Chiral Gold Complex Catalyzed Cycloisomerization/Regio- and Enantioselective Nitroso-Diels–Alder Reaction of 1,6-Diyne Esters with Nitrosobenzenes

An efficient chiral gold­(I) complex-catalyzed synthetic method that enables the cycloisomerization/regio- and enantioselective nitroso-Diels–Alder (NDA) reaction of 1,6-diyne esters with nitrosobenzenes is described. The sequential ring formation protocol offers access to a wide variety of 3,5,6,8a...

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Veröffentlicht in:ACS catalysis 2022-06, Vol.12 (12), p.7288-7299
Hauptverfasser: Yu, Lei, Li, Wenhai, Tapdara, Anyawan, Kyne, Sara Helen, Harode, Mandeep, Babaahmadi, Rasool, Ariafard, Alireza, Chan, Philip Wai Hong
Format: Artikel
Sprache:eng
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