Association Reaction of Gaseous C 2 H 4 in Femtosecond Laser Filaments Studied by Time-of-Flight Mass Spectrometry
Association reactions by femtosecond laser filamentation in gaseous C H were studied by time-of-flight mass spectrometry of neutral reaction products. Direct sampling from the reaction cell to a mass spectrometer via a differential pumping stage allowed the identification of various hydrocarbon mole...
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| Veröffentlicht in: | ACS omega 2021-11, Vol.6 (44), p.29862-29868 |
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| creator | Matsuda, Akitaka Tani, Kentaro Takeuchi, Yukari Hayakawa, Yui Hishikawa, Akiyoshi |
| description | Association reactions by femtosecond laser filamentation in gaseous C
H
were studied by time-of-flight mass spectrometry of neutral reaction products. Direct sampling from the reaction cell to a mass spectrometer via a differential pumping stage allowed the identification of various hydrocarbon molecules C
H
with
= 3-7 and
= 4-7, which includes species not observed in the previous studies. It was found that products containing three and four carbon atoms dominate the mass spectrum with smaller yields for higher-mass species, suggesting that carbon chain growth proceeds through the reaction with C
H
in the reaction cell. The product distribution showed a clear dependence on the laser pulse energy for filamentation. |
| doi_str_mv | 10.1021/acsomega.1c04354 |
| format | Article |
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H
were studied by time-of-flight mass spectrometry of neutral reaction products. Direct sampling from the reaction cell to a mass spectrometer via a differential pumping stage allowed the identification of various hydrocarbon molecules C
H
with
= 3-7 and
= 4-7, which includes species not observed in the previous studies. It was found that products containing three and four carbon atoms dominate the mass spectrum with smaller yields for higher-mass species, suggesting that carbon chain growth proceeds through the reaction with C
H
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H
were studied by time-of-flight mass spectrometry of neutral reaction products. Direct sampling from the reaction cell to a mass spectrometer via a differential pumping stage allowed the identification of various hydrocarbon molecules C
H
with
= 3-7 and
= 4-7, which includes species not observed in the previous studies. It was found that products containing three and four carbon atoms dominate the mass spectrum with smaller yields for higher-mass species, suggesting that carbon chain growth proceeds through the reaction with C
H
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H
were studied by time-of-flight mass spectrometry of neutral reaction products. Direct sampling from the reaction cell to a mass spectrometer via a differential pumping stage allowed the identification of various hydrocarbon molecules C
H
with
= 3-7 and
= 4-7, which includes species not observed in the previous studies. It was found that products containing three and four carbon atoms dominate the mass spectrum with smaller yields for higher-mass species, suggesting that carbon chain growth proceeds through the reaction with C
H
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| language | eng |
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| source | DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; American Chemical Society (ACS) Open Access; PubMed Central |
| title | Association Reaction of Gaseous C 2 H 4 in Femtosecond Laser Filaments Studied by Time-of-Flight Mass Spectrometry |
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