Silver Nanoparticle on Alumina Films Tailored for Surface-enhanced Raman Spectroscopy and Detection of Pesticides

Silver nanoparticles (AgNPs) have been widely investigated for their ability to enable surface-enhanced Raman scattering for chemical sensing. Despite many advantages of silver over other plasmonic metals, the unwanted reactivity of silver makes long-term substrate stability and quantitative reprodu...

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Veröffentlicht in:ACS applied nano materials 2022-12, Vol.5 (12), p.18561-18567
Hauptverfasser: Beaton, Graham, Bdour, Yazan, Escobedo, Carlos, Stamplecoskie, Kevin
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creator Beaton, Graham
Bdour, Yazan
Escobedo, Carlos
Stamplecoskie, Kevin
description Silver nanoparticles (AgNPs) have been widely investigated for their ability to enable surface-enhanced Raman scattering for chemical sensing. Despite many advantages of silver over other plasmonic metals, the unwanted reactivity of silver makes long-term substrate stability and quantitative reproducibility in sensing challenging. AgNPs supported on alumina display robust stability against oxidation while remaining labile to photochemical shape control methods. These easily reproduced films can be tailored to absorb light across the visible spectrum depending on user needs and show long-term performance as SERS sensors. Optimization parameters are explored, and these films are showcased as promising chemical sensors for the pesticide thiram with a 96 ppb (m/v) detection limit.
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