Formation of Supramolecular Polymer Network and Single-Chain Polymer Nanoparticles via Host–Guest Complexation from Pillar[5]arene Pendant Polymer

Formation of Supramolecular Polymer Network and Single-Chain Polymer Nanoparticles via Host–Guest Complexation from Pillar[5]arene Pendant Polymer

A pillar[5]­arene pendant polymer was synthesized by ring-opening metathesis polymerization using the Grubbs first-generation catalyst and cross-linked using a bis­(imidazolium) cross-linker via host–guest complexation. Inclusion of the bis­(imidazolium) guest within the cavity of the pillar[5]­aren...

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Veröffentlicht in:ACS applied polymer materials 2020-11, Vol.2 (11), p.4368-4372
Hauptverfasser: Boominathan, Muniyappan, Arunachalam, Murugan
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description A pillar[5]­arene pendant polymer was synthesized by ring-opening metathesis polymerization using the Grubbs first-generation catalyst and cross-linked using a bis­(imidazolium) cross-linker via host–guest complexation. Inclusion of the bis­(imidazolium) guest within the cavity of the pillar[5]­arene resulted in the formation of a supramolecular polymer network (SPN) at high concentration. Upon high dilution, the SPN formed single-chain polymer nanoparticles (SCPNs). The formation of the SPN and SCPNs were evidenced by NMR spectroscopy, dynamic light scattering, scanning electron microscopy, and atomic force microscopy.
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