3D Porous Metal–Organic Skeleton Based on Polyoxometalate Nanoclusters as an Anode in a Lithium-Ion Battery

3D Porous Metal–Organic Skeleton Based on Polyoxometalate Nanoclusters as an Anode in a Lithium-Ion Battery

Basket-like polyoxometalate (POM) nanoclusters possess bulky space barriers and limited coordination active sites; therefore, it is difficult for them to bond with functional metal–organic building units to construct porous materials. To overcome this bottleneck, we adopt a dual-ligand strategy to a...

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Veröffentlicht in:ACS applied nano materials 2024-01, Vol.7 (1), p.1310-1318
Hauptverfasser: Sun, Shuang, Cui, Liping, Yu, Kai, Wang, Meilin, Lv, Jinghua, Ge, Shuanghong, Zhou, Baibin
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container_issue 1
container_start_page 1310
container_title ACS applied nano materials
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creator Sun, Shuang
Cui, Liping
Yu, Kai
Wang, Meilin
Lv, Jinghua
Ge, Shuanghong
Zhou, Baibin
description Basket-like polyoxometalate (POM) nanoclusters possess bulky space barriers and limited coordination active sites; therefore, it is difficult for them to bond with functional metal–organic building units to construct porous materials. To overcome this bottleneck, we adopt a dual-ligand strategy to anchor basket-like POM nanoclusters onto a Ag-pz metal–organic chain yielding a polyporous hybrid material, (H4btb)­[{Ag4(H2O)­(pz)5Cl}­{H2SrP6Mo18O73}]·4H2O (BAS-MOF-1). It is the first three-dimensional (3D) net with intersecting tunnels based on a unique double-layer structure composed of {P6Mo18O73} nodes and Ag-pz chains. As an anode for a Li-ion battery (LIB), this material shows higher lithiation capacity, stability, and rate than zero-dimensional (0D) control compounds, which can be ascribed to the superior redox ability of basket-like POMs and stable organic–inorganic porous structures.
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title 3D Porous Metal–Organic Skeleton Based on Polyoxometalate Nanoclusters as an Anode in a Lithium-Ion Battery
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