Electrocatalytic Water Oxidation by a Trinuclear Copper(II) Complex

We report a trinuclear copper­(II) complex, [(DAM)­Cu3(μ3-O)]­[Cl]4 (1, DAM = dodecaaza macrotetracycle), as a homogeneous electrocatalyst for water oxidation to dioxygen in phosphate-buffered solutions at pH 7.0, 8.1, and 11.5. Electrocatalytic water oxidation at pH 7 occurs at an overpotential of...

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Veröffentlicht in:	ACS catalysis 2021-06, Vol.11 (12), p.7223-7240
Hauptverfasser:	Geer, Ana M, Musgrave III, Charles, Webber, Christopher, Nielsen, Robert J, McKeown, Bradley A, Liu, Chang, Schleker, P. Philipp M, Jakes, Peter, Jia, Xiaofan, Dickie, Diane A, Granwehr, Josef, Zhang, Sen, Machan, Charles W, Goddard, William A, Gunnoe, T. Brent
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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