Efficient Base-Free Hydrogenation of Amides to Alcohols and Amines Catalyzed by Well-Defined Pincer Imidazolyl–Ruthenium Complexes

Novel homogeneous ruthenium catalysts bearing an imidazolylaminophosphino pincer ligand have been synthesized. The active catalyst allows for the hydrogenation of a range of amides under base-free conditions to afford the corresponding alcohols and amines in high yields.

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Veröffentlicht in:ACS catalysis 2016-01, Vol.6 (1), p.47-54
Hauptverfasser: Cabrero-Antonino, Jose R, Alberico, Elisabetta, Drexler, Hans-Joachim, Baumann, Wolfgang, Junge, Kathrin, Junge, Henrik, Beller, Matthias
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container_end_page 54
container_issue 1
container_start_page 47
container_title ACS catalysis
container_volume 6
creator Cabrero-Antonino, Jose R
Alberico, Elisabetta
Drexler, Hans-Joachim
Baumann, Wolfgang
Junge, Kathrin
Junge, Henrik
Beller, Matthias
description Novel homogeneous ruthenium catalysts bearing an imidazolylaminophosphino pincer ligand have been synthesized. The active catalyst allows for the hydrogenation of a range of amides under base-free conditions to afford the corresponding alcohols and amines in high yields.
doi_str_mv 10.1021/acscatal.5b01955
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title Efficient Base-Free Hydrogenation of Amides to Alcohols and Amines Catalyzed by Well-Defined Pincer Imidazolyl–Ruthenium Complexes
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