Transparent and Photochromic Material Prepared by Copolymerization of Bismuth(III) Methacrylate

Transparent and Photochromic Material Prepared by Copolymerization of Bismuth(III) Methacrylate

Transparent, photochromic, and X-ray shielding polymer films were obtained by bulk radical copolymerization of bismuth­(III) methacrylate (BiMA), easily synthesized from Ph3Bi and methacrylic acid, and N,N-dimethylacrylamide (DMAA). The refractive indices and X-ray shielding abilities were increased...

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Veröffentlicht in:ACS applied polymer materials 2021-09, Vol.3 (9), p.4419-4423
Hauptverfasser: Ochiai, Bungo, Kikuta, Kohei, Matsumura, Yoshimasa, Horikoshi, Hiroshi, Furukawa, Kikuo, Miyamoto, Miyuki, Nishimura, Yoshio
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container_end_page 4423
container_issue 9
container_start_page 4419
container_title ACS applied polymer materials
container_volume 3
creator Ochiai, Bungo
Kikuta, Kohei
Matsumura, Yoshimasa
Horikoshi, Hiroshi
Furukawa, Kikuo
Miyamoto, Miyuki
Nishimura, Yoshio
description Transparent, photochromic, and X-ray shielding polymer films were obtained by bulk radical copolymerization of bismuth­(III) methacrylate (BiMA), easily synthesized from Ph3Bi and methacrylic acid, and N,N-dimethylacrylamide (DMAA). The refractive indices and X-ray shielding abilities were increased as the increase of the bismuth content. The photochromism, coloring by UV irradiation and discoloring under ambient conditions, occurs by reversible redox between the bismuth carboxylate structure and Bi(0). The facile preparation procedure using inexpensive substances is an advantage over those of previously reported bismuth-containing polymers.
doi_str_mv 10.1021/acsapm.1c00710
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title Transparent and Photochromic Material Prepared by Copolymerization of Bismuth(III) Methacrylate
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