N‑Heterocyclic Carbene-Carbodiimide (NHC-CDI) Betaines as Organocatalysts for β‑Butyrolactone Polymerization: Synthesis of Green PHB Plasticizers with Tailored Molecular Weights

The manufacture of poly­(3-hydroxybutyrate) (PHB) stands out as a promising alternative to traditional plastics. This polymer is usually produced by bacteria-based biotechnology or metal-catalyzed ring-opening polymerization (ROP) of β-butyrolactone (β-BL). Nevertheless, commercial PHB suffers from...

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Veröffentlicht in:	ACS catalysis 2024-02, Vol.14 (4), p.2487-2501
Hauptverfasser:	Sánchez-Roa, David, Sessini, Valentina, Mosquera, Marta E. G., Cámpora, Juan
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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