Photocatalytic CO 2 Transformation to CH 4 by Ag/Pd Bimetals Supported on N-Doped TiO 2 Nanosheet
To develop photocatalysts with desirable compositions and structures for improving the efficiency and selectivity of CO conversion to CH under mild conditions is of great importance. Here, we design an effective photocatalyst of bimetal (Ag/Pd) nanoalloys supported on nitrogen-doped TiO nanosheet fo...
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| Veröffentlicht in: | ACS applied materials & interfaces 2018-07, Vol.10 (29), p.24516-24522 |
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| container_issue | 29 |
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| container_title | ACS applied materials & interfaces |
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| creator | Tan, Dongxing Zhang, Jianling Shi, Jinbiao Li, Shaopeng Zhang, Bingxing Tan, Xiuniang Zhang, Fanyu Liu, Lifei Shao, Dan Han, Buxing |
| description | To develop photocatalysts with desirable compositions and structures for improving the efficiency and selectivity of CO
conversion to CH
under mild conditions is of great importance. Here, we design an effective photocatalyst of bimetal (Ag/Pd) nanoalloys supported on nitrogen-doped TiO
nanosheet for CO
conversion. Such a novel photocatalyst combines multiple advantages of abundant Ti
ions, oxygen vacancies, and substitutional nitrogen that are favorable for catalyzing CO
reduction. It was found that CO
could be efficiently transformed to CH
under mild conditions, i.e., in aqueous solution and at atmospheric pressure and room temperature. The maximum production rate of CH
can reach 79.0 μmol g
h
. Moreover, the Ag/Pd bimetals supported on N-doped TiO
nanosheet exhibit high selectivity to CH
. The as-synthesized photocatalyst can be well recycled for CO
reduction. |
| doi_str_mv | 10.1021/acsami.8b06320 |
| format | Article |
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conversion to CH
under mild conditions is of great importance. Here, we design an effective photocatalyst of bimetal (Ag/Pd) nanoalloys supported on nitrogen-doped TiO
nanosheet for CO
conversion. Such a novel photocatalyst combines multiple advantages of abundant Ti
ions, oxygen vacancies, and substitutional nitrogen that are favorable for catalyzing CO
reduction. It was found that CO
could be efficiently transformed to CH
under mild conditions, i.e., in aqueous solution and at atmospheric pressure and room temperature. The maximum production rate of CH
can reach 79.0 μmol g
h
. Moreover, the Ag/Pd bimetals supported on N-doped TiO
nanosheet exhibit high selectivity to CH
. The as-synthesized photocatalyst can be well recycled for CO
reduction.</description><identifier>ISSN: 1944-8244</identifier><identifier>EISSN: 1944-8252</identifier><identifier>DOI: 10.1021/acsami.8b06320</identifier><identifier>PMID: 29969233</identifier><language>eng</language><publisher>United States</publisher><ispartof>ACS applied materials & interfaces, 2018-07, Vol.10 (29), p.24516-24522</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1073-9bf8382f1188075ac134186c3915b12034a07b6c38cb2fa2f1be9e3b439c44683</citedby><cites>FETCH-LOGICAL-c1073-9bf8382f1188075ac134186c3915b12034a07b6c38cb2fa2f1be9e3b439c44683</cites><orcidid>0000-0002-2648-7529 ; 0000-0003-0440-809X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,2752,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29969233$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Tan, Dongxing</creatorcontrib><creatorcontrib>Zhang, Jianling</creatorcontrib><creatorcontrib>Shi, Jinbiao</creatorcontrib><creatorcontrib>Li, Shaopeng</creatorcontrib><creatorcontrib>Zhang, Bingxing</creatorcontrib><creatorcontrib>Tan, Xiuniang</creatorcontrib><creatorcontrib>Zhang, Fanyu</creatorcontrib><creatorcontrib>Liu, Lifei</creatorcontrib><creatorcontrib>Shao, Dan</creatorcontrib><creatorcontrib>Han, Buxing</creatorcontrib><title>Photocatalytic CO 2 Transformation to CH 4 by Ag/Pd Bimetals Supported on N-Doped TiO 2 Nanosheet</title><title>ACS applied materials & interfaces</title><addtitle>ACS Appl Mater Interfaces</addtitle><description>To develop photocatalysts with desirable compositions and structures for improving the efficiency and selectivity of CO
conversion to CH
under mild conditions is of great importance. Here, we design an effective photocatalyst of bimetal (Ag/Pd) nanoalloys supported on nitrogen-doped TiO
nanosheet for CO
conversion. Such a novel photocatalyst combines multiple advantages of abundant Ti
ions, oxygen vacancies, and substitutional nitrogen that are favorable for catalyzing CO
reduction. It was found that CO
could be efficiently transformed to CH
under mild conditions, i.e., in aqueous solution and at atmospheric pressure and room temperature. The maximum production rate of CH
can reach 79.0 μmol g
h
. Moreover, the Ag/Pd bimetals supported on N-doped TiO
nanosheet exhibit high selectivity to CH
. The as-synthesized photocatalyst can be well recycled for CO
reduction.</description><issn>1944-8244</issn><issn>1944-8252</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNo9kE1PAjEURRujEUS3Lk3_wEC_ZqZd4ohiQoBEXE_a0soYZzppy4J_bxFk9e5Lzr2LA8AjRmOMCJ5IHWTbjLlCBSXoCgyxYCzjJCfXl8zYANyF8I3-mPwWDIgQhSCUDoFc71x0Wkb5c4iNhtUKErjxsgvW-VbGxnUwOljNIYPqAKdfk_UWPjetSYUAP_Z973w0W5iwZfbi-hQ3zXFjKTsXdsbEe3BjE2sezncEPl9nm2qeLVZv79V0kWmMSpoJZTnlxGLMOSpzqTFlmBeaCpwrTBBlEpUq_VwrYmUClRGGKkaFZqzgdATGp13tXQje2Lr3TSv9ocaoPrqqT67qs6tUeDoV-r1qzfaC_8uhv_oIY8Q</recordid><startdate>20180725</startdate><enddate>20180725</enddate><creator>Tan, Dongxing</creator><creator>Zhang, Jianling</creator><creator>Shi, Jinbiao</creator><creator>Li, Shaopeng</creator><creator>Zhang, Bingxing</creator><creator>Tan, Xiuniang</creator><creator>Zhang, Fanyu</creator><creator>Liu, Lifei</creator><creator>Shao, Dan</creator><creator>Han, Buxing</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-2648-7529</orcidid><orcidid>https://orcid.org/0000-0003-0440-809X</orcidid></search><sort><creationdate>20180725</creationdate><title>Photocatalytic CO 2 Transformation to CH 4 by Ag/Pd Bimetals Supported on N-Doped TiO 2 Nanosheet</title><author>Tan, Dongxing ; Zhang, Jianling ; Shi, Jinbiao ; Li, Shaopeng ; Zhang, Bingxing ; Tan, Xiuniang ; Zhang, Fanyu ; Liu, Lifei ; Shao, Dan ; Han, Buxing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1073-9bf8382f1188075ac134186c3915b12034a07b6c38cb2fa2f1be9e3b439c44683</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tan, Dongxing</creatorcontrib><creatorcontrib>Zhang, Jianling</creatorcontrib><creatorcontrib>Shi, Jinbiao</creatorcontrib><creatorcontrib>Li, Shaopeng</creatorcontrib><creatorcontrib>Zhang, Bingxing</creatorcontrib><creatorcontrib>Tan, Xiuniang</creatorcontrib><creatorcontrib>Zhang, Fanyu</creatorcontrib><creatorcontrib>Liu, Lifei</creatorcontrib><creatorcontrib>Shao, Dan</creatorcontrib><creatorcontrib>Han, Buxing</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><jtitle>ACS applied materials & interfaces</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tan, Dongxing</au><au>Zhang, Jianling</au><au>Shi, Jinbiao</au><au>Li, Shaopeng</au><au>Zhang, Bingxing</au><au>Tan, Xiuniang</au><au>Zhang, Fanyu</au><au>Liu, Lifei</au><au>Shao, Dan</au><au>Han, Buxing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Photocatalytic CO 2 Transformation to CH 4 by Ag/Pd Bimetals Supported on N-Doped TiO 2 Nanosheet</atitle><jtitle>ACS applied materials & interfaces</jtitle><addtitle>ACS Appl Mater Interfaces</addtitle><date>2018-07-25</date><risdate>2018</risdate><volume>10</volume><issue>29</issue><spage>24516</spage><epage>24522</epage><pages>24516-24522</pages><issn>1944-8244</issn><eissn>1944-8252</eissn><abstract>To develop photocatalysts with desirable compositions and structures for improving the efficiency and selectivity of CO
conversion to CH
under mild conditions is of great importance. Here, we design an effective photocatalyst of bimetal (Ag/Pd) nanoalloys supported on nitrogen-doped TiO
nanosheet for CO
conversion. Such a novel photocatalyst combines multiple advantages of abundant Ti
ions, oxygen vacancies, and substitutional nitrogen that are favorable for catalyzing CO
reduction. It was found that CO
could be efficiently transformed to CH
under mild conditions, i.e., in aqueous solution and at atmospheric pressure and room temperature. The maximum production rate of CH
can reach 79.0 μmol g
h
. Moreover, the Ag/Pd bimetals supported on N-doped TiO
nanosheet exhibit high selectivity to CH
. The as-synthesized photocatalyst can be well recycled for CO
reduction.</abstract><cop>United States</cop><pmid>29969233</pmid><doi>10.1021/acsami.8b06320</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-2648-7529</orcidid><orcidid>https://orcid.org/0000-0003-0440-809X</orcidid></addata></record> |
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| ispartof | ACS applied materials & interfaces, 2018-07, Vol.10 (29), p.24516-24522 |
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| language | eng |
| recordid | cdi_crossref_primary_10_1021_acsami_8b06320 |
| source | American Chemical Society Journals |
| title | Photocatalytic CO 2 Transformation to CH 4 by Ag/Pd Bimetals Supported on N-Doped TiO 2 Nanosheet |
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