellulose-based strategy for the synthesis of dibenzofurans and bicycloalkanes, which was previously unattainable in the conventional lignin-based route.
doi_str_mv 10.1021/acssuschemeng.1c00864
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title Selective Synthesis of Bioderived Dibenzofurans and Bicycloalkanes from a Cellulose-Based Route
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