Hydrogen Bonds-Enabled Design of a C 1‑Symmetric Chiral Brønsted Acid Catalyst

We have developed new C 1-symmetric, chiral bis-phosphoric acids with an electron-withdrawing group as one of the two substituents. This C 1-symmetric, chiral bis-phosphoric acid with a pentafluorophenyl group performs exceptionally well in the asymmetric Diels–Alder reaction of acrolein, methacrole...

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Veröffentlicht in:ACS catalysis 2016-02, Vol.6 (2), p.949-956
Hauptverfasser: Momiyama, Norie, Funayama, Kosuke, Noda, Hirofumi, Yamanaka, Masahiro, Akasaka, Naohiko, Ishida, Shintaro, Iwamoto, Takeaki, Terada, Masahiro
Format: Artikel
Sprache:eng
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