Boron-Doped PdRh Mesoporous Nanotubes for Electrocatalytic Nitrogen Reduction to Ammonia
It is important to achieve sustainable ammonia production under mild conditions, and the electrocatalytic nitrogen reduction reaction (NRR) is a promising strategy. However, the precise construction of highly active NRR electrocatalysts for ammonia synthesis remains challenging. Here, we construct B...
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| Veröffentlicht in: | ACS applied nano materials 2024-05, Vol.7 (9), p.10895-10901 |
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| container_title | ACS applied nano materials |
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| creator | Yang, Guanghui Zhang, Hugang Li, Jiarong Wang, Yile Deng, Kai Yu, Hongjie Wang, Hongjing Wang, Ziqiang Wang, Liang |
| description | It is important to achieve sustainable ammonia production under mild conditions, and the electrocatalytic nitrogen reduction reaction (NRR) is a promising strategy. However, the precise construction of highly active NRR electrocatalysts for ammonia synthesis remains challenging. Here, we construct B-doped PdRh mesoporous nanotubes (B-PdRh MNTs) as efficient NRR electrocatalysts. The mesoporous nanotubular structure provides abundant active sites, and B doping enhances the adsorption energy of N2. As such, the NH3 yield and Faraday efficiency of B-PdRh MNTs reach 12.03 μg h–1 mgcat –1 and 16.28% under 0.1 M Na2SO4, respectively. This work provides strategies for B-doped catalysts for efficient electrocatalytic NRR applications. |
| doi_str_mv | 10.1021/acsanm.4c01571 |
| format | Article |
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However, the precise construction of highly active NRR electrocatalysts for ammonia synthesis remains challenging. Here, we construct B-doped PdRh mesoporous nanotubes (B-PdRh MNTs) as efficient NRR electrocatalysts. The mesoporous nanotubular structure provides abundant active sites, and B doping enhances the adsorption energy of N2. As such, the NH3 yield and Faraday efficiency of B-PdRh MNTs reach 12.03 μg h–1 mgcat –1 and 16.28% under 0.1 M Na2SO4, respectively. 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Nano Mater</addtitle><description>It is important to achieve sustainable ammonia production under mild conditions, and the electrocatalytic nitrogen reduction reaction (NRR) is a promising strategy. However, the precise construction of highly active NRR electrocatalysts for ammonia synthesis remains challenging. Here, we construct B-doped PdRh mesoporous nanotubes (B-PdRh MNTs) as efficient NRR electrocatalysts. The mesoporous nanotubular structure provides abundant active sites, and B doping enhances the adsorption energy of N2. As such, the NH3 yield and Faraday efficiency of B-PdRh MNTs reach 12.03 μg h–1 mgcat –1 and 16.28% under 0.1 M Na2SO4, respectively. 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Nano Mater</addtitle><date>2024-05-10</date><risdate>2024</risdate><volume>7</volume><issue>9</issue><spage>10895</spage><epage>10901</epage><pages>10895-10901</pages><issn>2574-0970</issn><eissn>2574-0970</eissn><abstract>It is important to achieve sustainable ammonia production under mild conditions, and the electrocatalytic nitrogen reduction reaction (NRR) is a promising strategy. However, the precise construction of highly active NRR electrocatalysts for ammonia synthesis remains challenging. Here, we construct B-doped PdRh mesoporous nanotubes (B-PdRh MNTs) as efficient NRR electrocatalysts. The mesoporous nanotubular structure provides abundant active sites, and B doping enhances the adsorption energy of N2. As such, the NH3 yield and Faraday efficiency of B-PdRh MNTs reach 12.03 μg h–1 mgcat –1 and 16.28% under 0.1 M Na2SO4, respectively. 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| title | Boron-Doped PdRh Mesoporous Nanotubes for Electrocatalytic Nitrogen Reduction to Ammonia |
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