Nickel-Catalyzed Oxidative Decarboxylative (Hetero)Arylation of Unactivated C–H Bonds: Ni and Ag Synergy

Nickel-Catalyzed Oxidative Decarboxylative (Hetero)Arylation of Unactivated C–H Bonds: Ni and Ag Synergy

Oxidative decarboxylative arylation reactions are potentially attractive routes to generate biaryl structures from simple and readily available precursors; yet, they are underutilized, because of limitations in the carboxylic acid scope. Here, we report a nickel catalyst system that enables the sele...

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Veröffentlicht in:ACS catalysis 2017-07, Vol.7 (7), p.4597-4601
Hauptverfasser: Honeycutt, Aaron P, Hoover, Jessica M
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Hoover, Jessica M
description Oxidative decarboxylative arylation reactions are potentially attractive routes to generate biaryl structures from simple and readily available precursors; yet, they are underutilized, because of limitations in the carboxylic acid scope. Here, we report a nickel catalyst system that enables the selective decarboxylative arylation of unactivated C–H bonds with a broad scope of (hetero)­aromatic carboxylate coupling partners. Preliminary mechanistic insights suggest that the efficiency and selectivity of this protocol originate from cooperation between Ni and Ag.
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title Nickel-Catalyzed Oxidative Decarboxylative (Hetero)Arylation of Unactivated C–H Bonds: Ni and Ag Synergy
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