Absorption- and Excitation-Modulated Luminescence of Pr 3+ , Nd 3+ , and Lu 3+ Compounds with Dianions of Tetrafluoroterephthalic and Camphoric Acids
The luminescence of coordination polymers of Pr , Nd , and Lu with tetrafluoroterephthalate and camphorate, [Ln (Fbdc) (DMF) (H O)] (Ln = Pr, Nd, Lu) and [Ln (Camph) (NO ) (MeOH)] (Ln = Pr, Nd, Lu), was studied. Ligand-centered and/or metal-centered emissions appear, which depend on the excitation w...
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| Veröffentlicht in: | ACS omega 2019-02, Vol.4 (2), p.2669-2675 |
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| creator | Mikhalyova, Elena A Khomenko, Olena V Gavrilenko, Konstantin S Dotsenko, Vladimir P Addison, Anthony W Pavlishchuk, Vitaly V |
| description | The luminescence of coordination polymers of Pr
, Nd
, and Lu
with tetrafluoroterephthalate and camphorate, [Ln
(Fbdc)
(DMF)
(H
O)]
(Ln = Pr, Nd, Lu) and [Ln
(Camph)
(NO
)
(MeOH)]
(Ln = Pr, Nd, Lu), was studied. Ligand-centered and/or metal-centered emissions appear, which depend on the excitation wavelength, ultimately allowing the emitted light color to be adjusted. Low-efficiency ligand-to-metal energy transfer leads to a difference between the excitation spectra of the tetrafluoroterephthalate- and camphorate-Pr
compounds, arising from a primary filtering effect on the ligand-centered excitation, by Pr
absorption. A secondary inner filter effect significantly changes the shape of the luminescence band, allowing a wide variation in the emission color, producing, for instance, a purple color, which is not the normal spectral emission. The low-efficiency energy transfer renders tetrafluoroterephthalate and camphorate ineffective as traditional "antenna" ligands for Pr
and Nd
. |
| doi_str_mv | 10.1021/acsomega.8b02388 |
| format | Article |
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, Nd
, and Lu
with tetrafluoroterephthalate and camphorate, [Ln
(Fbdc)
(DMF)
(H
O)]
(Ln = Pr, Nd, Lu) and [Ln
(Camph)
(NO
)
(MeOH)]
(Ln = Pr, Nd, Lu), was studied. Ligand-centered and/or metal-centered emissions appear, which depend on the excitation wavelength, ultimately allowing the emitted light color to be adjusted. Low-efficiency ligand-to-metal energy transfer leads to a difference between the excitation spectra of the tetrafluoroterephthalate- and camphorate-Pr
compounds, arising from a primary filtering effect on the ligand-centered excitation, by Pr
absorption. A secondary inner filter effect significantly changes the shape of the luminescence band, allowing a wide variation in the emission color, producing, for instance, a purple color, which is not the normal spectral emission. The low-efficiency energy transfer renders tetrafluoroterephthalate and camphorate ineffective as traditional "antenna" ligands for Pr
and Nd
.</description><identifier>ISSN: 2470-1343</identifier><identifier>EISSN: 2470-1343</identifier><identifier>DOI: 10.1021/acsomega.8b02388</identifier><identifier>PMID: 31459502</identifier><language>eng</language><publisher>United States</publisher><ispartof>ACS omega, 2019-02, Vol.4 (2), p.2669-2675</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1112-e1a7af2c28d26f7c403904feac337798e62cc18f8a1e8068d25073bc4d2078a93</citedby><cites>FETCH-LOGICAL-c1112-e1a7af2c28d26f7c403904feac337798e62cc18f8a1e8068d25073bc4d2078a93</cites><orcidid>0000-0002-0706-7377</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,860,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31459502$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Mikhalyova, Elena A</creatorcontrib><creatorcontrib>Khomenko, Olena V</creatorcontrib><creatorcontrib>Gavrilenko, Konstantin S</creatorcontrib><creatorcontrib>Dotsenko, Vladimir P</creatorcontrib><creatorcontrib>Addison, Anthony W</creatorcontrib><creatorcontrib>Pavlishchuk, Vitaly V</creatorcontrib><title>Absorption- and Excitation-Modulated Luminescence of Pr 3+ , Nd 3+ , and Lu 3+ Compounds with Dianions of Tetrafluoroterephthalic and Camphoric Acids</title><title>ACS omega</title><addtitle>ACS Omega</addtitle><description>The luminescence of coordination polymers of Pr
, Nd
, and Lu
with tetrafluoroterephthalate and camphorate, [Ln
(Fbdc)
(DMF)
(H
O)]
(Ln = Pr, Nd, Lu) and [Ln
(Camph)
(NO
)
(MeOH)]
(Ln = Pr, Nd, Lu), was studied. Ligand-centered and/or metal-centered emissions appear, which depend on the excitation wavelength, ultimately allowing the emitted light color to be adjusted. Low-efficiency ligand-to-metal energy transfer leads to a difference between the excitation spectra of the tetrafluoroterephthalate- and camphorate-Pr
compounds, arising from a primary filtering effect on the ligand-centered excitation, by Pr
absorption. A secondary inner filter effect significantly changes the shape of the luminescence band, allowing a wide variation in the emission color, producing, for instance, a purple color, which is not the normal spectral emission. The low-efficiency energy transfer renders tetrafluoroterephthalate and camphorate ineffective as traditional "antenna" ligands for Pr
and Nd
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, Nd
, and Lu
with tetrafluoroterephthalate and camphorate, [Ln
(Fbdc)
(DMF)
(H
O)]
(Ln = Pr, Nd, Lu) and [Ln
(Camph)
(NO
)
(MeOH)]
(Ln = Pr, Nd, Lu), was studied. Ligand-centered and/or metal-centered emissions appear, which depend on the excitation wavelength, ultimately allowing the emitted light color to be adjusted. Low-efficiency ligand-to-metal energy transfer leads to a difference between the excitation spectra of the tetrafluoroterephthalate- and camphorate-Pr
compounds, arising from a primary filtering effect on the ligand-centered excitation, by Pr
absorption. A secondary inner filter effect significantly changes the shape of the luminescence band, allowing a wide variation in the emission color, producing, for instance, a purple color, which is not the normal spectral emission. The low-efficiency energy transfer renders tetrafluoroterephthalate and camphorate ineffective as traditional "antenna" ligands for Pr
and Nd
.</abstract><cop>United States</cop><pmid>31459502</pmid><doi>10.1021/acsomega.8b02388</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-0706-7377</orcidid></addata></record> |
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| source | DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; American Chemical Society (ACS) Open Access; PubMed Central |
| title | Absorption- and Excitation-Modulated Luminescence of Pr 3+ , Nd 3+ , and Lu 3+ Compounds with Dianions of Tetrafluoroterephthalic and Camphoric Acids |
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