NASICON-Type Na 3 V 1.5 Cr 0.4 Fe 0.1 (PO 4 ) 3 : High-Voltage and High-Rate Cathode Materials for Sodium-Ion Batteries

NASICON-Type Na 3 V 1.5 Cr 0.4 Fe 0.1 (PO 4 ) 3 : High-Voltage and High-Rate Cathode Materials for Sodium-Ion Batteries

Cationic alteration related to a sodium super ion conductor (NASICON)-structured Na V (PO ) (NVP) is an effective strategy for formulating high-energy and stable cathodes for sodium-ion batteries (SIBs). In this study, we altered the structure of NVP with dual cations, namely, Cr and Fe, to develop...

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Veröffentlicht in:ACS applied materials & interfaces 2024-02, Vol.16 (5), p.5896-5904
Hauptverfasser: Kim, Yeongmin, Oh, Gwangeon, Lee, Jun, Baek, Jaeryeol, Alfaza, Ghalib, Lee, Seunggyeong, Mathew, Vinod, Kansara, Shivam, Hwang, Jang-Yeon, Kim, Jaekook
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container_end_page 5904
container_issue 5
container_start_page 5896
container_title ACS applied materials & interfaces
container_volume 16
creator Kim, Yeongmin
Oh, Gwangeon
Lee, Jun
Baek, Jaeryeol
Alfaza, Ghalib
Lee, Seunggyeong
Mathew, Vinod
Kansara, Shivam
Hwang, Jang-Yeon
Kim, Jaekook
description Cationic alteration related to a sodium super ion conductor (NASICON)-structured Na V (PO ) (NVP) is an effective strategy for formulating high-energy and stable cathodes for sodium-ion batteries (SIBs). In this study, we altered the structure of NVP with dual cations, namely, Cr and Fe, to develop Na V Cr Fe (PO ) cathodes for SIBs with high-rate capability (∼71 mAh g at 100 C) and an extreme cycle life output (∼75 mAh g with 95% capacity retention for 10,000 cycles). These excellent electrochemical properties can be ascribed to the synergistic effects of Cr and Fe in the NVP structure, as verified experimentally and theoretically. Therefore, the proposed cosubstitution method can enhance the performance of SIBs by improving their structural stability, electronic conductivity, and phase-change behavior.
doi_str_mv 10.1021/acsami.3c17166
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title NASICON-Type Na 3 V 1.5 Cr 0.4 Fe 0.1 (PO 4 ) 3 : High-Voltage and High-Rate Cathode Materials for Sodium-Ion Batteries
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