Fast Analytics of High-Impact Polypropylene (HIPP)

Fast Analytics of High-Impact Polypropylene (HIPP)

High-impact polypropylenes (HIPPs) are complex blends, featuring a crystalline isotactic polypropylene matrix and a dispersed phase consisting of an amorphous ethylene/propylene copolymer (EPR). The relative amount of EPR and its composition heavily affect the application properties of the material...

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Veröffentlicht in:ACS applied polymer materials 2023-06, Vol.5 (6), p.3894-3897
Hauptverfasser: Antinucci, Giuseppe, Pucciarelli, Andrea, Vittoria, Antonio, Zaccaria, Francesco, Urciuoli, Gaia, Ehm, Christian, Cannavacciuolo, Felicia Daniela, Cipullo, Roberta, Busico, Vincenzo
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container_issue 6
container_start_page 3894
container_title ACS applied polymer materials
container_volume 5
creator Antinucci, Giuseppe
Pucciarelli, Andrea
Vittoria, Antonio
Zaccaria, Francesco
Urciuoli, Gaia
Ehm, Christian
Cannavacciuolo, Felicia Daniela
Cipullo, Roberta
Busico, Vincenzo
description High-impact polypropylenes (HIPPs) are complex blends, featuring a crystalline isotactic polypropylene matrix and a dispersed phase consisting of an amorphous ethylene/propylene copolymer (EPR). The relative amount of EPR and its composition heavily affect the application properties of the material and need to be accurately controlled. Standard analytical methods are time- and labor-intensive and require considerable amounts of sample and of a toxic solvent, xylene. Here, we introduce an analytical approach to HIPP characterization based on crystallization elution fractionation. The approach is fast, can be operated on just a few mg of sample, and does not require sophisticated and expensive techniques.
doi_str_mv 10.1021/acsapm.3c00810
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