Crystalline Engineering Toward Large-Scale High-Efficiency Printable Cu(In,Ga)Se 2 Thin Film Solar Cells on Flexible Substrate by Femtosecond Laser Annealing Process
Ink-printing method emerges as a viable way for manufacturing large-scale flexible Cu(In,Ga)Se (CIGS) thin film photovoltaic (TFPV) devices owing to its potential for the rapid process, mass production, and low-cost nonvacuum device fabrication. Here, we brought the femtosecond laser annealing (fs-L...
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| Veröffentlicht in: | ACS applied materials & interfaces 2017-04, Vol.9 (16), p.14006-14012 |
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| creator | Chen, Shih-Chen She, Nian-Zu Wu, Kaung-Hsiung Chen, Yu-Ze Lin, Wei-Sheng Li, Jia-Xing Lai, Fang-I Juang, Jenh-Yih Luo, Chih Wei Cheng, Lung-Teng Hsieh, Tung-Po Kuo, Hao-Chung Chueh, Yu-Lun |
| description | Ink-printing method emerges as a viable way for manufacturing large-scale flexible Cu(In,Ga)Se
(CIGS) thin film photovoltaic (TFPV) devices owing to its potential for the rapid process, mass production, and low-cost nonvacuum device fabrication. Here, we brought the femtosecond laser annealing (fs-LA) process into the ink-printing CIGS thin film preparation. The effects of fs-LA treatment on the structural and optoelectronic properties of the ink-printing CIGS thin films were systematically investigated. It was observed that, while the film surface morphology remained essentially unchanged under superheating, the quality of crystallinity was significantly enhanced after the fs-LA treatment. Moreover, a better stoichiometric composition was achieved with an optimized laser scanning rate of the laser beam, presumably due to the much reduced indium segregation phenomena, which is believed to be beneficial in decreasing the defect states of In
, V
, and In
. Consequently, the shunt leakage current and recombination centers were both greatly decreased, resulting in a near 20% enhancement in photovoltaic conversion efficiency. |
| doi_str_mv | 10.1021/acsami.7b00082 |
| format | Article |
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(CIGS) thin film photovoltaic (TFPV) devices owing to its potential for the rapid process, mass production, and low-cost nonvacuum device fabrication. Here, we brought the femtosecond laser annealing (fs-LA) process into the ink-printing CIGS thin film preparation. The effects of fs-LA treatment on the structural and optoelectronic properties of the ink-printing CIGS thin films were systematically investigated. It was observed that, while the film surface morphology remained essentially unchanged under superheating, the quality of crystallinity was significantly enhanced after the fs-LA treatment. Moreover, a better stoichiometric composition was achieved with an optimized laser scanning rate of the laser beam, presumably due to the much reduced indium segregation phenomena, which is believed to be beneficial in decreasing the defect states of In
, V
, and In
. Consequently, the shunt leakage current and recombination centers were both greatly decreased, resulting in a near 20% enhancement in photovoltaic conversion efficiency.</description><identifier>ISSN: 1944-8244</identifier><identifier>EISSN: 1944-8252</identifier><identifier>DOI: 10.1021/acsami.7b00082</identifier><identifier>PMID: 28281352</identifier><language>eng</language><publisher>United States</publisher><ispartof>ACS applied materials & interfaces, 2017-04, Vol.9 (16), p.14006-14012</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1072-5343c158dcb84246e064dabe6872816778f43d93f8aa5786985019b64ec09e703</citedby><cites>FETCH-LOGICAL-c1072-5343c158dcb84246e064dabe6872816778f43d93f8aa5786985019b64ec09e703</cites><orcidid>0000-0002-0155-9987</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,2756,27915,27916</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28281352$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Chen, Shih-Chen</creatorcontrib><creatorcontrib>She, Nian-Zu</creatorcontrib><creatorcontrib>Wu, Kaung-Hsiung</creatorcontrib><creatorcontrib>Chen, Yu-Ze</creatorcontrib><creatorcontrib>Lin, Wei-Sheng</creatorcontrib><creatorcontrib>Li, Jia-Xing</creatorcontrib><creatorcontrib>Lai, Fang-I</creatorcontrib><creatorcontrib>Juang, Jenh-Yih</creatorcontrib><creatorcontrib>Luo, Chih Wei</creatorcontrib><creatorcontrib>Cheng, Lung-Teng</creatorcontrib><creatorcontrib>Hsieh, Tung-Po</creatorcontrib><creatorcontrib>Kuo, Hao-Chung</creatorcontrib><creatorcontrib>Chueh, Yu-Lun</creatorcontrib><title>Crystalline Engineering Toward Large-Scale High-Efficiency Printable Cu(In,Ga)Se 2 Thin Film Solar Cells on Flexible Substrate by Femtosecond Laser Annealing Process</title><title>ACS applied materials & interfaces</title><addtitle>ACS Appl Mater Interfaces</addtitle><description>Ink-printing method emerges as a viable way for manufacturing large-scale flexible Cu(In,Ga)Se
(CIGS) thin film photovoltaic (TFPV) devices owing to its potential for the rapid process, mass production, and low-cost nonvacuum device fabrication. Here, we brought the femtosecond laser annealing (fs-LA) process into the ink-printing CIGS thin film preparation. The effects of fs-LA treatment on the structural and optoelectronic properties of the ink-printing CIGS thin films were systematically investigated. It was observed that, while the film surface morphology remained essentially unchanged under superheating, the quality of crystallinity was significantly enhanced after the fs-LA treatment. Moreover, a better stoichiometric composition was achieved with an optimized laser scanning rate of the laser beam, presumably due to the much reduced indium segregation phenomena, which is believed to be beneficial in decreasing the defect states of In
, V
, and In
. Consequently, the shunt leakage current and recombination centers were both greatly decreased, resulting in a near 20% enhancement in photovoltaic conversion efficiency.</description><issn>1944-8244</issn><issn>1944-8252</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNo9kF1LwzAUhoMoTqe3XkouFexM0rRNL0fZFwwcbF6XND3dImk6kg7tD_J_2rG5q3M4533Px4PQEyUjShh9l8rLWo-SghAi2BW6oynngWARu77knA_QvfdfhMQhI9EtGjDBBA0jdod-M9f5VhqjLeCJ3fYBnLZbvGm-pSvxUrotBGslDeC53u6CSVVppcGqDq96YSuLvpMdXhb2bSZf14AZ3uy0xVNtarxujHQ4A2M8bvqagR991K8PhW-dbAEXHZ5C3TYeVGOP6zw4PLYWpDlesXKNAu8f0E0ljYfHcxyiz-lkk82D5cdskY2XgaIkYUEU8lDRSJSqEJzxGEjMS1lALJL-3zhJRMXDMg0rIWWUiDgVEaFpEXNQJIWEhEM0Os1VrvHeQZXvna6l63JK8iPv_MQ7P_PuDc8nw_5Q1FBe5P-Awz9XdH1c</recordid><startdate>20170426</startdate><enddate>20170426</enddate><creator>Chen, Shih-Chen</creator><creator>She, Nian-Zu</creator><creator>Wu, Kaung-Hsiung</creator><creator>Chen, Yu-Ze</creator><creator>Lin, Wei-Sheng</creator><creator>Li, Jia-Xing</creator><creator>Lai, Fang-I</creator><creator>Juang, Jenh-Yih</creator><creator>Luo, Chih Wei</creator><creator>Cheng, Lung-Teng</creator><creator>Hsieh, Tung-Po</creator><creator>Kuo, Hao-Chung</creator><creator>Chueh, Yu-Lun</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-0155-9987</orcidid></search><sort><creationdate>20170426</creationdate><title>Crystalline Engineering Toward Large-Scale High-Efficiency Printable Cu(In,Ga)Se 2 Thin Film Solar Cells on Flexible Substrate by Femtosecond Laser Annealing Process</title><author>Chen, Shih-Chen ; She, Nian-Zu ; Wu, Kaung-Hsiung ; Chen, Yu-Ze ; Lin, Wei-Sheng ; Li, Jia-Xing ; Lai, Fang-I ; Juang, Jenh-Yih ; Luo, Chih Wei ; Cheng, Lung-Teng ; Hsieh, Tung-Po ; Kuo, Hao-Chung ; Chueh, Yu-Lun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1072-5343c158dcb84246e064dabe6872816778f43d93f8aa5786985019b64ec09e703</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Shih-Chen</creatorcontrib><creatorcontrib>She, Nian-Zu</creatorcontrib><creatorcontrib>Wu, Kaung-Hsiung</creatorcontrib><creatorcontrib>Chen, Yu-Ze</creatorcontrib><creatorcontrib>Lin, Wei-Sheng</creatorcontrib><creatorcontrib>Li, Jia-Xing</creatorcontrib><creatorcontrib>Lai, Fang-I</creatorcontrib><creatorcontrib>Juang, Jenh-Yih</creatorcontrib><creatorcontrib>Luo, Chih Wei</creatorcontrib><creatorcontrib>Cheng, Lung-Teng</creatorcontrib><creatorcontrib>Hsieh, Tung-Po</creatorcontrib><creatorcontrib>Kuo, Hao-Chung</creatorcontrib><creatorcontrib>Chueh, Yu-Lun</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><jtitle>ACS applied materials & interfaces</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Shih-Chen</au><au>She, Nian-Zu</au><au>Wu, Kaung-Hsiung</au><au>Chen, Yu-Ze</au><au>Lin, Wei-Sheng</au><au>Li, Jia-Xing</au><au>Lai, Fang-I</au><au>Juang, Jenh-Yih</au><au>Luo, Chih Wei</au><au>Cheng, Lung-Teng</au><au>Hsieh, Tung-Po</au><au>Kuo, Hao-Chung</au><au>Chueh, Yu-Lun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystalline Engineering Toward Large-Scale High-Efficiency Printable Cu(In,Ga)Se 2 Thin Film Solar Cells on Flexible Substrate by Femtosecond Laser Annealing Process</atitle><jtitle>ACS applied materials & interfaces</jtitle><addtitle>ACS Appl Mater Interfaces</addtitle><date>2017-04-26</date><risdate>2017</risdate><volume>9</volume><issue>16</issue><spage>14006</spage><epage>14012</epage><pages>14006-14012</pages><issn>1944-8244</issn><eissn>1944-8252</eissn><abstract>Ink-printing method emerges as a viable way for manufacturing large-scale flexible Cu(In,Ga)Se
(CIGS) thin film photovoltaic (TFPV) devices owing to its potential for the rapid process, mass production, and low-cost nonvacuum device fabrication. Here, we brought the femtosecond laser annealing (fs-LA) process into the ink-printing CIGS thin film preparation. The effects of fs-LA treatment on the structural and optoelectronic properties of the ink-printing CIGS thin films were systematically investigated. It was observed that, while the film surface morphology remained essentially unchanged under superheating, the quality of crystallinity was significantly enhanced after the fs-LA treatment. Moreover, a better stoichiometric composition was achieved with an optimized laser scanning rate of the laser beam, presumably due to the much reduced indium segregation phenomena, which is believed to be beneficial in decreasing the defect states of In
, V
, and In
. Consequently, the shunt leakage current and recombination centers were both greatly decreased, resulting in a near 20% enhancement in photovoltaic conversion efficiency.</abstract><cop>United States</cop><pmid>28281352</pmid><doi>10.1021/acsami.7b00082</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-0155-9987</orcidid></addata></record> |
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| title | Crystalline Engineering Toward Large-Scale High-Efficiency Printable Cu(In,Ga)Se 2 Thin Film Solar Cells on Flexible Substrate by Femtosecond Laser Annealing Process |
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