Chemical Vapor Deposition Synthesis and Optical Properties of Nb 2 O 5 Thin Films with Hybrid Functional Theoretical Insight into the Band Structure and Band Gaps
Nb O is an important material able to exist in many polymorphs with unique optical properties and morphologies that are dependent on the synthetic route. Here we report a novel ambient-pressure chemical vapor deposition route to Nb O via aerosol-assisted chemical vapor deposition. The amorphous as-d...
Gespeichert in:
| Veröffentlicht in: | ACS applied materials & interfaces 2017-05, Vol.9 (21), p.18031-18038 |
|---|---|
| Hauptverfasser: | , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 18038 |
|---|---|
| container_issue | 21 |
| container_start_page | 18031 |
| container_title | ACS applied materials & interfaces |
| container_volume | 9 |
| creator | Sathasivam, Sanjayan Williamson, Benjamin A D Althabaiti, Shaeel A Obaid, Abdullah Y Basahel, Sulaiman N Mokhtar, Mohamed Scanlon, David O Carmalt, Claire J Parkin, Ivan P |
| description | Nb
O
is an important material able to exist in many polymorphs with unique optical properties and morphologies that are dependent on the synthetic route. Here we report a novel ambient-pressure chemical vapor deposition route to Nb
O
via aerosol-assisted chemical vapor deposition. The amorphous as-deposited films were annealed in air to obtain the the three most stable crystal structures: orthorhombic, tetragonal, and monoclinic. The films were thoroughly characterized for their material properties, and an in-depth study into the optical properties was carried out using state-of-the-art hybrid functional theory that allowed more insight into the optical properties of the materials. |
| doi_str_mv | 10.1021/acsami.7b00907 |
| format | Article |
| fullrecord | <record><control><sourceid>pubmed_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_acsami_7b00907</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>28492079</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1079-880c41b6da4d5347c10fa7e0ef86663ebb57e40961e2528cff7540517ea517053</originalsourceid><addsrcrecordid>eNo9kMtOwzAQRS0EoqWwZYnmB1rsxHktodCHVFGkFraR40yIURNHtiPU3-FLSZvSzcxoNPdezSHkntEJox57FNKKSk2ijNKERhdkyBLOx7EXeJfnmfMBubH2m9LQ92hwTQZezBOPRsmQ_E5LrJQUO_gUjTbwgo22yildw2ZfuxKtsiDqHNaNO569G92gcQot6ALeMvBgDQFsS1XDTO0qCz_KlbDYZ0blMGtreTDrhNsStcHeZFlb9VU6ULXT0IXA8yFi40wrXWvwGHhczUVjb8lVIXYW7059RD5mr9vpYrxaz5fTp9VYsu6VcRxTyVkW5oLngc-jbluICCkWcRiGPmZZECGnSciwoxPLoogCTgMWoegKDfwRmfS-0mhrDRZpY1QlzD5lND3ATnvY6Ql2J3joBU2bVZifz__p-n8ujXzp</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Chemical Vapor Deposition Synthesis and Optical Properties of Nb 2 O 5 Thin Films with Hybrid Functional Theoretical Insight into the Band Structure and Band Gaps</title><source>ACS Publications</source><creator>Sathasivam, Sanjayan ; Williamson, Benjamin A D ; Althabaiti, Shaeel A ; Obaid, Abdullah Y ; Basahel, Sulaiman N ; Mokhtar, Mohamed ; Scanlon, David O ; Carmalt, Claire J ; Parkin, Ivan P</creator><creatorcontrib>Sathasivam, Sanjayan ; Williamson, Benjamin A D ; Althabaiti, Shaeel A ; Obaid, Abdullah Y ; Basahel, Sulaiman N ; Mokhtar, Mohamed ; Scanlon, David O ; Carmalt, Claire J ; Parkin, Ivan P</creatorcontrib><description>Nb
O
is an important material able to exist in many polymorphs with unique optical properties and morphologies that are dependent on the synthetic route. Here we report a novel ambient-pressure chemical vapor deposition route to Nb
O
via aerosol-assisted chemical vapor deposition. The amorphous as-deposited films were annealed in air to obtain the the three most stable crystal structures: orthorhombic, tetragonal, and monoclinic. The films were thoroughly characterized for their material properties, and an in-depth study into the optical properties was carried out using state-of-the-art hybrid functional theory that allowed more insight into the optical properties of the materials.</description><identifier>ISSN: 1944-8244</identifier><identifier>EISSN: 1944-8252</identifier><identifier>DOI: 10.1021/acsami.7b00907</identifier><identifier>PMID: 28492079</identifier><language>eng</language><publisher>United States</publisher><ispartof>ACS applied materials & interfaces, 2017-05, Vol.9 (21), p.18031-18038</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1079-880c41b6da4d5347c10fa7e0ef86663ebb57e40961e2528cff7540517ea517053</citedby><cites>FETCH-LOGICAL-c1079-880c41b6da4d5347c10fa7e0ef86663ebb57e40961e2528cff7540517ea517053</cites><orcidid>0000-0003-1788-6971 ; 0000-0002-5206-9558 ; 0000-0001-9174-8601</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,2752,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28492079$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Sathasivam, Sanjayan</creatorcontrib><creatorcontrib>Williamson, Benjamin A D</creatorcontrib><creatorcontrib>Althabaiti, Shaeel A</creatorcontrib><creatorcontrib>Obaid, Abdullah Y</creatorcontrib><creatorcontrib>Basahel, Sulaiman N</creatorcontrib><creatorcontrib>Mokhtar, Mohamed</creatorcontrib><creatorcontrib>Scanlon, David O</creatorcontrib><creatorcontrib>Carmalt, Claire J</creatorcontrib><creatorcontrib>Parkin, Ivan P</creatorcontrib><title>Chemical Vapor Deposition Synthesis and Optical Properties of Nb 2 O 5 Thin Films with Hybrid Functional Theoretical Insight into the Band Structure and Band Gaps</title><title>ACS applied materials & interfaces</title><addtitle>ACS Appl Mater Interfaces</addtitle><description>Nb
O
is an important material able to exist in many polymorphs with unique optical properties and morphologies that are dependent on the synthetic route. Here we report a novel ambient-pressure chemical vapor deposition route to Nb
O
via aerosol-assisted chemical vapor deposition. The amorphous as-deposited films were annealed in air to obtain the the three most stable crystal structures: orthorhombic, tetragonal, and monoclinic. The films were thoroughly characterized for their material properties, and an in-depth study into the optical properties was carried out using state-of-the-art hybrid functional theory that allowed more insight into the optical properties of the materials.</description><issn>1944-8244</issn><issn>1944-8252</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNo9kMtOwzAQRS0EoqWwZYnmB1rsxHktodCHVFGkFraR40yIURNHtiPU3-FLSZvSzcxoNPdezSHkntEJox57FNKKSk2ijNKERhdkyBLOx7EXeJfnmfMBubH2m9LQ92hwTQZezBOPRsmQ_E5LrJQUO_gUjTbwgo22yildw2ZfuxKtsiDqHNaNO569G92gcQot6ALeMvBgDQFsS1XDTO0qCz_KlbDYZ0blMGtreTDrhNsStcHeZFlb9VU6ULXT0IXA8yFi40wrXWvwGHhczUVjb8lVIXYW7059RD5mr9vpYrxaz5fTp9VYsu6VcRxTyVkW5oLngc-jbluICCkWcRiGPmZZECGnSciwoxPLoogCTgMWoegKDfwRmfS-0mhrDRZpY1QlzD5lND3ATnvY6Ql2J3joBU2bVZifz__p-n8ujXzp</recordid><startdate>20170531</startdate><enddate>20170531</enddate><creator>Sathasivam, Sanjayan</creator><creator>Williamson, Benjamin A D</creator><creator>Althabaiti, Shaeel A</creator><creator>Obaid, Abdullah Y</creator><creator>Basahel, Sulaiman N</creator><creator>Mokhtar, Mohamed</creator><creator>Scanlon, David O</creator><creator>Carmalt, Claire J</creator><creator>Parkin, Ivan P</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-1788-6971</orcidid><orcidid>https://orcid.org/0000-0002-5206-9558</orcidid><orcidid>https://orcid.org/0000-0001-9174-8601</orcidid></search><sort><creationdate>20170531</creationdate><title>Chemical Vapor Deposition Synthesis and Optical Properties of Nb 2 O 5 Thin Films with Hybrid Functional Theoretical Insight into the Band Structure and Band Gaps</title><author>Sathasivam, Sanjayan ; Williamson, Benjamin A D ; Althabaiti, Shaeel A ; Obaid, Abdullah Y ; Basahel, Sulaiman N ; Mokhtar, Mohamed ; Scanlon, David O ; Carmalt, Claire J ; Parkin, Ivan P</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1079-880c41b6da4d5347c10fa7e0ef86663ebb57e40961e2528cff7540517ea517053</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sathasivam, Sanjayan</creatorcontrib><creatorcontrib>Williamson, Benjamin A D</creatorcontrib><creatorcontrib>Althabaiti, Shaeel A</creatorcontrib><creatorcontrib>Obaid, Abdullah Y</creatorcontrib><creatorcontrib>Basahel, Sulaiman N</creatorcontrib><creatorcontrib>Mokhtar, Mohamed</creatorcontrib><creatorcontrib>Scanlon, David O</creatorcontrib><creatorcontrib>Carmalt, Claire J</creatorcontrib><creatorcontrib>Parkin, Ivan P</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><jtitle>ACS applied materials & interfaces</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sathasivam, Sanjayan</au><au>Williamson, Benjamin A D</au><au>Althabaiti, Shaeel A</au><au>Obaid, Abdullah Y</au><au>Basahel, Sulaiman N</au><au>Mokhtar, Mohamed</au><au>Scanlon, David O</au><au>Carmalt, Claire J</au><au>Parkin, Ivan P</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Chemical Vapor Deposition Synthesis and Optical Properties of Nb 2 O 5 Thin Films with Hybrid Functional Theoretical Insight into the Band Structure and Band Gaps</atitle><jtitle>ACS applied materials & interfaces</jtitle><addtitle>ACS Appl Mater Interfaces</addtitle><date>2017-05-31</date><risdate>2017</risdate><volume>9</volume><issue>21</issue><spage>18031</spage><epage>18038</epage><pages>18031-18038</pages><issn>1944-8244</issn><eissn>1944-8252</eissn><abstract>Nb
O
is an important material able to exist in many polymorphs with unique optical properties and morphologies that are dependent on the synthetic route. Here we report a novel ambient-pressure chemical vapor deposition route to Nb
O
via aerosol-assisted chemical vapor deposition. The amorphous as-deposited films were annealed in air to obtain the the three most stable crystal structures: orthorhombic, tetragonal, and monoclinic. The films were thoroughly characterized for their material properties, and an in-depth study into the optical properties was carried out using state-of-the-art hybrid functional theory that allowed more insight into the optical properties of the materials.</abstract><cop>United States</cop><pmid>28492079</pmid><doi>10.1021/acsami.7b00907</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0003-1788-6971</orcidid><orcidid>https://orcid.org/0000-0002-5206-9558</orcidid><orcidid>https://orcid.org/0000-0001-9174-8601</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1944-8244 |
| ispartof | ACS applied materials & interfaces, 2017-05, Vol.9 (21), p.18031-18038 |
| issn | 1944-8244 1944-8252 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_acsami_7b00907 |
| source | ACS Publications |
| title | Chemical Vapor Deposition Synthesis and Optical Properties of Nb 2 O 5 Thin Films with Hybrid Functional Theoretical Insight into the Band Structure and Band Gaps |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-08T14%3A21%3A53IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pubmed_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Chemical%20Vapor%20Deposition%20Synthesis%20and%20Optical%20Properties%20of%20Nb%202%20O%205%20Thin%20Films%20with%20Hybrid%20Functional%20Theoretical%20Insight%20into%20the%20Band%20Structure%20and%20Band%20Gaps&rft.jtitle=ACS%20applied%20materials%20&%20interfaces&rft.au=Sathasivam,%20Sanjayan&rft.date=2017-05-31&rft.volume=9&rft.issue=21&rft.spage=18031&rft.epage=18038&rft.pages=18031-18038&rft.issn=1944-8244&rft.eissn=1944-8252&rft_id=info:doi/10.1021/acsami.7b00907&rft_dat=%3Cpubmed_cross%3E28492079%3C/pubmed_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/28492079&rfr_iscdi=true |